journal article·2023-03Open access

Effects of Laser Surface Remelting on Microstructure and Corrosion Properties of Mg-12Dy-1.1Ni Alloy

Guangli Bi, Siqi Chen, Jing Jiang, Yuandong Li, Tijun Chen, Xiao-Bo Chen, Duyao Zhang, Dong Qiu, Mark Easton

Abstract

Abstract Effects of laser surface remelting (LSR) on microstructure and corrosion properties of as-cast Mg-12Dy-1.1Ni (wt.%) alloy were investigated. The as-cast alloy was mainly composed of α-Mg, lamellar Mg12DyNi phase with an 18R-long period stacking order (LPSO) structure and Mg24Dy5. After LSR treatment, fine and compact 18R-LPSO phase reprecipitated on dendrite boundaries as a continuous network. In addition, the volume fraction of the LPSO phase remarkably increased to 34.9% and the grain size of as-cast alloy was refined to ca. 4 μm. Electrochemical and immersion tests indicated that the LSR-treated alloy exhibited a lower weight loss rate (2.8 ± 0.2 mg/cm2/h) and corrosion current density (160.1 ± 20.7 μA/cm2, and of 37% reduction after LSR) than the as-cast alloy in 0.1 M NaCl solution. The improved corrosion resistance of the LSR alloy was mainly ascribed to the grain refinement and continuous distribution of 18R-LPSO phase on dendrite boundaries.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Hydrogen Storage and Materials · Aluminum Alloys Composites Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (42)

Show source-provided references
1. G.L. Bi, Y.S. Wang, J. Jiang, J.R. Gu and Y. Ma, Microstructure and Mechanical Properties of Extruded Mg-Y-Zn (Ni) Alloys, J. Alloys Compd., 2021, 881, 160577.10.1016/j.jallcom.2021.160577 ↗
2. G.L. Bi, Y.X. Han, J. Jiang, Y.D. Li, D.Y. Zhang, D. Qiu and M. Easton, Microstructure and Mechanical Properties of an Extruded Mg-Dy-Ni Alloy, Mater. Sci. Eng. A, 2019, 760, p 246–257.10.1016/j.msea.2019.06.006 ↗
3. Y. Yao, Z.H. Huang, H. Ma, H. Zhang, Z.M. Zhan, C.J. Xu, N. Zhou, M. Kuang and J.C. Huang, High Strength Mg-1.4Gd-1.2Y-0.4Zn Sheet and its Strengthening Mechanisms, Mater. Sci. Eng. A, 2017, 747, p 17–26.10.1016/j.msea.2019.01.055 ↗
4. L. Zhang, S.J. Zhang, P. Xu and H. Huang, Effects of Substitution of Cu with Ni on Microstructure and Mechanical Properties of Mg-Er-Cu Alloy, J. Mater. Eng. Perform., 2021, 23(10), p 2100368.
