Comparison of Corrosion Behavior of CoCrNi Medium-Entropy Alloy with CoCrFeMnNi High-Entropy Alloy in SO2-Polluted Marine Environment
Source abstract
Abstract
A comparative study on the corrosion behavior of CoCrNi medium-entropy alloy (MEA) with CoCrFeMnNi high-entropy alloy (HEA) in SO2-polluted marine environment was investigated by a series of tests. Results indicate that CoCrNi MEA possesses smaller passive current density, larger polarization resistance and lower corrosion rate compared with those of CoCrFeMnNi HEA, which demonstrates that the MEA possesses better anti-corrosion performance than the HEA. This could be ascribed to the detail difference in the microstructure and passive film of the two alloys. Compared with the MEA, the smaller grain size and the larger number of oxides reduce the anti-corrosion performance of the HEA. Moreover, the oxide and matrix constitute the micro-galvanic corrosion cell, which promotes the generation of pits.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: High Entropy Alloys Studies · High-Temperature Coating Behaviors · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (72)
Show source-provided references
1. M.G. Stewart and A. Al-Harthy, Pitting Corrosion and Structural Reliability of Corroding RC Structures: Experimental Data and Probabilistic Analysis, Reliab. Eng. Syst. Safe., 2008, 93, p 373–382.10.1016/j.ress.2006.12.013 ↗
2. E. Han, J. Chen, Y. Su, and M. Liu, Corrosion Protection Techniques of Marine Engineering Structure and Ship Equipment-Current Status and Future Trend, Mater. China, 2014, 33, p 65–76.
3. Y.W. Ye, Y.X. Wang, H. Chen, J.L. Li, Y.R. Yao, and C.T. Wang, Doping Carbon to Improve the Tribological Performance of CrN Coatings in Seawater, Tribol. Int., 2015, 90, p 362–371.10.1016/j.triboint.2015.04.008 ↗
4. L.D. Yan, K. Xiao, P. Yi, C.F. Dong, J.S. Wu, Z.H. Bai, C.L. Mao, L. Jiang, and X.G. Li, The Corrosion Behavior of PCB-ImAg in Industry Polluted Marine Atmosphere Environment, Mater. Des., 2017, 115, p 404–414.10.1016/j.matdes.2016.11.074 ↗
5. W. Wu, Z.Y. Liu, Q.Y. Wang, and X.G. Li, Improving the Resistance of High-Strength Steel to SCC in a SO2-Polluted Marine Atmosphere through Nb and Sb Microalloying, Corros. Sci., 2020, 170, p 108693.10.1016/j.corsci.2020.108693 ↗
6. A. Milito, C. Murano, I. Castellano, G. Romano, and A. Palumbo, Antioxidant and Immune Response of the Sea Urchin Paracentrotus Lividus to Different Re-Suspension Patterns of Highly Polluted Marine Sediments, Mar. Environ. Res., 2020, 160, p 104978.10.1016/j.marenvres.2020.104978 ↗
7. G.S. Frankel, Pitting Corrosion of Metals: A Review of the Critical Factors, J. Electrochem. Soc., 1998, 145, p 2186–2198.10.1149/1.1838615 ↗
8. A. Nishikata, Q.J. Zhu, and E. Tada, Long-Term Monitoring of Atmospheric Corrosion at Weathering Steel Bridges by an Electrochemical Impedance Method, Corros. Sci., 2014, 87, p 80–88.10.1016/j.corsci.2014.06.007 ↗
