journal article·2022-04

New Insights to Understand the Influence of Nb/Mo on Hydrogen Embrittlement Resistance of Warm-Rolled Medium-Mn Steels

Haijun Pan, Xinyu Li, Bo Qiao, Yi Zhang, Naiming Miao, Lin Liu, Hua Ding, Minghui Cai

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Abstract

This work elucidated the influence of Nb/Mo on the hydrogen embrittlement (HE) resistance of medium Mn steels (MMS) through an electrochemical cathodic charging method, slow rate tensile tests and microstructure characterization. According to the experimental results, the influences of Nb/Mo on HE resistance could be described as follows: (1) Nb/Mo addition could decrease the mean grain size of MMS up to 0.24 μm, which would decrease the hydrogen content per unit area by supporting more grain boundaries; (2) Nb/Mo addition could produce lots of precipitates, which could act as potential stable hydrogen trapping sites; (3) Nb/Mo addition decreased the diffusible hydrogen contents from 3.6 to 2.2 ppm and effective hydrogen diffusion coefficient from 5.6×10-10 to 2.9×10-10 m2/s;(4) Nb/Mo addition could increase austenite stability, and decrease transformed austenite fraction. Compared with single Nb addition, multiple Nb-Mo addition could further decrease the mean grain size and precipitate size, increase precipitate density and enhance grain boundary cohesion. Therefore, the Nb-Mo bearing MMS has a good HE resistance.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Microstructure and Mechanical Properties of Steels · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. B.B. He, B. Hu, H.W. Yen, G.J. Cheng, Z.K. Wang, H.W. Luo and M.X. Huang, High Dislocation Density-Induced Large Ductility in Deformed and Partitioned Steels, Science, 2017, 357, p 1029–1032.10.1126/science.aan0177 ↗
2. H.J. Pan, P. Jiang, Y. Zhang, W.P. Wu, Z.Z. Wang, Q. Wang and H.Y. Li, Microstructure Evolution and Enhanced Mechanical Properties of a Nb-Mo Microalloyed Medium Mn Alloy Fabricated by a Novel Cyclic Quenching Treatment, Mater. Sci. Eng. A, 2020, 797, p 140076.10.1016/j.msea.2020.140076 ↗
3. W. Bleck, F. Brühl, Y. Ma and C. Sasse, Materials and Processes for the Third-Generation Advanced High-Strength Steels, BHM, 2019, 164, p 466–474.
4. H.J. Pan, P. Jiang, Y. Zhang, W.P. Wu, Z.Z. Wang, Q. Wang and H.Y. Li, Microstructure and Mechanical Properties of a Novel Nb-Mo Bearing Medium-Mn Alloy Affected by intercritical Annealing and Tempering, Mater. Sci. Eng. A, 2021, 802, p 140680.10.1016/j.msea.2020.140680 ↗
5. B. Hu, H.W. Luo, F. Yang and H. Dong, Recent Progress in Medium-Mn Steels made with New Designing Strategies, a Review, J. Mater. Sci. Technol., 2017, 33, p 1457–1464.10.1016/j.jmst.2017.06.017 ↗
6. D.K. Matlock, J.G. Speer, E. De Moor and P.J. Gibbs, Recent Developments in Advanced High Strength Sheet Steels for Automotive Applications: An Overview, JESTECH, 2012, 15, p 1–12.
7. X.L. Zhao, Y.J. Zhang, W.J. Hui, C.W. Shao, C.Y. Wang and H. Dong, The Potential Significance of Tempering Treatment in Alleviating the Hydrogen Embrittlement Susceptibility of a Hot-Rolled and Intercritically Annealed Medium-Mn Steel, Eng. Fail. Anal., 2021, 119, p 104969.10.1016/j.engfailanal.2020.104969 ↗
8. P.W. Zhou, W. Li, H.S. Zhao and X.J. Jin, Role of Microstructure on Electrochemical Hydrogen Permeation Properties In Advanced High Strength Steels, Int. J. Hydrogen Energy, 2018, 43, p 10905–10914.10.1016/j.ijhydene.2018.04.241 ↗
9. Q.L. Liu, Q.J. Zhou, J. Venezuela, M.X. Zhang and A. Atrens, The Role of the Microstructure on the Influence of Hydrogen on Some Advanced High-Strength Steels, Mater. Sci. Eng. A, 2018, 715, p 370–378.10.1016/j.msea.2017.12.079 ↗
