journal article·2023-11

Influence of Manganese Content on Microstructure, Mechanical Properties and High Temperature Oxidation Resistance of Reduced Activation Ferritic/Martensitic Steels

Wen Zeng, Ming Zhou, Mei Yang, Risheng Qiu, Xinu Tan, Anruo Zhou, Xianfu Luo

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Abstract

The effect of the manganese content (0.5-2.0 wt.%) on the microstructure, mechanical properties and high temperature oxidation resistance of reduced activation ferritic/martensitic (RAFM) steels was studied. The examinations reveal that the microstructure of the steels shows a fully martensite structure. A large number of M23C6 carbides and a small number of Zr(C, N) carbonitrides were detected in the steels. The results of mechanical experiments showed that the strength increases and the toughness decreases with increasing Mn content. The improvement of strength can be ascribed to solution strengthening by Mn and gain size strengthening by refining lath width. After oxidation at 650 °C for 400 h, both MnCr2O4 oxides and Cr2O3 oxides are founded on the surface of the steels. The steel with 1.2 wt.% Mn exhibit the optimum high temperature oxidation resistance, followed by the steel with 0.5 wt.% Mn. The increase of oxidation resistance can be ascribed to the addition of Mn promotes the formation of Mn oxides, which refined the diameter of MnCr2O4 oxides. The decrease of oxidation resistance mainly due to the higher Mn content reduces the critical concentration of Cr to form Cr oxides (Cr2O3), thus promoting the formation of large-sized Cr2O3 oxides.
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OpenAlex topics: High-Temperature Coating Behaviors · Fusion materials and technologies · Metal and Thin Film Mechanics

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References (39)