9. D.D.N. Singh, S. Yadav, and J.K. Saha, Role of Climatic Conditions on Corrosion Characteristics of Structural Steels, Corros. Sci., 2008, 50, p 93–110.10.1016/j.corsci.2007.06.026 ↗
10. J. Alcantara, D. Fuente, B. Chico, J. Simancas, I. Diaz, and M. Morcillo, Marine Atmospheric Corrosion of Carbon Steel: A Review, Materials, 2017, 10, p 406.10.3390/ma10040406 ↗
11. H.C. Ma, C.W. Du, Z.Y. Liu, and X.G. Li, Effect of SO2 Content on SCC Behavior of E690 High-Strength Steel in SO2-Polluted Marine Atmosphere, Ocean Eng., 2018, 164, p 256–262.10.1016/j.oceaneng.2018.06.051 ↗
12. X.T. Wang, L.Y. Wang, and H.F. Sun, The Influence of Atmospheric SO2 and NaCl to Copper Corrosion, Mater. Prot., 2011, 44, p 28–31. (In Chinese)
13. J.X. Yu, H.K. Wang, Y. Yu, Z. Luo, W.D. Liu, and C.M. Wang, Corrosion Behavior of X65 Pipeline Steel: Comparison of Wet-Dry Cycle and Full Immersion, Corros. Sci., 2018, 133, p 276–287.10.1016/j.corsci.2018.01.007 ↗
14. J.V. Sharp, J. Billingham, and M.J. Robinson, The Risk Management of High-Strength Steels in Jack-Ups in Seawater, Mar. Struct., 2001, 14, p 537–551.10.1016/S0951-8339(00)00053-8 ↗
15. B.J. Dong, W. Liu, T.Y. Zhang, L.J. Chen, Y.M. Fan, Y.G. Zhao, W.J. Yang, and W. Banthukul, Corrosion Failure Analysis of Low Alloy Steel and Carbon Steel Rebar in Tropical Marine Atmospheric Environment: Outdoor Exposure and Indoor Test, Eng. Failure Anal., 2021, 129, p 105720.10.1016/j.engfailanal.2021.105720 ↗
16. M.F. Erinosho, E.T. Akinlabi, and S. Pityana, Microstructure and Corrosion Behaviour of Laser Metal Deposited Ti6Al4V/Cu Composites in 3.5% Sea Water, Mater. Today: Proc., 2015, 2, p 1166–1174.
17. J.W. Yeh, S.J. Lin, T.S. Chin, J.Y. Gan, S.K. Chen, T.T. Shun, C.H. Tsau, and S.Y. Chou, Formation of Simple Crystal Structures in Cu-Co-Ni-Cr-Al-Fe-Ti-V Alloys with Multiprincipal Metallic Elements, Metall. Mater. Trans. A, 2004, 35, p 2533–2536.10.1007/s11661-006-0234-4 ↗
18. A. Gali and E.P. George, Tensile Properties of High- and Medium-Entropy Alloys, Intermetallics, 2013, 39, p 74–78.10.1016/j.intermet.2013.03.018 ↗
19. B. Schuh, B. Völker, J. Todt, K.S. Kormout, N. Schell, and A. Hohenwarter, Influence of Annealing on Microstructure and Mechanical Properties of a Nanocrystalline CrCoNi Medium-Entropy Alloy, Materials, 2018, 11, p 662.10.3390/ma11050662 ↗
20. G. Laplanche, P. Gadaud, O. Horst, F. Otto, G. Eggeler, and E.P. George, Temperature Dependencies of the Elastic Moduli and Thermal Expansion Coefficient of an Equiatomic, Single-Phase CoCrFeMnNi High-Entropy Alloy, J. Alloys Compd., 2015, 623, p 348–353.10.1016/j.jallcom.2014.11.061 ↗
21. K. Lu, A. Chauhan, M. Walter, A.S. Tirunilai, M. Schneider, G. Laplanche, J. Freudenberger, A. Kauffmann, M. Heilmaier, and J. Aktaa, Superior Low-Cycle Fatigue Properties of CoCrNi Compared to CoCrFeMnNi, Scr. Mater., 2021, 194, p 113667.10.1016/j.scriptamat.2020.113667 ↗
22. G. Laplanche, A. Kostka, C. Reinhart, J. Hunfeld, G. Eggeler, and E.P. George, Reasons for the Superior Mechanical Properties of Medium-Entropy CrCoNi Compared to High-Entropy CrMnFeCoNi, Acta Mater., 2017, 128, p 292–303.10.1016/j.actamat.2017.02.036 ↗
