journal article·2019-09-01

Reinforcement Corrosion in Marine Concretes—1: Initiation

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ACI Materials Journal· Volume 116· Issue 5
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Abstract

Many cases of high-quality reinforced concrete structures in marine environments show little or no corrosion despite very high chloride contents in the concrete. To explain this, it is necessary to separate initiation from active corrosion because they are governed by different mechanisms. The present paper considers corrosion initiation. It reports observations for realistic model concrete specimens at intervals for up to 12 years of exposure in a high-humidity environment. Initiation of reinforcement corrosion occurred soon after first exposure and was predominantly localized (pitting) on the side away from the casting direction. The localized corrosion was consistent with air voids at the concrete steel interface. After 2 to 3 years, the rate of corrosion declined very considerably owing to oxygen depletion within the concrete. To explain these observations, a model involving electrochemical differential aeration at the air voids at the concrete-steel interface is proposed. Numerous practical implications are discussed.
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Research context

OpenAlex topics: Concrete Corrosion and Durability · Corrosion Behavior and Inhibition · Structural Behavior of Reinforced Concrete

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References (39)

Show source-provided references
1. Richardson, M. G., Fundamentals of Durable Reinforced Concrete, SponPress, London, UK, 2002.10.1201/9781482272109 ↗
2. Angst, U.; Elsener, B.; Larsen, C. K.; and Vennesland, O., “Critical Chloride Content in Reinforced Concrete—A Review,” Cement and Concrete Research, V. 39, No. 12, 2009, pp. 1122-1138. doi: 10.1016/j.cemconres.2009.08.00610.1016/j.cemconres.2009.08.006 ↗
3. Fukute, F., and Moriwake, A., “Ninety-Year Durability of Concrete Structures in the Port of Yokohama,” Concrete Under Severe Conditions 2: Environment and Loading, Proceedings of the Second International Conference on Concrete under Severe Conditions (CONSEC’98), O. E. Gjørv, K. Sakai, and N. Banthia, eds., E&FN Spon, London, UK, 1998, pp. 163-172.
4. Melchers, R. E.; Li, C. Q.; and Davison, M. A., “Observations and Analysis of a 63-year Old Reinforced Concrete Promenade Railing Exposed to the North Sea,” Magazine of Concrete Research, V. 61, No. 4, 2009, pp. 233-243. doi: 10.1680/macr.2007.0009310.1680/macr.2007.00093 ↗
5. Gjørv, O. E., Durability Design of Concrete Structures in Severe Environments, Taylor & Francis, London, UK, 2009.10.4324/9781482265903 ↗
6. Lau, K.; Sagues, A. A.; Yao, L.; and Powers, R. G., “Corrosion Performance of Concrete Cylinder Piles,” Corrosion, V. 63, No. 4, 2007, pp. 366-378. doi: 10.5006/1.327839010.5006/1.3278390 ↗
7. Papé, T. M., and Melchers, R. E., “The Effects of Corrosion on 45-Year-Old Prestressed Concrete Bridge Beams,” Structure and Infrastructure Engineering, V. 7, No. 1-2, 2011, pp. 101-108. doi: 10.1080/1573247100358841110.1080/15732471003588411 ↗
8. Melchers, R. E.; Papé, T. M.; Chaves, I. A.; and Heywood, R., “Long-Term Durability of Reinforced Concrete Piles from the Hornibrook Highway Bridge,” Australian Journal of Structural Engineering, V. 18, No. 1, 2017, pp. 41-57. doi: 10.1080/13287982.2017.132188110.1080/13287982.2017.1321881 ↗