5. H. Liu, F. Xue, J. Bai and J. Zhou, Microstructure and Mechanical Properties of a Mg94Y4Ni2 Alloy with Long Period Stacking Ordered Structure, J Mater. Eng. Perform., 2013, 22, p 3500–3506.10.1007/s11665-013-0617-9 ↗
6. Z. Hu, Z. Yin, Z. Yin, K. Wang, Q. Liu, P. Sun, H. Yan, H. Song, C. Luo, H. Guan and C. Luc, Corrosion Behavior Characterization of as Extruded Mg-8Li-3Al Alloy with Minor Alloying Elements (Gd, Sn and Cu) by Scanning Kelvin Probe Force Microscopy, Corros. Sci, 2020, 176, 108923.10.1016/j.corsci.2020.108923 ↗
7. J. Zhang, B. Jiang, Q. Yang, D. Huang, A. Tang, F. Pan and Q. Han, Role of Second Phases on the Corrosion Resistance of Mg-Nd-Zr Alloys, J. Alloys Compd., 2020, 849, 156619.10.1016/j.jallcom.2020.156619 ↗
8. J. Liu, L. Yang, C. Zhang, B. Zhang, T. Zhang, Y. Li, K. Wu and F. Wang, Role of the LPSO Structure in the Improvement of Corrosion Resistance of Mg-Gd-Zn-Zr Alloys, J. Alloys Compd., 2019, 782, p 648–658.10.1016/j.jallcom.2018.12.233 ↗
9. X. Zhang, W. Qian, F. Chen, Y. Wu and W. Qiang, Relation Between LPSO Structure and Biocorrosion Behavior of Biodegradable GZ51K Alloy, Mater. Lett., 2015, 138, p 212–215.10.1016/j.matlet.2014.09.133 ↗
10. X. Zhao, L.L. Shi and J. Xu, Mg-Zn-Y Alloys with Long-Period Stacking Ordered Structure: In Vitro Assessments of Biodegradation Behavior, Mater. Sci. Eng. C, 2013, 33, p 3627–3637.10.1016/j.msec.2013.04.051 ↗
11. P. Pérez, S. Cabeza, G. Garcés and P. Adeva, Influence of Long Period Stacking Ordered Phase Arrangements on the Corrosion Behaviour of Extruded Mg97Y2Zn1 Alloy, Corros. Sci., 2016, 107, p 107–112.10.1016/j.corsci.2016.02.024 ↗
12. R. Maurya, A.R. Siddiqui and K. Balani, An Environment-Friendly Phosphate Chemical Conversion Coating on Novel Mg-9Li-7Al-1Sn and Mg-9Li-5Al-3Sn-1Zn Alloys with Remarkable Corrosion Protection, Appl. Surf. Sci., 2018, 443, p 429–440.10.1016/j.apsusc.2018.02.254 ↗
13. K.D. Ralston, N. Birbilis and C.H.J. Davies, Revealing the Relationship Between Grain Size and Corrosion Rate of Metals, Scr. Mater., 2010, 63(12), p 1201–1204.10.1016/j.scriptamat.2010.08.035 ↗
14. Y. Cubides, A.I. Karayan, M.W. Vaughan, I. Karaman and H. Castaneda, Enhanced Mechanical Properties and Corrosion Resistance of a Fine-Grained Mg-9Al-1Zn Alloy: The Role of Bimodal Grain Structure and β-Mg17Al12 Precipitates, Materialia, 2020, 13, 100840.10.1016/j.mtla.2020.100840 ↗
15. G.R. Argade, S.K. Panigrahi and R.S. Mishra, Effects of Grain Size on the Corrosion Resistance of Wrought Magnesium Alloys Containing Neodymium, Corros. Sci., 2012, 58, p 145–151.10.1016/j.corsci.2012.01.021 ↗
16. Y.H. Li, S. Arthanari and Y.C. Guan, Influence of Laser Surface Melting on the Properties of MB26 and AZ80 Magnesium Alloys, Surf. Coat Technol., 2019, 378, 124964.10.1016/j.surfcoat.2019.124964 ↗
17. D.H. StJohn, M. Qian, M.A. Easton and P. Cao, The Interdependence Theory: The Relationship Between Grain Formation and Nucleant Selection, Acta Mater., 2011, 59, p 4907–4921.10.1016/j.actamat.2011.04.035 ↗