23. M. Zhu, F. He, Y.Y. Yuan, S.Y. Guo, and G.Y. Wei, A Comparative Study on the Corrosion Behavior of CoCrNi Medium-Entropy Alloy and 316L Stainless Steel in Simulated Marine Environment, Intermetallics, 2021, 139, p 107370.10.1016/j.intermet.2021.107370 ↗
24. H. Luo, Z.M. Li, A.M. Mingers, and D. Raabe, Corrosion Behavior of an Equiatomic CoCrFeMnNi High-Entropy Alloy Compared with 304 Stainless Steel in Sulfuric Acid Solution, Corros. Sci., 2018, 134, p 131–139.10.1016/j.corsci.2018.02.031 ↗
25. H. Torbati-Sarraf, M. Shabani, P.D. Jablonski, G.J. Pataky, and A. Poursaee, The Influence of Incorporation of Mn on the Pitting Corrosion Performance of CrFeCoNi High Entropy Alloy at Different Temperatures, Mater. Des., 2019, 184, p 108170.10.1016/j.matdes.2019.108170 ↗
26. I. Moravcik, S.N. Peighambardoust, A. Motallebzadeh, L. Moravcikova-Gouvea, C. Liu, M.J. Prabhakar, I. Dlouhy, and Z.M. Li, Interstitial Nitrogen Enhances Corrosion Resistance of an Equiatomic CoCrNi Medium-Entropy Alloy in Sulfuric Acid Solution, Mater. Charact., 2021, 172, p 110869.10.1016/j.matchar.2020.110869 ↗
27. F. Huang, X.G. Li, J. Liu, Y.M. Qu, and C.W. Du, Effects of Alloying Elements, Microstructure, and Inclusions on Hydrogen Induced Cracking of X120 Pipeline Steel in Wet H2S Sour Environment, Mater. Corros., 2012, 63, p 59–66.10.1002/maco.201005649 ↗
28. N. Kumar, M. Fusco, M. Komarasamy, R.S. Mishra, M. Bourham, and K.L. Murty, Understanding Effect of 3.5 wt.% NaCl on the Corrosion of Al0.1CoCrFeNi High-Entropy Alloy, J. Nucl. Mater., 2017, 495, p 154–163.10.1016/j.jnucmat.2017.08.015 ↗
29. J.Z. Lu, X. Xu, H.F. Lu, Y.Y. Su, M.X. Peng, F. Xing, and K.Y. Luo, Comparing Corrosion Behavior of Additively Manufactured Cr-Rich Stainless Steel Coating Between Conventional and Extreme High-Speed Laser Metal Deposition, Corros. Sci., 2021, 195, p 109976.
30. D.D. Gu, H. Zhang, D.H. Dai, C.L. Ma, H.M. Zhang, Y.X. Li, and S.H. Li, Anisotropic Corrosion Behavior of Sc and Zr Modified Al-Mg Alloy Produced by Selective Laser Melting, Corros. Sci., 2020, 170, p 108657.10.1016/j.corsci.2020.108657 ↗
31. M. Alnajjar, F. Christien, V. Barnier, C. Bosch, K. Wolski, A.D. Fortes, and M. Telling, Influence of Microstructure and Manganese Sulfides on Corrosion Resistance of Selective Laser Melted 17–4 PH Stainless Steel in Acidic Chloride Medium, Corros. Sci., 2020, 168, p 108585.10.1016/j.corsci.2020.108585 ↗
32. D.Q. Martins, W.R. Osório, M.E.P. Souza, R. Caram, and A. Garcia, Effects of Zr Content on Microstructure and Corrosion Resistance of Ti-30Nb-Zr Casting Alloys for Biomedical Applications, Electrochim. Acta, 2008, 53, p 2809–2817.10.1016/j.electacta.2007.10.060 ↗
33. A. Shahriari, M. Ghaffari, L. Khaksar, A. Nasiri, A. Hadadzadeh, B.S. Amirkhiz, and M. Mohammadi, Corrosion Resistance of 13 wt.% Cr Martensitic Stainless Steels: Additively Manufactured CX Versus Wrought Ni-Containing AISI 420, Corros. Sci., 2021, 184, p 109362.10.1016/j.corsci.2021.109362 ↗
