Effects of ZrO2 Coating on LiNi1/3Mn1/3Co1/3O2 Particle with Microwave Pyrolysis
Source abstract
Abstract
In this paper, ZrO2-coated LiNi1/3Mn1/3Co1/3O2 is successfully prepared by the microwave pyrolysis method. The structure and electrochemical properties of the ZrO2-coated LiNi1/3Co1/3Mn1/3O2 are investigated using x-ray diffraction, AC impedance, and charge/discharge tests, indicating that the lattice structure of LiNi1/3Co1/3Mn1/3O2 is unchanged after the coating but the cycling stability is improved. As the coating amount is 2 wt.%, initial capacity of the coated LiNi1/3Co1/3Mn1/3O2 decreases slightly. However, the cycling stability increases remarkably over the cut-off voltages of 2.75~4.3 V and the capacity retention reaches 93.1% after 50 cycles. Electrochemical impedance spectra results show that the increase of charge transfer resistance during cycling is suppressed significantly by coating with ZrO2.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Advanced Battery Materials and Technologies
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References (22)
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1. T. Ohzuku and Y. Makimura, Layered Lithium Insertion Material of LiNi1/3Co1/3Mn1/3O2 for Lithium-Ion Batteries, Chem. Lett., 2001, 30(7), p 642–64310.1246/cl.2001.642 ↗
2. D.D. MacNeil, Z. Lu, and J.R. Dahn, Structure and Electrochemistry of Li[Ni x Co1−2x Mn x ]O2 (0 ≤ x ≤ l/2), J. Electrochem. Soc., 2002, 149(10), p A1332–A133610.1149/1.1505633 ↗
3. S. Jouanneau, D.D. MacNeil, Z. Lu, S.D. Beattie, G. Murphy, and J.R. Dahn, Morphology and Safety of Li[Ni x Co1−2x Mn x ]O2 (0 ≤ x ≤ l/2), J. Electrochem. Soc., 2003, 150(10), p A1299–A130410.1149/1.1602077 ↗
4. K. Zaghib, A. Mauger, H. Groult, J.B. Goodenough, and C.M. Julien, Advanced Electrodes for High Power Li-Ion Batteries, Materials, 2013, 6(3), p 1028–104910.3390/ma6031028 ↗
5. H. Yamei, Z. Zhengfu, Z. Libo, P. Jinhui, and F. Mengbi, The Analysis of Orthogonal Experiment Method of Carbon-Coated LiNi1/3Mn1/3Co1/3O2 via Microwave-Pyrolysis Method, In 4th International Symposium on High-Temperature Metallurgical Processing, 2013, p 277–28510.1002/9781118663448.ch34 ↗
6. Y. Shangyun, X. Yongyao, Z. Pingwei, and Q. Zhiyu, Al, B, and F Doped LiNi1/3Co1/3Mn1/3O2 as Cathode Material of Lithium-Ion Batteries, J. Solid State Electrochem., 2007, 11(6), p 805–81010.1007/s10008-006-0226-8 ↗
7. L. Liu, K. Sun, N. Zhang, and T. Yang, Improvement of High-Voltage Cycling Behavior of Li(Ni1/3Co1/3Mn1/3)O2 Cathodes by Mg, Cr and Al substitution, J. Solid State Electrochem., 2009, 13(9), p 1381–138610.1007/s10008-008-0695-z ↗
8. Y. Sasaki, Y. Kikuzono, N. Fukiya, N. Taguchi, K. Araki, K. Okamura, K. Kojimaf, F. Kitaf, T. Takeuchig, H. Sakaebeg, K. Tatsumig, and Z. Ogumi, Structural and Electrochemical Properties of LiNi1/3Co1/3Mn1/3O2 Positive Electrode Material Modified by Coating with Al Oxides (2), 223rd ECS Meeting, J. Electrochem. Soc., 2012, 8, p 627
9. B. Bang and T. Yeu, Characterization of LiNi1/3Mn1/3Co1/3O2/C Composite Positive Electrodes for Non-Aqueous Supercapacitors, 223rd ECS Meeting, J. Electrochem. Soc., 2012, 6, p 589