9. Melchers, R. E., and Li, C. Q., “Reinforcement Corrosion Initiation and Activation Times in Concrete Structures Exposed to Severe Marine Environments,” Cement and Concrete Research, V. 39, No. 11, 2009, pp. 1068-1076. doi: 10.1016/j.cemconres.2009.07.00310.1016/j.cemconres.2009.07.003 ↗
10. Melchers, R. E., and Li, C. Q., “Phenomenological Modeling of Corrosion Loss of Steel Reinforcement in Marine Environments,” ACI Materials Journal, V. 103, No. 1, Jan.-Feb. 2006, pp. 25-32.
11. François, R., and Arliguie, G., “Effect of Microcracking and Cracking on the Development of Corrosion in Reinforced Concrete Members,” Magazine of Concrete Research, V. 51, No. 2, 1999, pp. 143-150. doi: 10.1680/macr.1999.51.2.14310.1680/macr.1999.51.2.143 ↗
12. Melchers, R. E., and Chaves, I. A., “A Comparative Study of Chlorides and Longer-Term Reinforcement Corrosion,” Materials and Corrosion, V. 68, No. 6, 2017, pp. 613-621. doi: 10.1002/maco.20160931010.1002/maco.201609310 ↗
13. Tuuti, K., “Service Life of Structures with Regard to Corrosion of Embedded Steel,” Performance of Concrete in Marine Environment, SP-65, American Concrete Institute, Farmington Hills, MI, 1980, pp. 223-236.
14. Clear, K. C., “Time-to-Corrosion for Reinforcing Steel in Concrete Slabs. V. 3: Performance after 830 Daily Salt Applications,” Report No. FHWA-RD-76-70, Federal Highway Administration, Washington, DC, Apr. 1976, 64 pp.
15. Hausmann, D. A., “Steel Corrosion in Concrete,” Materials Protection, V. 6, No. 11, 1967, pp. 19-23.
16. Monfore, G. E., and Verbeek, G. J., “Corrosion of Prestressed Wire in Concrete,” ACI Journal Proceedings, V. 57, No. 11, Nov. 1975, pp. 491-515.
17. Escalante, E., and Ito, S., “Measuring the Rate of Corrosion of Steel in Concrete,” Corrosion Rates of Steel in Concrete, ASTM STP 1065, N. S. Berke, V. Chaker, and D. Whiting, eds., ASTM International, West Conshohocken, PA, 1990, pp. 86-102.10.1520/STP25017S ↗
18. Poursaee, A., and Hansson, C. M., “Potential Pitfalls in Assessing Chloride-Induced Corrosion of Steel in Concrete,” Cement and Concrete Research, V. 39, No. 5, 2009, pp. 391-400. doi: 10.1016/j.cemconres.2009.01.01510.1016/j.cemconres.2009.01.015 ↗
19. Glass, G. K., and Buenfeld, N. R., “The Presentation of the Chloride Threshold Level for Corrosion of Steel in Concrete,” Corrosion Science, V. 39, No. 5, 1997, pp. 1001-1013. doi: 10.1016/S0010-938X(97)00009-710.1016/S0010-938X(97)00009-7 ↗
20. St. John, D. A.; Poole, A. W.; and Sims, I., Concrete Petrography, Arnold, London, UK, 1988.
21. Parrott, L. J., “A Review of Carbonation in Reinforced Concrete,” Building Research Establishment, Department of the Environment, UK, 1987.
22. Melchers, R. E., and Jeffrey, R., “Long-Term Corrosion of Mild Steel in Natural and UV-Treated Coastal Seawater,” Corrosion, V. 70, No. 8, 2014, pp. 804-818. doi: 10.5006/112210.5006/1122 ↗
23. Bungey, J. H., The Testing of Concrete in Structures, Surrey University Press, Guildford, UK, 1982.
24. Grubb, J. A.; Limaye, H. S.; and Kakade, A. M., “Testing pH of Concrete,” Concrete International, V. 29, No. 4, Apr. 2007, pp. 78-83.