34. H. Luo, C.F. Dong, X.G. Li, and K. Xiao, The Electrochemical Behaviour of 2205 Duplex Stainless Steel in Alkaline Solutions with Different PH in the Presence of Chloride, Electrochim. Acta, 2012, 64, p 211–220.10.1016/j.electacta.2012.01.025 ↗
35. P. Shukla, Chap. 7-Thermodynamics of corrosion and potentiometric methods for measuring localized corrosion, in Techniques for Corrosion Monitoring, ed by L.T. Yang, (Woodhead Publishing, 2008), p 156–18610.1533/9781845694050.1.156 ↗
36. R.F. Li, Z.G. Li, Y.Y. Zhu, and K. Qi, Structure and Corrosion Resistance Properties of Ni-Fe-B-Si-Nb Amorphous Composite Coatings Fabricated by Laser Processing, J. Alloys Compd., 2013, 580, p 327–331.10.1016/j.jallcom.2013.06.111 ↗
37. A. Fattah-Alhosseini, and S. Vafaeian, Influence of Grain Refinement on the Electrochemical Behavior of AISI 430 Ferritic Stainless Steel in an Alkaline Solution, Appl. Surf. Sci., 2016, 360, p 921–928.10.1016/j.apsusc.2015.11.085 ↗
38. C.F. Dong, Z.Y. Liu, X.G. Li, and Y.F. Cheng, Effects of Hydrogen Charging on the Susceptibility of X100 Pipeline Steel to Hydrogen Induced Cracking, Int. J. Hydrog. Energy, 2009, 34, p 9879–9884.10.1016/j.ijhydene.2009.09.090 ↗
39. Z. Pu, X.L. Chen, X.D. Meng, Y.P. Wu, L. Shen, Q.F. Wang, T.W. Liu, and M.B. Shuai, Effect of Carbo-Nitride-Rich and Oxide-Rich Inclusions on the Pitting Susceptibility of Depleted Uranium, Corros. Sci., 2017, 124, p 160–166.10.1016/j.corsci.2017.05.019 ↗
40. E. Sidorova, A. Karasev, D. Kuznetsov, and P.G. Jönsson, Investigation of the Initial Corrosion Destruction of a Metal Matrix around Different Non-Metallic Inclusions on Surfaces of Pipeline Steels, Materials, 2022, 15, p 2530.10.3390/ma15072530 ↗
41. Y.H. Zhang, Q. Hu, M.J. Dai, F. Huang, F.Y. Cheng, and J. Liu, Investigation of Micro-Electrochemical Activities of Oxide Inclusions and Microphases in Duplex Stainless Steel and the Implication on Pitting Corrosion, Mater. Corros., 2020, 71, p 876–886.10.1002/maco.201911335 ↗
42. M. Schulte, S. Steentjes, N. Leuning, W. Bleck, and K. Hameyer, Effect of Manganese in High Silicon Alloyed Non-Oriented Electrical Steel Sheets, J. Magn. Magn. Mater., 2019, 477, p 372–381.10.1016/j.jmmm.2018.07.025 ↗
43. L. Pao, I. Muto, and Y. Sugawara, Pitting at Inclusions of the Equiatomic CoCrFeMnNi Alloy and Improving Corrosion Resistance by Potentiodynamic Polarization in H2SO4, Corros. Sci., 2021, 191, p 109748.10.1016/j.corsci.2021.109748 ↗
44. M. Zhu, B.Z. Zhao, Y.F. Yuan, S.M. Yin, and S.Y. Guo, Effect of Annealing Time on Microstructure and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy in Alkaline Soil Simulation Solution, Corros. Commun., 2021, 3, p 45–61.10.1016/j.corcom.2021.09.006 ↗
45. Z.Y. Cui, S.S. Chen, Y.P. Dou, S.K. Han, L.W. Wang, C. Man, X. Wang, S.G. Chen, Y.F. Cheng, and X.G. Li, Passivation Behavior and Surface Chemistry of 2507 Super Duplex Stainless Steel in Artificial Seawater: Influence of Dissolved Oxygen and PH, Corros. Sci., 2019, 150, p 218–234.10.1016/j.corsci.2019.02.002 ↗