10. X. Liu, H. Li, E. Yoo, M. Ishida, and H. Zhou, Fabrication of FePO4 layer coated LiNi1/3Co1/3Mn1/3O2: Towards High-performance Cathode Materials for Lithium Ion Batteries, Electrochim. Acta, 2012, 83, p 253–25810.1016/j.electacta.2012.07.111 ↗
11. H.B. Kang, S.T. Myung, K. Amine, S.M. Lee, and Y.K. Sun, Improved Electrochemical Properties of BiOF-Coated 5V Spinel Li[Ni0.5Mn1.5]O4 for Rechargeable Lithium Batteries, J. Power Sour., 2010, 195(7), p 2023–202810.1016/j.jpowsour.2009.10.068 ↗
12. T. Ohzuku, A. Ueda, and M. Nagayama, Electrochemistry and Structural Chemistry of LiNiO2 (R3m) for 4 Volt Secondary Lithium Cells, J. Electrochem. Soc., 1993, 140(7), p 1862–187010.1149/1.2220730 ↗
13. Z. Chen and J.R. Dahn, Effect of a ZrO2 Coating on the Structure and Electrochemistry of LixCoO2 When Cycled to 4.5 V, Electrochem. Solid State Lett., 2002, 5(10), A213–A21610.1149/1.1503202 ↗
14. Y. Gao, M.V. Yakovleva, and W.B. Ebner, Novel LiNi1−x Ti x/2Mg x/2O2 Compounds as Cathode Materials for Safer Lithium-Ion Batteries, Electrochem. Solid State Lett., 1998, 1(3), p 117–11910.1149/1.1390656 ↗
15. K.M. Shaju, G.V. Subba Rao, and B.V.R. Chowdari, Performance of Layered Li(Ni1/3Co1/3Mn1/3)O2 as Cathode for Li-Ion Batteries, Electrochim. Acta, 2002, 48(2), p 145–15110.1016/S0013-4686(02)00593-5 ↗
16. Y. Huang, J. Chen, J. Ni, H. Zhou, and X. Zhang, A Modified ZrO2-Coating Process to Improve Electrochemical Performance of Li(Ni1/3Co1/3Mn1/3)O2, J. Power Sour., 2009, 188(2), p 538–54510.1016/j.jpowsour.2008.12.037 ↗
17. S. Xiaoran, L. Jiajun, S. Chunsheng, W. Zhiyuan, L. Enzuo, H. Chunnian, D. Xiwen, and Z. Naiqin, Enhanced Electrochemical Performance of LiFePO4 Cathode with In-Situ Chemical Vapor Deposition Synthesized Carbon Nanotubes as Conductor, J. Power Sour., 2012, 220, p 264–26810.1016/j.jpowsour.2012.07.082 ↗
18. C.H. Chen, J. Liu, and K. Amine, Symmetric Cell Approach and Impedance Spectroscopy of High Power Lithium-Ion Batteries, J. Power Sour., 2001, 96, p 321–32810.1016/S0378-7753(00)00666-2 ↗
19. J. Liu and A. Manthiram, Understanding the Improvement in the Electrochemical Properties of Surface Modified 5 V LiMn1.42Ni0.42Co0.16O4 Spinel Cathodes in Lithium-Ion Cells, Chem. Mater., 2009, 21, p 1695–170710.1021/cm9000043 ↗
20. W. Zhiyuan, L. Enzuo, H. Chunnian, S. Chunsheng, L. Jiajun, and Z. Naiqin, Effect of Amorphous FePO4 Coating on Structure and Electrochemical Performance of Li1.2Ni0.13Co0.13Mn0.54O2 as Cathode Material for Li-Ion Batteries, J. Power Sour., 2013, 236, p 25–3210.1016/j.jpowsour.2013.02.022 ↗
21. X. Liu, P. He, H. Li, M. Ishida, M. Ishida, and H. Zhou, Improvement of Electrochemical Properties of LiNi1/3Co1/3Mn1/3O2 by Coating with V2O5 Layer, J. Alloys Compd., 2012, 552, p 76–8210.1016/j.jallcom.2012.10.090 ↗
22. S.T. Myung, K.S. Lee, C.S. Yoon, Y.K. Sun, K. Amine, and H. Yashiro, Effect of AlF3 Coating on Thermal Behavior of Chemically Delithiated Li0.35[Ni1/3Co1/3Mn1/3]O2, J. Phys. Chem. C, 2010, 114(10), p 4710–471810.1021/jp9082322 ↗