18. D. Shu, B. Sun, J. Mi and P.S. Grant, A Quantitative Study of Solute Diffusion Field Effects on Heterogeneous Nucleation and the Grain Size of Alloys, Acta Mater., 2011, 59, p 2135–2144.10.1016/j.actamat.2010.12.014 ↗
19. D.Y. Zhang, D. Qiu, S.M. Zhu, M. Dargusch and M.A. Easton, Grain Refinement in Laser Remelted Mg-3Nd-1Gd-0.5Zr Alloy, Scr. Mater., 2020, 183, p 12–16. https://doi.org/10.1016/j.scriptamat.2020.03.00610.1016/j.scriptamat.2020.03.006 ↗
20. J. Park, H.S. Han, J. Park, H. Seo, J. Edwards, Y.C. Kim, M.R. Ok, H.K. Seok and H. Jeon, Corrosion Behavior of Biodegradable Mg-Based Alloys via Femtosecond Laser Surface Melting, Appl. Surf. Sci., 2018, 448, p 424–434.10.1016/j.apsusc.2018.04.088 ↗
21. Y.C. Guan, W. Zhou, Z.L. Li and H.Y. Zheng, Study on the Solidification Microstructure in AZ91D Mg Alloy After Laser Surface Melting, Appl. Surf. Sci., 2009, 255, p 8235–8238.10.1016/j.apsusc.2009.05.055 ↗
22. K.R. Rakensh, S. Bontha, M.R. Ramesh, M. Das and V.K. Balla, Laser Surface Melting of Mg-Zn-Dy Alloy for Better Wettability and Corrosion Resistance for Biodegradable Implant Applications, Appl. Surf. Sci., 2019, 480, p 70–82.10.1016/j.apsusc.2019.02.167 ↗
23. A.E. Coy, F. Viejo, F.J. Garcia-Garcia, Z. Liu, P. Skeldon and G.E. Thompson, Effect of Excimer Laser Surface Melting on the Microstructure and Corrosion Performance of the Die Cast AZ91D Magnesium Alloy, Corros. Sci., 2010, 52, p 387–397.10.1016/j.corsci.2009.09.025 ↗
24. S.C. Chen and J.C. Huang, Influence of Welding Parameters on Microstructures and Mechanical Properties of Electron Beam Welded Aluminium-Lithium Plates, J. Mater. Sci. Technol., 2013, 15, p 965–978.10.1179/026708399101506652 ↗
25. J.S. Zhang, J.D. Xu, W.L. Cheng, C.J. Chen and J.J. Kang, Corrosion Behavior of Mg-Zn-Y Alloy with Long-Period Stacking Ordered Structures, J. Mater. Sci. Technol., 2012, 28(12), p 1157–1162.10.1016/S1005-0302(12)60186-8 ↗
26. Y.M. Zhu, A.J. Morton and J.F. Nie, The 18R and 14H Long-Period Stacking Ordered Structures in Mg-Y-Zn Alloys, Acta Mater., 2010, 58, p 2936–2947.10.1016/j.actamat.2010.01.022 ↗
27. G.L. Bi, X.M. Luo, J. Jiang, Y.G. Zhang, J.J. Xu, J.M. Chen, Y.D. Li and Y. Ma, Effect of Zn Cu and Ni Addition on Microstructure and Mechanical Properties of As-Cast Mg-Dy Alloys, China Foundry., 2016, 13, p 54–58.10.1007/s41230-016-5062-6 ↗
28. H. Liu, F. Xue, J. Bai and Y.S. Sun, Effect of Heat Treatments on the Microstructure and Mechanical Properties of an Extruded Mg95.5Y3Zn1.5 Alloy, Mater. Sci. Eng. A, 2013, 585, p 261–267.10.1016/j.msea.2013.07.025 ↗
29. D. Wang, H. Wu, R. Wu, Y. Wang, J. Zhang, S. Betsofen, B. Krit, L. Hou and T. Nodir, The Transformation of LPSO Type in Mg-4Y-2Er-2Zn-0.6Zr and its Response to the Mechanical Properties and Damping Capacities, J. Magnes. Alloys, 2020, 8(3), p 793–798. https://doi.org/10.1016/j.jma.2019.10.00310.1016/j.jma.2019.10.003 ↗
30. Y.Q. Ge, W.X. Wang, S. Guo and Z.Q. Cui, Laser Surface Melting and Strengthening Magnesium Alloy Far from Equilibrium, Rare Metal Mater. Eng., 2016, 45, p 1949–1955.10.1016/S1875-5372(16)30152-7 ↗