46. M. Liu, Effect of Uniform Corrosion on Mechanical Behavior of E690 High-Strength Steel Lattice Corrugated Panel in Marine Environment: A Finite Element Analysis, Mater. Res. Express., 2021, 8, p 066510.10.1088/2053-1591/ac0655 ↗
47. D.C. Kong, C.F. Dong, X.Q. Ni, L. Zhang, H. Luo, R.X. Li, L. Wang, C. Man, and X.G. Li, Superior Resistance to Hydrogen Damage for Selective Laser Melted 316L Stainless Steel in a Proton Exchange Membrane Fuel Cell Environment, Corros. Sci., 2020, 166, p 108425.10.1016/j.corsci.2019.108425 ↗
48. K. Feng, Y. Zhang, Z.G. Li, C.W. Yao, L. Yao, and C.Y. Fan, Corrosion Properties of Laser Cladded CrCoNi Medium Entropy Alloy Coating, Surf. Coat. Tech., 2020, 397, p 126004.10.1016/j.surfcoat.2020.126004 ↗
49. J.B. Huang, X.Q. Wu, and E.H. Han, Electrochemical Properties and Growth Mechanism of Passive Films on Alloy 690 in High-Temperature Alkaline Environments, Corros. Sci., 2010, 52, p 3444–3452.10.1016/j.corsci.2010.06.016 ↗
50. M. Liu, Finite Element Analysis of Pitting Corrosion on Mechanical Behavior of E690 Steel Panel, Anti-Corros. Method. M., 2022, 28, p 7527–7536.
51. H. Feng, H.B. Li, X.L. Wu, Z.H. Jiang, S. Zhao, T. Zhang, D.K. Xu, S.C. Zhang, H.C. Zhu, B.B. Zhang, and M.X. Yang, Effect of Nitrogen on Corrosion Behaviour of a Novel High Nitrogen Medium-Entropy Alloy CrCoNiN Manufactured by Pressurized Metallurgy, J. Mater. Sci. Technol., 2018, 34, p 1781–1790.10.1016/j.jmst.2018.03.021 ↗
52. J.Z. Yao, D.D. Macdonald, and C.F. Dong, Passive Film on 2205 Duplex Stainless Steel Studied by Photo-Electrochemistry and ARXPS Methods, Corros. Sci., 2019, 146, p 221–232.10.1016/j.corsci.2018.10.020 ↗
53. S. Maximovitch, Influence of Formation Conditions on Impedance Properties of Nickel Passive Layers Formed in 1 M KOH, Electrochim. Acta, 1996, 41, p 2761–2771.10.1016/0013-4686(96)00135-1 ↗
54. S. Carmelo, P. Salvatore, and D.Q. Francesco, Photocurrent Spectroscopic Investigations of Passive Films on Chromium, J. Electrochem. Soc., 1990, 137, p 2411–2417.10.1149/1.2086952 ↗
55. R. Drasovean, S. Condurache-bota, and N. Tigau, Structural and Electricial Characterization of Cobalt Oxide Semiconductors, J. Sci. Arts, 2010, 2, p 379–384.
56. D.D. Macdonald, The Point Defect Model for the Passive State, J. Electrochem. Soc., 1992, 139, p 3434.10.1149/1.2069096 ↗
57. D.D. Macdonald, The History of the Point Defect Model for the Passive State: A Brief Review of Film Growth Aspects, Electrochim. Acta, 2011, 56, p 1761–1772.10.1016/j.electacta.2010.11.005 ↗
58. S. Ningshen, M.U. Kamachi, V.K. Mittal, and H.S. Khatak, Semiconducting and Passive Film Properties of Nitrogen-Containing Type 316LN Stainless Steels, Corros. Sci., 2007, 49, p 481–496.10.1016/j.corsci.2006.05.041 ↗
59. M. Zhu, B.Z. Zhao, Y.F. Yuan, S.Y. Guo, and G.Y. Wei, Study on Corrosion Behavior and Mechanism of CoCrFeMnNi HEA Interfered by AC Current in Simulated Alkaline Soil Environment, J. Electroanal. Chem., 2021, 882, p 115026.10.1016/j.jelechem.2021.115026 ↗
