journal article·2018-06

Synthesis of Flexible Graphene/Polymer Composites for Supercapacitor Applications

Himangshu Pal, Shuvam Bhubna, Praduman Kumar, Rajat Mahapatra, Somenath Chatterjee

Publisher page

Abstract

In this paper, the graphene was synthesized using biocompatible cellulosic component from onions. Onion epidermal cells were chosen as raw material. During heating at high temperature, the bonding among atoms in material was rearranged and forms two-dimensional hexagonal carbon layer (graphene). The characterization of synthesized graphene was done by x-ray diffractometer, Raman spectrometer and field emission scanning electron microscopy, respectively. An attempt has been taken to form the capacitors with two different current collector electrodes, anticipating the performance of the supercapacitors. The observed capacitance values as-obtained for Al and Au current collector were 1.3 μF and 6.08 μF, respectively. However, when thermally exfoliated graphene was used as an electrode on Al and Au current collector, the capacitance value was drastically increased and found to be 1.6 and 41.25 μF, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Graphene research and applications · Graphene and Nanomaterials Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (18)

Show source-provided references
1. H. Zhao, Q. Wu, S. Hu, H. Xu, and C.N. Rasmussen, Review of Energy Storage System for Wind Power Integration Support, Appl. Energy, 2015, 137, p 545–55310.1016/j.apenergy.2014.04.103 ↗
2. Y. Shao, M.F. El-Kady, L.J. Wang, Q. Zhang, Y. Li, H. Wang, M.F. Mousavi, and R.B. Kaner, Graphene-Based Materials for Flexible Supercapacitors, Chem. Soc. Rev., 2015, 44(11), p 3639–366510.1039/C4CS00316K ↗
3. B.E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Plenum Publishers, New York, 199910.1007/978-1-4757-3058-6 ↗
4. P. Simon and Y. Gogotsi, Materials for Electrochemical Capacitors, Nat. Mater., 2008, 7, p 845–85410.1038/nmat2297 ↗
5. R. Kotz and M. Carlen, Principles and Applications of Electrochemical Capacitors, Electrochim. Acta, 2000, 45, p 2483–249810.1016/S0013-4686(00)00354-6 ↗
6. A. Burke, Ultracapacitors: Why, How, and Where is the Technology, J. Power Sources, 2000, 91, p 37–5010.1016/S0378-7753(00)00485-7 ↗
7. A.K. Geim, Graphene: Status and Prospects, Science, 2009, 324, p 1530–153410.1126/science.1158877 ↗
8. A.K. Geim and K.S. Novoselov, The Rise of Graphene, Nat. Mater., 2007, 6, p 183–19110.1038/nmat1849 ↗
9. A.H. Castro Neto, F. Guinea, N.M.R. Peres, K.S. Novoselov, and A.K. Geim, Rev. Mod. Phys., 2009, 81, p 109–16210.1103/RevModPhys.81.109 ↗
10. S. Das Sarma, A.K. Geim, P. Kim, and A.H. MacDonald, Special Edition: Exploring Graphene—Recent Research Advances, Solid State Commun., 2012, 152, p 1275–150810.1016/j.ssc.2012.07.011 ↗
11. K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, and A.A. Firsov, Electric Field Effect in Atomically Thin Carbon Films, Science, 2004, 306, p 666–66910.1126/science.1102896 ↗
12. W. Ma, S. Chen, S. Yang, W. Chen, W. Weng, Y. Cheng, and M. Zhu, Flexible All-Solid-State Asymmetric Supercapacitor Based on Transition Metal Oxide Nanorods/Reduced Graphene Oxide Hybrid Fibres with High Energy Density, Carbon, 2017, 113, p 151–15810.1016/j.carbon.2016.11.051 ↗
13. C. Zhong, Y. Deng, W. Hu, J. Qiao, L. Zhang, and J. Zhang, A Review of Electrolyte Materials and Compositions for Electrochemical Supercapacitors, Chem. Soc. Rev., 2015, 44, p 7484–753910.1039/C5CS00303B ↗
14. A.K. Ray, S. Chatterjee, J.K. Singh, and H. Bapari, Thermal Exfoliation of Natural Cellulosic Material for Graphene Synthesis, J. Mater. Eng. Perform., 2015, 24, p 80–8410.1007/s11665-014-1224-0 ↗
15. A.K. Ray, R.K. Sahu, V. Rajinikanth, H. Bapari, M. Ghosh, and P. Paul, Preparation and Characterization of Graphene and Ni-Decorated Graphene Using Flower Petals as the Precursor Material, Carbon, 2012, 50(11), p 4123–412910.1016/j.carbon.2012.04.060 ↗
16. Y. Yang, B. Li, C. Zhang, S. Wang, K. Liu, and B. Yang, Fabrication and Properties of Graphene Reinforced Silicon Nitride Composite Materials, Mater. Sci. Eng. A, 2015, 644, p 90–9510.1016/j.msea.2015.07.062 ↗
17. Y.-Q. Dang, S.-Z. Ren, G. Liu, J. Cai, Y. Zhang, and J. Qiu, Electrochemical and Capacitive Properties of Carbon Dots/Reduced Graphene Oxide Supercapacitors, Nanomaterials, 2016, 6(11), p 21210.3390/nano6110212 ↗
18. L. Chen, Y. Tang, K. Wang, C. Liu, and S. Luo, Direct Electro deposition of Reduced Graphene Oxide on Glassy Carbon Electrode and Its Electrochemical Application, Electrochem. Commun., 2011, 13(2), p 133–13710.1016/j.elecom.2010.11.033 ↗