31. D. Zhang, Y. Qin, W. Feng, M. Huang, X. Wang and S. Yang, Microstructural Evolution of the Amorphous Layers on Mg-Zn-Ca Alloy During Laser Remelting Process, Surf. Coatings Technol., 2019, 363, p 87–94.10.1016/j.surfcoat.2019.02.051 ↗
32. P.C. Banerjee, R.K.S. Raman, Y. Durandet and G. McADam, Influence of Laser Processing Parameters on Microstructure and Corrosion kinetics of Laser-Treated ZE41 Magnesium Alloy, Metall. Mater. Trans. A, 2013, 44, p 2346–2357.10.1007/s11661-012-1590-x ↗
33. C.C. Liu, J. Liang, J.S. Zhou, L.Q. Wang and Q.B. Li, Effect of Laser Surface Melting on Microstructure and Corrosion Characteristics of AM60B Magnesium Alloy, Appl. Surf. Sci., 2015, 343, p 133–140.10.1016/j.apsusc.2015.03.067 ↗
34. H.G. Liao, P.H. Fu, L.M. Peng, J. Li, S.Q. Zhang, G.Q. Hu and W.J. Ding, Microstructure and Mechanical Properties of Laser Melting Deposited GW103K Mg-RE Alloy, Mater. Sci. Eng. A, 2017, 687, p 281–287.10.1016/j.msea.2017.01.084 ↗
35. J.R. Zhang, Y.C. Guan, W.T. Lin and X.N. Gu, Enhanced Mechanical Properties and Biocompatibility of Mg-Gd-Ca alloy by Laser Surface Processing, Surf. Coat. Technol., 2019, 362, p 176–184.10.1016/j.surfcoat.2019.01.063 ↗
36. C.C. Liu, J. Liang, J.S. Zhou, Q.B. Li and L.Q. Wang, Characterization of AZ31 Magnesium Alloy by Duplex Process Combining Laser Surface Melting and Plasma Electrolytic Oxidation, Appl. Surf. Sci., 2016, 382, p 47–55.10.1016/j.apsusc.2016.04.047 ↗
37. J.D. Majumdar, R. Galun, B.L. Mordike and I. Manna, Effect of Laser Surface Melting on Corrosion and Wear Resistance of a Commercial Magnesium Alloy, Mater. Sci. Eng. A, 2003, 361, p 119–129.10.1016/S0921-5093(03)00519-7 ↗
38. Y.J. Feng, L. Wei, X.B. Chen, M.C. Li, Y.F. Cheng and Q. Li, Unexpected Cathodic Role of Mg41Sm5 Phase in Mitigating Localized Corrosion of Extruded Mg-Sm-Zn-Zr Alloy in NaCl Solution, Corros. Sci., 2019, 159, 108133.10.1016/j.corsci.2019.108133 ↗
39. T. Zhang, G.Z. Meng, Y.W. Shao, Z.Y. Cui and F.H. Wang, Corrosion of Hot Extrusion AZ91 Magnesium Alloy. Part II: Effect of Rare Earth Element Neodymium (Nd) on the Corrosion Behavior of Extruded Alloy, Corros. Sci., 2011, 53, p 2934–2942.10.1016/j.corsci.2011.05.035 ↗
40. H.R. Bakhsheshi-Rad, M.R. Abdul-Kadir, M.H. Idris and S. Farahany, Relationship Between the Corrosion Behavior and the Thermal Characteristics and Microstructure of Mg-0.5Ca-xZn Alloys, Corros. Sci., 2012, 64, p 184–197.10.1016/j.corsci.2012.07.015 ↗
41. L. Yang, N. Hort, D. Laipple, D. Höche, Y. Huang, K.U. Kainer, R. Willumeit and F. Feyerabend, Element Distribution in the Corrosion Layer and Cytotoxicity of Alloy Mg-10Dy During In Vitro Biodegradation, Acta Biomater., 2013, 9, p 8475–8487.10.1016/j.actbio.2012.10.001 ↗
42. N. Birbilis, K.D. Ralston, S. Virtanen, H.L. Fraser and C.H.J. Davies, Grain Character Influences on Corrosion of ECAPed Pure Magnesium, Corros. Eng. Sci. Technol., 2010, 45(3), p 224–230.10.1179/147842209X12559428167805 ↗