journal article·2023-04Open access

Coaxial Laser Cladding of Cobalt-Base Alloy Stellite™ 6 on Grey Cast Iron Analysis of the Microstructural and Mechanical Properties Depending on the Laser Power

Maximilian Kiehl, Adriano Scheid, Karin Graf, Benedikt Ernst, Ulrich Tetzlaff

Abstract

Abstract A high-power diode laser was used to generate single- and multi-bead coatings of Stellite™ 6 by coaxial laser cladding over flat grey cast iron (EN-GJLP-200) as a preliminary study to develop a wear and corrosion resistant coating for brake disks on a cost-effective substrate. In this article, we have focused on a detailed quantitative analysis of the effect of different laser powers (1.5, 2.0, 2.5, 3.0, 3.5, and 4.0 kW) on the bead geometry, dilution, microstructure, and hardness. Coatings dilution or composition depends directly on the laser power as well as bead geometry. The typical microstructure of the coatings comprises a solid solution of α (hcp)- and β (fcc)-Co with a dendritic structure as a metal matrix and an interdendritic lamellar eutectic, which contains predominantly β-Co, chromium carbides Cr7C3and Cr23C6as well as blocky tungsten carbide W2C. Coating hardness depends on the chemical composition and microstructure that is modified by the deposition parameters. Low laser power results in high carbide fraction and most refined microstructures, accounting for harder coatings.
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Research context

OpenAlex topics: High Entropy Alloys Studies · Metal Alloys Wear and Properties · High-Temperature Coating Behaviors

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References (71)

Show source-provided references
1. S. Apay and B. Gulenc, Wear Properties of AISI 1015 Steel Coated with Stellite 6 by Microlaser Welding, Mater. Des., 2014, 55, p 1–8. https://doi.org/10.1016/j.matdes.2013.09.05610.1016/j.matdes.2013.09.056 ↗
2. S. Atamert and H. Bhadeshia, Comparison of the Microstructure and Abrasive Wear Properties of Stellite Hardfacing Alloys Deposited by Arc Welding and Laser Cladding, Metall. Trans., 1989, 20, p 1037–1054.10.1007/BF02650140 ↗
3. P. Ganesh, A. Moitra, P. Tiwari, S. Sathyanarayanan, H. Kumar, S. Rai, R. Kaul, C. Paul, R. Prasad, and L. Kukreja, Fracture Behavior of Laser-Clad Joint of Stellite 21 on AISI 316L Stainless Steel, Mater. Sci. Eng., 2010, 527, p 3748–3756. https://doi.org/10.1016/j.msea.2010.03.01710.1016/j.msea.2010.03.017 ↗
4. Š Houdková, Z. Pala, E. Smazalová, M. Vostřák, and Z. Česánek, Microstructure and Sliding Wear Properties of HVOF Sprayed, Laser Remelted and Laser Clad Stellite 6 Coatings, Surf. Coat. Technol., 2017, 318, p 129–141. https://doi.org/10.1016/j.surfcoat.2016.09.01210.1016/j.surfcoat.2016.09.012 ↗
5. Š. Houdková, O. Soukup, M. Prantnerová, Z. Pala, Comparison of HVOF Sprayed and Laser Cladded Stellite 6 Coatings Wear Behaviour (16.-18.06.2014).
6. F. Luo, A. Cockburn, R. Lupoi, M. Sparkes, and W. O’Neill, Performance Comparison of Stellite 6® Deposited on Steel Using Supersonic Laser Deposition and Laser Cladding, Surf. Coat. Technol., 2012, 212, p 119–127. https://doi.org/10.1016/j.surfcoat.2012.09.03110.1016/j.surfcoat.2012.09.031 ↗
7. R. Singh, D. Kumar, S. Mishra, and S. Tiwari, Laser Cladding of Stellite 6 on Stainless Steel to Enhance Solid Particle Erosion and Cavitation Resistance, Surf. Coat. Technol., 2014, 251, p 87–97. https://doi.org/10.1016/j.surfcoat.2014.04.00810.1016/j.surfcoat.2014.04.008 ↗