Show source-provided references
1. D. Buckthorpe, (2017) Chapter 1-Introduction to Generation IV nuclear reactors, Structural Materials for Generation IV Nuclear Reactorsed., P. Yvon, (Ed.), Woodhead Publishing, Cambridge 1–2210.1016/B978-0-08-100906-2.00001-X ↗
2. Q. Huang, X. Wang, S. Sun, Y. Liu, H. Liao, P. Zheng, L. Peng, and Y. Zhai, Development of Reduced Activation Ferritic/Martensitic Steels in China, J. Nucl. Mater., 2022, 568, p 153887.10.1016/j.jnucmat.2022.153887 ↗
3. Y. Shen, H. Liu, Z. Shang, and Z. Xu, Precipitate Phases in Normalized and Tempered Ferritic/Martensitic Steel P92, J. Nucl. Mater., 2015, 465, p 373–382.10.1016/j.jnucmat.2015.05.043 ↗
4. Y. Shen, X. Zhou, X. Huang, Z. Fan, X. Ma, H. Chen, and X. Shi, Identification of Precipitate Phases in CLAM Steel, Fusion Eng. Des., 2021, 163, p 112168.10.1016/j.fusengdes.2020.112168 ↗
5. Y.Z. Shen, S.H. Kim, H.D. Cho, C.H. Han, and W.S. Ryu, Precipitates in Normalized and Tempered 10%Cr Ferritic/Martensitic Steels, J. Nucl. Mater., 2012, 430(1–3), p 264–269.10.1016/j.jnucmat.2012.07.016 ↗
6. S. Ge, B. Niu, Z. Wang, Q. Pan, C. Liu, and Q. Wang, Microstructural Stability and Mechanical Property of a Medium-Si 12%Cr Reduced Activation Ferritic/Martensitic Steel at High Temperatures, J. Mater. Eng. Perform., 2022, 31(7), p 5697–5705.10.1007/s11665-022-06675-x ↗
7. Q. Min, Q. Guo-xing, C. Ming-chong, D. Qing, C. Lei, and W. Hong-yan, Microstructure Stability and Mechanical Properties of Reduced Activated Ferritic Martensitic Steel during Thermal Aging at 550 °C for 5000 h, J. Mater. Eng. Perform, 2022 https://doi.org/10.1007/s11665-022-07498-610.1007/s11665-022-07498-6 ↗
8. L. Zhao, X. Chen, T. Wu, and Q. Zhai, Study on Strengthening Mechanism of 9Cr-1.5Mo-1Co and 9Cr-3W-3Co Heat Resistant Steels, Materials, 2020, 13(19), p 4340.10.3390/ma13194340 ↗
9. J.H. Zhou, Y.F. Shen, and N. Jia, Strengthening Mechanisms of Reduced Activation Ferritic/Martensitic Steels—A Review, Int. J. Miner. Metall. Mater., 2021, 28(3), p 335–348.10.1007/s12613-020-2121-1 ↗
10. S.F. Yang, M.J. Zhao, J. Feng, J.S. Li, and C.S. Liu, Induced-Pitting Behaviors of MnS Inclusions in Steel, High Temp. Mater. Proc., 2018, 37(9–10), p 1007–1016.10.1515/htmp-2017-0155 ↗
11. H. Yu, M. Li, J. Zhang, and D. Yang, Effect of Mn Content on the Reaction between Fe-xMn (x = 5, 10, 15, and 20 Mass pct) Steel and CaO-SiO2-Al2O3-MgO Slag, Metals, 2021, 11(8), p 1200.10.3390/met11081200 ↗
12. C.L. Zhang, H.G. Fu, S.Q. Ma, D.W. Yi, J. Lin, Z.G. Xing, and Y.P. Lei, Effect of Mn Content on Microstructure and Properties of Wear-Resistant Bainitic Steel, Mater. Res. Exp., 2019, 6(8), p 086581.10.1088/2053-1591/ab1c8d ↗
13. T. Zhao, F. Wang, C. Chen, H. Ma, Z.A. Yang, F.C. Zhang, and T.B. Tang, Effect of Mn Content and Strain Rate on Mechanical Properties of High-C High-Mn Austenitic Steel, Mater. Sci. Eng. A., 2022, 851, p 143653.10.1016/j.msea.2022.143653 ↗
14. M. Schulte, S. Steentjes, N. Leuning, W. Bleck, and K. Hameyer, Effect of Manganese in High Silicon Alloyed Non-Oriented Electrical Steel Sheets, J. Magn. Magn. Mater., 2019, 477, p 372–381.10.1016/j.jmmm.2018.07.025 ↗
15. J.B. Li, X.Y. Xiong, Q. Shen, Q.K. Zhai, and W.Q. Liu, Effect of Mn on precipitation behaviour of NiAl phase in Fe-NiAl steels, Mater. Sci. Technol., 2020, 36(7), p 852–857.10.1080/02670836.2020.1745410 ↗
16. Q. Shen, X.J. Wang, A.Y. Zhao, Y.F. He, X.L. Fang, J.R. Ma, and W.Q. Liu, Effects of Mn on Multi-Precipitates Evolution of Cu-Rich and Nial Phase in Steels, Acta Metall. Sin., 2016, 52(5), p 513–518.
17. J. Oñoro, Martensite Microstructure of 9–12%Cr Steels Weld Metals, J. Mater. Process. Technol., 2006, 180, p 137–142.10.1016/j.jmatprotec.2006.05.014 ↗
18. P. Hu, W. Yan, L.-F. Deng, W. Sha, Y. Shan, and K. Yang, Nitride-Strengthened Reduced Activation Ferritic/Martensitic Steels, Fusion Eng. Des., 2010, 85, p 1632–1637.10.1016/j.fusengdes.2010.04.066 ↗
19. C.-H. Lee, J. Moon, M.-G. Park, T.-H. Lee, M.-H. Jang, H.C. Kim, and D.-W. Suh, Effect of Constituent Phase on Mechanical Properties of 9Cr–1WVTa Reduced Activation Ferritic–Martensitic Steels, J. Nucl. Mater., 2014, 455(1), p 421–425.10.1016/j.jnucmat.2014.07.047 ↗
20. W. Zeng, M. Zhou, M. Yang, and R. Qiu, Effect of Zr on the Microstructure and Mechanical Properties of 12Cr Ferritic/Martensitic Steels, Fusion Eng. Des., 2022, 177, p 113084.10.1016/j.fusengdes.2022.113084 ↗