25. Horne, A. T.; Richardson, I. G.; and Brydson, R. M. D., “Quantitative Analysis of the Microstructure of Interfaces in Steel Reinforced Concrete,” Cement and Concrete Research, V. 37, No. 12, 2007, pp. 1613-1623. doi: 10.1016/j.cemconres.2007.08.02610.1016/j.cemconres.2007.08.026 ↗
26. Bouteiller, V.; Cremona, C.; Baroghel-Bouny, V.; and Maloula, A., “Corrosion Initiation of Reinforced Concretes Based on Portland or GGBS Cements: Chloride Contents and Electrochemical Characteristics versus Time,” Cement and Concrete Research, V. 42, No. 11, 2012, pp. 1456-1467. doi: 10.1016/j.cemconres.2012.07.00410.1016/j.cemconres.2012.07.004 ↗
27. Nawy, E. G., Concrete Construction Engineering Handbook, CRC Press, Boca Raton, FL, 2008, pp. 30-57.10.1201/9781420007657.ch17 ↗
28. Zhang, R.; Castel, A.; and Francois, R., “Influence of Steel-Concrete Interface Defects Owing to the Top-Bar Effect on the Chloride-Induced Corrosion of Reinforcement,” Magazine of Concrete Research, V. 63, No. 10, 2011, pp. 773-781. doi: 10.1680/macr.2011.63.10.77310.1680/macr.2011.63.10.773 ↗
29. Jones, D. A., Principles and Prevention of Corrosion, second editiion, Prentice-Hall, Upper Saddle River, NJ, 1996.
30. Chitty, W.-J.; Dillmann, P.; L’Hostis, V.; and Lombard, C., “Long-Term Corrosion Resistance of Metallic Reinforcements in Concrete—A Study of Corrosion Mechanisms Based on Archaeological Artefacts,” Corrosion Science, V. 47, No. 6, 2005, pp. 1555-1581. doi: 10.1016/j.corsci.2004.07.03210.1016/j.corsci.2004.07.032 ↗
31. Pourbaix, M., “Significance of Protection Potential in Pitting and Intergranular Corrosion,” Corrosion, V. 26, No. 10, 1970, pp. 431-438. doi: 10.5006/0010-9312-26.10.43110.5006/0010-9312-26.10.431 ↗
32. Heyn, E., and Bauer, O., “Ueber den Angriff des Eisens durch Wasser und wässerige Losungen,” Stahl und Eisen, V. 28, No. 44, 1908, pp. 1564-1573.
33. Brasher, D. M., “Stability of the Oxide Film on Metals in Relation to Inhibition of Corrosion. I. Mild Steel in the Presence of Aggressive Ions,” British Corrosion Journal, V. 2, No. 3, 1967, pp. 95-103. doi: 10.1179/00070596779832688510.1179/000705967798326885 ↗
34. Mercer, A. D., and Lumbard, E. A., “Corrosion of Mild Steel in Water,” British Corrosion Journal, V. 30, No. 1, 1995, pp. 43-55. doi: 10.1179/bcj.1995.30.1.4310.1179/bcj.1995.30.1.43 ↗
35. Butler, G.; Stretton, P.; and Beynon, J. G., “Initiation and Growth of Pits on High-Purity Iron and its Alloys with Chromium and Copper in Neutral Chloride Solutions,” British Corrosion Journal, V. 7, No. 4, 1972, pp. 168-173. doi: 10.1179/00070597279832299110.1179/000705972798322991 ↗
36. Sharland, S. M., and Tasker, P. W., “A Mathematical Model of Crevice and Pitting Corrosion—I. The Physical Model,” Corrosion Science, V. 28, No. 6, 1988, pp. 603-620. doi: 10.1016/0010-938X(88)90027-310.1016/0010-938X(88)90027-3 ↗
37. Jeffrey, R., and Melchers, R. E., “The Changing Topography of Corroding Mild Steel Surfaces in Seawater,” Corrosion Science, V. 49, No. 5, 2007, pp. 2270-2288. doi: 10.1016/j.corsci.2006.11.00310.1016/j.corsci.2006.11.003 ↗
38. Melchers, R. E., “A Review of Trends for Corrosion Loss and Pit Depth in Longer-Term Exposures,” Corrosion and Materials Degradation, V. 1, No. 1, 2018, pp. 42-58. doi: 10.3390/cmd101000410.3390/cmd1010004 ↗
39. Wranglen, G., “Pitting and Sulphide Inclusions in Steel,” Corrosion Science, V. 14, No. 5, 1974, pp. 331-349. doi: 10.1016/S0010-938X(74)80047-810.1016/S0010-938X(74)80047-8 ↗