8. E. Toyserkani, S. Corbin, and A. Khajepour, Laser Cladding, CRC Press, Boca Raton, FL, 2005.
9. Deloro Wear Solutions GmbH, Stellite 6 Alloy: Technical Data.
10. R. Paes and A. Scheid, Effect of Deposition Current on Microstructure and Properties of CoCrWC Alloy PTA Coatings, Soldagem Inspeção, 2014, 19(3), p 247–254. https://doi.org/10.1590/0104-9224/SI1903.0710.1590/0104-9224/SI1903.07 ↗
11. M. Alimardani, V. Fallah, A. Khajepour, and E. Toyserkani, The Effect of Localized Dynamic Surface Preheating in Laser Cladding of Stellite 1, Surf. Coat. Technol., 2010, 204(23), p 3911–3919. https://doi.org/10.1016/j.surfcoat.2010.05.00910.1016/j.surfcoat.2010.05.009 ↗
12. S. Sun, Y. Durandet, and M. Brandt, Parametric Investigation of Pulsed Nd: YAG Laser Cladding of Stellite 6 on Stainless Steel, Surf. Coat. Technol., 2005, 194(2–3), p 225–231. https://doi.org/10.1016/j.surfcoat.2004.03.05810.1016/j.surfcoat.2004.03.058 ↗
13. Y. Cao, S. Zhu, X. Liang, and W. Wang, Overlapping Model of Beads and Curve Fitting of Bead Section for Rapid Manufacturing by Robotic MAG Welding Process, Robot. Comput. Integr. Manuf., 2011, 27(3), p 641–645. https://doi.org/10.1016/j.rcim.2010.11.00210.1016/j.rcim.2010.11.002 ↗
14. S. Suryakumar, K.P. Karunakaran, A. Bernard, U. Chandrasekhar, N. Raghavender, and D. Sharma, Weld Bead Modeling and Process Optimization in Hybrid Layered manufacturing, Comput. Aided Des., 2011, 43(4), p 331–344. https://doi.org/10.1016/j.cad.2011.01.00610.1016/j.cad.2011.01.006 ↗
15. J. Xiong, G. Zhang, H. Gao, and L. Wu, Modeling of Bead Section Profile and Overlapping Beads with Experimental Validation for Robotic GMAW-Based Rapid Manufacturing, Robot. Comput. Integr. Manuf., 2013, 29(2), p 417–423. https://doi.org/10.1016/j.rcim.2012.09.01110.1016/j.rcim.2012.09.011 ↗
16. A. Frenk, N. Henchoz, and W. Kurz, Laser Cladding of a Cobalt-Based Alloy: Processing Parameters and Microstructure, Z. Met., 1993, 84, p 886–892.