21. J. Wang, K. Zhu, J. Zhou, and X. Lu, Effects of Peak Temperatures and Cooling Rates on Delta Ferrite Formation and Mechanical Properties for Heat Affected Zones in 9Cr-RAFM Steel, Int. J. Press. Vessel Pip., 2021, 192, p 104399.10.1016/j.ijpvp.2021.104399 ↗
22. Z. Shang, Y. Shen, B. Ji, and L. Zhang, Effect of δ-Ferrite Evolution and High-Temperature Annealing on Mechanical Properties of 11Cr3W3Co Ferritic/Martensitic Steel, Met. Mater. Int., 2016, 22(2), p 171–180.10.1007/s12540-016-5485-z ↗
23. W.C. Zhong, Y. Yang, K.G. Field, N. Sridharan, K. Terrani, and L.Z. Tan, Microstructure and Mechanical Properties of High Mn-Containing Ferritic-Martensitic Alloys Exposed to Cyclical Thermal Treatment, Mater. Sci. Eng. A., 2021, 813, p 141143.10.1016/j.msea.2021.141143 ↗
24. S. Chen, X. Jin, and L. Rong, Improvement in High Temperature Oxidation Resistance of 9%Cr Ferritic–Martensitic Steel by Enhanced Diffusion of Mn, Oxid. Met., 2016, 85(1), p 189–203.10.1007/s11085-015-9596-6 ↗
25. S.H. Chen, and L.J. Rong, Roles of Mn in the High-Temperature Air Oxidation of 9Cr Ferritic-Martensitic Steel After Severe Plastic Deformation, Oxid. Met., 2018, 89(3–4), p 415–428.10.1007/s11085-017-9796-3 ↗
26. X. Jin, S. Chen, and L. Rong, Effects of Mn on the Mechanical Properties and High Temperature Oxidation of 9Cr2WVTa Steel, J. Nucl. Mater., 2017, 494, p 103–113.10.1016/j.jnucmat.2017.07.024 ↗
27. Z. Dong, M. Li, Y. Behnamian, J.-L. Luo, W. Chen, B.S. Amirkhiz, P. Liu, X. Pang, J. Li, W. Zheng, D. Guzonas, and C. Xia, Effects of Si, Mn on the Corrosion Behavior of Ferritic–Martensitic Steels in Supercritical Water (SCW) Environments, Corros. Sci., 2020, 166, p 108432.10.1016/j.corsci.2020.108432 ↗
28. J. Gong, H. Liao, K. Zhang, and X. Wang, Heat Treatment Optimization of China Low-Activation Ferritic/Martensitic Steel with Cerium Addition, Fusion Eng. Des., 2020, 158, p 111696.10.1016/j.fusengdes.2020.111696 ↗
29. L. Yang, F. Zhao, and W. Ding, Laves Phase Evolution in China Low-Activation Martensitic (CLAM) Steel during Long-Term Aging at 550 °C, Materials., 2019, 13, p 154.10.3390/ma13010154 ↗
30. H.K. Danielsen, Review of Z Phase Precipitation in 9–12 wt.-%Cr Steels, Mater. Sci. Technol., 2016, 32(2), p 126–137.10.1179/1743284715Y.0000000066 ↗
31. L. Cipolla, H.K. Danielsen, D. Venditti, P.E. Di Nunzio, J. Hald, and M.A.J. Somers, Conversion of MX Nitrides to Z-Phase in a Martensitic 12% Cr Steel, Acta Mater., 2010, 58(2), p 669–679.10.1016/j.actamat.2009.09.045 ↗
32. Y. Shen, X. Zhou, T. Shi, X. Huang, Z. Shang, W. Liu, B. Ji, and Z. Xu, Sigma Phases in an 11%Cr Ferritic/Martensitic Steel with the Normalized and Tempered Condition, Mater. Charact., 2016, 122, p 113–123.10.1016/j.matchar.2016.10.031 ↗
33. T.N. Baker, Role of Zirconium in Microalloyed Steels: A Review, Mater. Sci. Technol., 2015, 31(3), p 265–294.10.1179/1743284714Y.0000000549 ↗
34. C. Qiu, H.S. Zurob, and C.R. Hutchinson, The Coupled Solute Drag Effect During Ferrite Growth in Fe-C-Mn-Si Alloys Using Controlled Decarburization, Acta Mater., 2015, 100, p 333–343.10.1016/j.actamat.2015.08.065 ↗
35. V.K. Devra and J. Maity, Solute Drag Effect on Austenite Grain Growth in Hypoeutectoid Steel, Philos. Mag. Lett., 2020, 100(6), p 245–259.10.1080/09500839.2020.1750723 ↗
36. H. Bhadeshia and R. Honeycombe, Chapter 15-Modelling of Structure and Properties, Steels: Microstructure and Properties (Fourth Edition) ed., H. Bhadeshia, R. Honeycombe. Butterworth-Heinemann, Oxford 421–455 (2017)10.1016/B978-0-08-100270-4.00015-9 ↗
37. M. Song, C. Sun, Z. Fan, Y. Chen, R. Zhu, K.Y. Yu, K.T. Hartwig, H. Wang, and X. Zhang, A Roadmap for Tailoring the Strength and Ductility of Ferritic/Martensitic T91 Steel Via Thermo-Mechanical Treatment, Acta Mater., 2016, 112, p 361–377.10.1016/j.actamat.2016.04.031 ↗
38. J.T. Ju, Y. Wang, F. Hao, Y.X. Du, W. Jiang, and F. Sun, Effect of Silicon on Mechanical Properties of Ti-6AI-2Zr-1Mo-1V Alloy, Rare Met. Mater. Eng., 2019, 48, p 1749–1755.
39. L. Zhang, W. Yan, Q. Shi, Y. Li, Y. Shan, and K. Yang, Silicon Enhances High Temperature Oxidation Resistance of SIMP Steel at 700 °C, Corros. Sci., 2020, 167, p 108519.10.1016/j.corsci.2020.108519 ↗