10. T.M. Park, H.J. Kim, H.Y. Um, N.H. Goo and J. Han, The Possibility of Enhanced Hydrogen Embrittlement Resistance of MediumMN Steels by Addition of Micro-Alloying Elements, Mater. Charact., 2020, 165, p 110386.10.1016/j.matchar.2020.110386 ↗
11. N. Zan, H. Ding, X.F. Guo, Z.Y. Tang and W. Bleck, Effects of Grain Size on Hydrogen Embrittlement in a Fe-22Mn-0.6C TWIP Steel, Int. J. Hydrogen Energy, 2015, 40, p 10687–10696.10.1016/j.ijhydene.2015.06.112 ↗
12. H.K.D.H. Bhadeshia, Prevention of Hydrogen Embrittlement in Steels, ISIJ Int., 2016, 56, p 24–36.10.2355/isijinternational.ISIJINT-2015-430 ↗
13. I.J. Park, S.Y. Jo, M. Kang, S.M. Lee and Y.K. Lee, The Effect of Ti Precipitates on Hydrogen Embrittlement of Fe-18Mn-0.6C-2Al-xTi Twinning-Induced Plasticity Steel, Corros. Sci., 2014, 89, p 38–45.10.1016/j.corsci.2014.08.005 ↗
14. M.C. Jo, J. Yoo, S. Kim, S. Kim, J. Oh, J. Bian, S.S. Sohn and S. Lee, Effects of Nb and Mo Alloying on Resistance to Hydrogen Embrittlement in 1.9 GPa-grade Hot-Stamping Steels, Mater. Sci. Eng. A, 2020, 789, p 139656.10.1016/j.msea.2020.139656 ↗
15. S. Zhang, Y. Huang, B. Sun, Q. Liao, H. Lu, B. Jian, H. Mohrbacher, W. Zhang, A. Guo and Y. Zhang, Effect of Nb on hydrogen-Induced Delayed Fracture in High Strength Hot Stamping Steels, Mater. Sci. Eng. A, 2015, 626, p 136–143.10.1016/j.msea.2014.12.051 ↗
16. N. Winzer, O. Rott, R. Thiessen, I. Thomas, K. Mraczek, T. Hoche, L. Wright and M. Mrovec, Hydrogen Diffusion and Trapping in Ti-Modified Advanced High Strength Steels, Mater. Des., 2016, 92, p 450–461.10.1016/j.matdes.2015.12.060 ↗
17. H. Kim, S. Jeon, W. Yang, B. Yoo, Y. Chung, H. Ha and H. Chung, Effects of Titanium Content on Hydrogen Embrittlement Susceptibility of Hot-Stamped Boron Steels, J. Alloys Compd., 2018, 735, p 2067–2080.10.1016/j.jallcom.2017.12.004 ↗
18. E.J. Song, S.W. Baek, S.H. Nahm and D.W. Suh, Effects of Molybdenum Addition on Hydrogen Desorption of TiC Precipitation-Hardened Steel, Met. Mater. Int., 2018, 24, p 532–536.10.1007/s12540-018-0067-x ↗
19. T.M. Park, H.J. Kim, H.Y. Um, N.H. Goo and J. Han, The Possibility of Enhanced Hydrogen Embrittlement Resistance of Medium Mn Steels by Addition of Micro-Alloying Elements, Mater. Charact., 2020, 165, p 110386.10.1016/j.matchar.2020.110386 ↗
20. H.J. Pan, H. Ding and M.H. Cai, Microstructural Evolution and Precipitation Behavior of the Warm-Rolled Medium Mn Steels Containing Nb or Nb-Mo during Intercritical Annealing, Mater. Sci. Eng. A, 2018, 736, p 375–382.10.1016/j.msea.2018.08.055 ↗
21. N.H.V. Dijk, A.M. Butt, L. Zhao, J. Sietsma, S.E. Offerman, J.P. Wright and S.V.D. Zwaag, Thermal Stability of Retained Austenite in TRIP Steels Studied by Synchrotron X-ray Diffraction during Cooling, Acta Mater., 2005, 53, p 5439–5447.10.1016/j.actamat.2005.08.017 ↗
22. X.Y. Sun, B. Zhang, H.Q. Lin, Y. Zhou, L. Sun, J.Q. Wang, E.H. Han and W. Ke, Correlations between Stress Corrosion Cracking Susceptibility and Grain Boundary Microstructures for an Al-Zn-Mg Alloy, Corros. Sci., 2013, 77, p 103–112.10.1016/j.corsci.2013.07.032 ↗
23. Y.J. Zhang, W.J. Hui, J.J. Wang, M. Lei and X.L. Zhao, Enhancing the Resistance to Hydrogen Embrittlement of Al-Containing Medium-Mn Steel through Heavy Warm Rolling, Scr. Mater., 2019, 165, p 15–19.10.1016/j.scriptamat.2019.02.009 ↗
24. H.J. Pan, H. Ding, M.H. Cai, D. Kibaroglu, Y. Ma and W.W. Song, Precipitation Behavior and Austenite Stability of Nb or Nb-Mo Micro-Alloyed Warm-Rolled Medium-Mn Steels, Mater. Sci. Eng. A, 2019, 766, p 138371.10.1016/j.msea.2019.138371 ↗
25. K. Sugimoto, M. Kobayashi and S. Hashimoto, Ductility and Strain-induced Transformation in a High-Strength Transformation-Induced Plasticity-Aided Dual-Phase Steel, Metall. Mater. Trans. A, 1992, 23, p 3085–3091.10.1007/BF02646127 ↗