17. A. Frenk and W. Kurz, High Speed Laser Cladding: Solidification Conditions and Microstructure of a Cobalt-Based Alloy, Mater. Sci. Eng. A, 1993, 173(1–2), p 339–342. https://doi.org/10.1016/0921-5093(93)90240-F10.1016/0921-5093(93)90240-F ↗
18. Y.P. Kathuria, Some Aspects of Laser Surface Cladding in the Turbine Industry, Surf. Coat. Technol., 2000, 132(2–3), p 262–269. https://doi.org/10.1016/S0257-8972(00)00735-010.1016/S0257-8972(00)00735-0 ↗
19. J.L. de van Mol Otterloo, and J. de Hosson, Microstructural Features and Mechanical Properties of a Cobalt-Based Laser Coating, Acta Mater., 1997, 45(3), p 1225–1236. https://doi.org/10.1016/S1359-6454(96)00250-910.1016/S1359-6454(96)00250-9 ↗
20. M. Zhong, W. Liu, K. Yao, J.-C. Goussain, C. Mayer, and A. Becker, Microstructural Evolution in High Power Laser Cladding of Stellite 6 + WC Layers, Surf. Coat. Technol., 2002, 157(2–3), p 128–137. https://doi.org/10.1016/S0257-8972(02)00165-210.1016/S0257-8972(02)00165-2 ↗
21. A.S.C. D’Oliveira, P.S.C. da Silva, and R.M. Vilar, Microstructural Features of Consecutive Layers of Stellite 6 Deposited by Laser Cladding, Surf. Coat. Technol., 2002, 153(2–3), p 203–209. https://doi.org/10.1016/S0257-8972(01)01687-510.1016/S0257-8972(01)01687-5 ↗
22. R. Paes, D. Martinazzi, T. Falcade, and A. Scheid, Effect of Bead Overlapping on the Microstructure and Mechanical Properties of CoCrWC Alloy Coatings, Mater. Res., 2018, 6, p 157–163. https://doi.org/10.1590/1980-5373-MR-2018-027410.1590/1980-5373-MR-2018-0274 ↗
23. TUPY S.A, Certificado de ensaio: FUCO® FC 300 - Ferro Cinzento Pelítico
24. Bruker Corporation, E-mail correspondence (06.01.2021)10.52314/tjima.2021.v1i1.3 ↗
25. ASTM, Standard Test Methods for Determining Average Grain Size, 2013. https://doi.org/10.1520/E0112-1210.1520/E0112-12 ↗
26. Deutsches Institut für Normung e. V., Metallic Materials: Brinell Hardness Test—Part 1: Test Method (02.2015)
27. DIN Deutsches Institut für Normung e. V., Metallic Materials: Conversion of Hardness Values (02.2014)
28. Deutsches Institut für Normung e. V., Metallic Materials: Vickers Hardness Test—Part 1: Test Method (07.2018)
29. B. Haldar and P. Saha, Identifying Defects and Problems in Laser Cladding and Suggestions of Some Remedies for the Same, Mater. Today Proc., 2018, 5(5), p 13090–13101. https://doi.org/10.1016/j.matpr.2018.02.29710.1016/j.matpr.2018.02.297 ↗
30. V. Ocelík, U. Oliveira, M. Boer, and J. Hosson, Thick Co-Based Coating on Cast Iron by Side Laser Cladding: Analysis of Processing Conditions and Coating Properties, Surf. Coat. Technol., 2007, 201(12), p 5875–5883. https://doi.org/10.1016/j.surfcoat.2006.10.04410.1016/j.surfcoat.2006.10.044 ↗
31. H. El-Cheikh, B. Courant, S. Branchu, J.-Y. Hascoët, and R. Guillén, Analysis and Prediction of Single Laser Tracks Geometrical Characteristics in Coaxial Laser Cladding Process, Opt. Lasers Eng., 2012, 50, p 413–422. https://doi.org/10.1016/j.optlaseng.2011.10.01410.1016/j.optlaseng.2011.10.014 ↗