60. C.O.A. Olsson and D. Landolt, Passive Films on Stainless Steels—Chemistry, Structure and Growth, Electrochim. Acta, 2003, 48, p 1093–1104.10.1016/S0013-4686(02)00841-1 ↗
61. G.O. Ilevbare and G.T. Burstein, Role of Alloyed Molybdenum in the Inhibition of Pitting Corrosion in Stainless Steels, Corros. Sci., 2001, 43, p 485–513.10.1016/S0010-938X(00)00086-X ↗
62. M. Zhu, B.Z. Zhao, Y.F. Yuan, S.M. Yin, S.Y. Guo, and G.Y. Wei, Effect of Annealing Temperature on Microstructure and Corrosion Behavior of CoCrFeMnNi High-Entropy Alloy in Alkaline Soil Simulation Solution, Mater. Chem. Phys., 2022, 279, p 125725.10.1016/j.matchemphys.2022.125725 ↗
63. J. Soltis, Passivity Breakdown, Pit Initiation and Propagation of Pits in Metallic Materials - Review, Corros. Sci., 2015, 90, p 5–22.10.1016/j.corsci.2014.10.006 ↗
64. C.D. Dai, H. Luo, J. Lia, C.W. Du, Z.Y. Liu, and J.Z. Yao, X-Ray Photoelectron Spectroscopy and Electrochemical Investigation of the Passive Behavior of High-Entropy FeCoCrNiMox Alloys in Sulfuric Acid, Appl. Surf. Sci., 2020, 499, p 143903.10.1016/j.apsusc.2019.143903 ↗
65. H. Luo, S.S. Sohn, W.J. Lu, L.L. Li, X.G. Li, C.K. Soundararajan, W. Krieger, Z.M. Li, and D. Raabe, A Strong and Ductile Medium-Entropy Alloy Resists Hydrogen Embrittlement and Corrosion, Nat. Commun., 2020, 11, p 3081.10.1038/s41467-020-16791-8 ↗
66. J.Y. Wang, W.H. Li, H.L. Yang, H. Huang, S.H. Ji, J.M. Ruan, and Z.L. Liu, Corrosion Behavior of CoCrNi Medium-Entropy Alloy Compared with 304 Stainless Steel in H2SO4 and NaOH Solutions, Corros. Sci., 2020, 177, p 108973.10.1016/j.corsci.2020.108973 ↗
67. M. Sahal, J. Creus, R. Sabot, and X. Feaugas, Consequences of Plastic Strain on the Dissolution Process of Polycrystalline Nickel in H2SO4 Solution, Scr. Mater., 2004, 51, p 869–873.10.1016/j.scriptamat.2004.07.004 ↗
68. Y. Wang, X. Zhang, L. Cheng, J. Liu, T. Hou, and K. Wu, Correlation between Active/Inactive (Ca, Mg, Al)-Ox-Sy Inclusions and Localised Marine Corrosion of EH36 Steels, J. Mater. Res. Technol., 2021, 13, p 2419–2432.10.1016/j.jmrt.2021.06.030 ↗
69. W. Chen, L. Hao, J. Dong, and W. Ke, Effect of Sulphur Dioxide on the Corrosion of a Low Alloy Steel in Simulated Coastal Industrial Atmosphere, Corros. Sci., 2014, 83, p 155–163.10.1016/j.corsci.2014.02.010 ↗
70. I.M. Allam, J.S. Arlow, and H. Saricimen, Initial Stages of Atmospheric Corrosion of Steel in the Arabian Gulf, Corros. Sci., 1991, 32, p 417–432.10.1016/0010-938X(91)90123-7 ↗
71. W.Z. Wei, K.M. Wu, J. Liu, L. Cheng, and X. Zhang, Initiation and Propagation of Localized Corrosion Induced by (Zr, Ti, Al)-Ox Inclusions in Low-Alloy Steels in Marine Environment, J. Iron Steel Res. Int., 2021, 28, p 453–463.10.1007/s42243-020-00492-z ↗
72. Y.B. Hu, C.F. Dong, M. Sun, K. Xiao, P. Zhong, and X.G. Li, Effects of Solution pH and Cl− on Electrochemical Behaviour of an Aermet100 Ultra-High Strength Steel in Acidic Environments, Corros. Sci., 2011, 53, p 4159–4165.10.1016/j.corsci.2011.08.024 ↗