32. T. Abioye, D. McCartney, and A. Clare, Laser cladding of Inconel 625 wire for corrosion protection, J. Mater. Process. Technol., 2015, 217, p 232–240. https://doi.org/10.1016/j.jmatprotec.2014.10.02410.1016/j.jmatprotec.2014.10.024 ↗
33. F. Arias-González, J. del Val, R. Comesaña, J. Penide, F. Lusquiños, F. Quintero, A. Riveiro, M. Boutinguiza and J. Pou, Fiber Laser Cladding of Nickel-Based Alloy on Cast Iron, Appl. Surf. Sci., 2016, 374, p 197–205. https://doi.org/10.1016/j.apsusc.2015.11.02310.1016/j.apsusc.2015.11.023 ↗
34. O. Nenadl, V. Ocelík, A. Palavra, and J. Hosson, The Prediction of Coating Geometry from Main Processing Parameters in Laser Cladding, Phys. Procedia, 2014, 56, p 220–227. https://doi.org/10.1016/j.phpro.2014.08.16610.1016/j.phpro.2014.08.166 ↗
35. A. Pinkerton, Advances in the Modeling of Laser Direct Metal Deposition, J. Laser Appl., 2015, 27(S1), p 1–8. https://doi.org/10.2351/1.481599210.2351/1.4815992 ↗
36. U. Oliveira, V. Ocelík, and J. Hosson, Analysis of Coaxial Laser Cladding Processing Conditions, Surf. Coat. Technol., 2005, 197(2–3), p 127–136. https://doi.org/10.1016/j.surfcoat.2004.06.02910.1016/j.surfcoat.2004.06.029 ↗
37. K. Bobzin, Oberflächentechnik für den Maschinenbau, Wiley, Hoboken, 2013. (in German)
38. W.C. Lin and C. Chen, Characteristics of Thin Surface Layers of Cobalt-Based Alloys Deposited by Laser Cladding, Surf. Coat. Technol., 2006, 200(14–15), p 4557–4563.10.1016/j.surfcoat.2005.03.033 ↗
39. E. Hug, C. Keller, P.-A. Dubos, and M.M. Celis, Size Effects in Cobalt Plastically Strained in Tension: Impact on Gliding and Twinning Work Hardening Mechanisms, J. Mater. Res., 2021, 11, p 1362–1377. https://doi.org/10.1016/j.jmrt.2021.01.10510.1016/j.jmrt.2021.01.105 ↗
40. M. Lachowicz, K. Haimann, W. Dudzinski, M. Morawska-Sołtysik, ARCHIVES 10/3 Characteristic of Intermetallic Phases in Cast Dental CoCrMo Alloy, Archives of Foundry Engineering 10.
41. S.M. Gaytan, L.E. Murr, D.A. Ramirez, B.I. Machado, E. Martinez, D.H. Hernandez, J.L. Martinez, F. Medina, and R.B. Wicker, A TEM Study of Cobalt-Base Alloy Prototypes Fabricated by EBM, Mater. Sci. Appl., 2011, 2(5), p 355–363. https://doi.org/10.4236/msa.2011.2504610.4236/msa.2011.25046 ↗
42. L. Rémy and A. Pineau, Twinning and Strain-Induced f.c.c. → h.c.p. Transformation on the Mechanical Properties of CoNiCrMo Alloys, Mater. Sci. Eng., 1976, 26(1), p 123–132. https://doi.org/10.1016/0025-5416(76)90234-210.1016/0025-5416(76)90234-2 ↗
43. X. Wu, N. Tao, Y. Hong, G. Liu, B. Xu, J. Lu, and K. Lu, Strain-Induced Grain Refinement of Cobalt During Surface Mechanical Attrition Treatment, Acta Mater., 2005, 53(3), p 681–691. https://doi.org/10.1016/j.actamat.2004.10.02110.1016/j.actamat.2004.10.021 ↗
44. P. Chowdhury, H. Sehitoglu, W. Abuzaid, and H.J. Maier, Mechanical Response of Low Stacking Fault Energy CoNi Alloys—Continuum, Mesoscopic and Atomic Level Treatments, Int. J. Plast., 2015, 71, p 32–61. https://doi.org/10.1016/j.ijplas.2015.04.00310.1016/j.ijplas.2015.04.003 ↗
45. A. Gholipour, M. Shamanian, and F. Ashrafizadeh, Microstructure and Wear Behavior of Stellite 6 Cladding on 17–4 PH Stainless Steel, J. Alloys Compd., 2011, 509(14), p 4905–4909. https://doi.org/10.1016/j.jallcom.2010.09.21610.1016/j.jallcom.2010.09.216 ↗
46. F. Rosalbino and G. Scavino, Corrosion Behaviour Assessment of Cast and HIPed Stellite 6 Alloy in a Chloride-Containing Environment, Electrochim. Acta, 2013, 111, p 656–662. https://doi.org/10.1016/j.electacta.2013.08.01910.1016/j.electacta.2013.08.019 ↗
47. B. Venkatesh, K. Sriker, and V. Prabhakar, Wear Characteristics of Hardfacing Alloys: State-of-the-art, Procedia Mater. Sci., 2015, 10, p 527–532. https://doi.org/10.1016/j.mspro.2015.06.00210.1016/j.mspro.2015.06.002 ↗
48. J. Sort, S. Suriñach, J.S. Muñoz, M.D. Baró, M. Wojcik, E. Jedryka, S. Nadolski, N. Sheludko, and J. Nogués, Role of Stacking Faults in the Structural and Magnetic Properties of Ball-Milled Cobalt, Phys. Rev. B, 2003, 68, p 1. https://doi.org/10.1103/PhysRevB.68.01442110.1103/PhysRevB.68.014421 ↗
49. E. Abouda, M. Dal, P. Aubry, T. Tarfa, I. Demirci, C. Gorny, and T. Malot, Effect of Laser Cladding Parameters on the Microstructure and Properties of High Chromium Hardfacing Alloys, Phys. Procedia, 2016, 83, p 684–696. https://doi.org/10.1016/j.phpro.2016.08.07010.1016/j.phpro.2016.08.070 ↗
50. T. Antoszczyszyn, R. Paes, A. Oliveira, and A. Scheid, Impact of Dilution on the Microstructure and Properties of Ni-Based 625 Alloy Coatings, Soldagem Inspeção, 2014, 19(2), p 134–144. https://doi.org/10.1590/0104-9224/SI1902.0510.1590/0104-9224/SI1902.05 ↗
51. J. De Hosson and J. De Mol Van Otterloo, Microstructural Features and Mechanical Properties of a Cobalt-Based Laser Coating, Acta Mater., 1997, 45(3), p 1225–1236.10.1016/S1359-6454(96)00250-9 ↗
52. M. Ferozhkhan, M. Duraiselvam, K. Kumar, and R. Ravibharath, Plasma Transferred Arc Welding of Stellite 6 Alloy on Stainless Steel for Wear Resistance, Procedia Technol., 2016, 25, p 1305–1311. https://doi.org/10.1016/j.protcy.2016.08.22610.1016/j.protcy.2016.08.226 ↗
53. A. d’Oliveiraa, P. da Silvaa, and R. Vilarc, Microstructural Features of Consecutive Layers of Stellite 6 Deposited by Laser Cladding, Surf. Coat. Technol., 2002, 153, p 203–209.10.1016/S0257-8972(01)01687-5 ↗
54. D. Karmakar, M. Gopinath, S. Harmalkar, and A. Nath, Investigation of Wear and Corrosion Characteristics of Stellite-6 and Stellite-21 Layers Deposited by Co-axial Laser Cladding, Proceedings of the ASME 2017 12th International Manufacturing Science and Engineering Conference, ASME, 2017, p 1–6
55. A. Kusmoko, D. Dunne, H. Li, and D. Nolan, Effect of Two Different Energy Inputs for Laser Cladding of Stellite 6 on P91 and P22 Steel Substrates, Procedia Mater. Sci., 2014, 6, p 26–36. https://doi.org/10.1016/j.mspro.2014.07.00510.1016/j.mspro.2014.07.005 ↗
56. A. Farnia, F. Malek Ghaini, V. Ocelík, and J. Hosson, Microstructural Characterization of Co-based Coating Deposited by Low Power Pulse Laser Cladding, J. Mater. Sci., 2013, 48(6), p 2714–2723. https://doi.org/10.1007/s10853-012-7069-810.1007/s10853-012-7069-8 ↗
57. A. Kusmoko, D. Dunne, and H. Li, Effect of Heat Input on Stellite 6 Coatings on a Medium Carbon Steel Substrate by Laser Cladding, Mater. Today Proc., 2015, 2, p 1747–1754. https://doi.org/10.1016/j.matpr.2015.07.01010.1016/j.matpr.2015.07.010 ↗
58. A. Kumar and S. Roy, Effect of Three-Dimensional Melt Pool Convection on Process Characteristics During Laser Cladding, Comput. Mater. Sci., 2009, 46(2), p 495–506. https://doi.org/10.1016/j.commatsci.2009.04.00210.1016/j.commatsci.2009.04.002 ↗
59. G. Schulze, Die Metallurgie des Schweissens: Eisenwerkstoffe - nichteisenmetallische Werkstoffe, 4th ed. VDI-Buch, Springer, Heidelberg, 2010. (in German)10.1007/978-3-642-03183-0 ↗
60. J.-M. Jouvard, D. Grevey, F. Lemoine, and A. Vannes, Continuous Wave Nd:YAG Laser Cladding Modeling: A Physical Study of Track Creation During Low Power Processing, J. Laser Appl., 1997, 9, p 43–50.10.2351/1.4745444 ↗
61. D.M. Goodarzi, J. Pekkarinen, and A. Salminen, Effect of Process Parameters in Laser Cladding on Substrate Melted Areas and the Substrate Melted Shape, J. Laser Appl., 2015, 27(S2), p S29201. https://doi.org/10.2351/1.490637610.2351/1.4906376 ↗
62. S. Wen, Y. Shin, J. Murthy, and P. Sojka, Modeling of Coaxial Powder Flow for the Laser Direct Deposition Process, Int. J. Heat Mass Transf., 2009, 52(25–26), p 5867–5877. https://doi.org/10.1016/j.ijheatmasstransfer.2009.07.01810.1016/j.ijheatmasstransfer.2009.07.018 ↗
63. R. Jendrzejewski, G. Śliwiński, M. Krawczuk, and W. Ostachowicz, Temperature and Stress Fields Induced During Laser Cladding, Comput. Struct., 2004, 82(7–8), p 653–658. https://doi.org/10.1016/j.compstruc.2003.11.00510.1016/j.compstruc.2003.11.005 ↗
64. W. Betteridge, Cobalt and Its Alloys, Horwood and Wiley, Chichester, 1982.
65. A. Karl, P. Schaaf, J. Bergmann, and A. Dwars, Laserauftragschweißen hochlegierter Duplexstähle, Vol. 10 of Werkstofftechnik aktuell, Univ.- Bibliothek and Univ.-Verl. Ilmenau, Ilmenau, 2014. (in German)
66. J. Lippold, Welding Metallurgy and Weldability, Wiley, Hoboken, 2015. https://doi.org/10.1002/978111896033210.1002/9781118960332 ↗
67. P. Sahm Ed., Schmelze, Erstarrung, Grenzflächen: Eine Einführung in die Physik und Technologie flüssiger und fester Metalle, Vieweg, Braunschweig, 1999 (in German)
68. A. Frenk and W. Kurz, Microstructural Effects on the Sliding Wear Resistance of a Cobalt-Based Alloy, Wear, 1994, 174, p 81–91.10.1016/0043-1648(94)90089-2 ↗
69. H. Berns Ed., Hartlegierungen und Hartverbundwerkstoffe: Gefüge, Eigenschaften, Bearbeitung, Anwendungen, Springer, Berlin, 1998 (in German)
70. H. Kleykamp, Thermodynamic Studies on Chromium Carbides by the Electromotive Force (emf) Method, J. Alloys Compd., 2001, 321(1), p 138–145. https://doi.org/10.1016/S0925-8388(01)01012-X10.1016/S0925-8388(01)01012-X ↗
71. S. Du Sichen and L.-I. Sheetharaman, Staffansson, Standard Gibbs Energies of Formation of the Carbides of Chromium by emf Measurements, Metall. Mater. Trans. B, 1989, 20(6), p 911–917. https://doi.org/10.1007/BF0267019610.1007/BF02670196 ↗