Electrochemical Corrosion Behavior of Powder Metallurgy Ti6Al4V Alloy
Source abstract
Abstract
The corrosion behavior of powder metallurgy (PM) Ti6Al4V alloys with different relative densities ranged from 95.2 to 99.5% is investigated in 3.5 wt.% NaCl solution at room temperature by electrochemical methods, including potentiodynamic polarization curves and electrochemical impedance spectroscopy. For comparison, traditional wrought Ti6Al4V alloy with full densification is also investigated. The results show that the corrosion resistance of PM Ti6Al4V alloys increases with the increasing density. All the studied samples exhibit low Ip values (in the order of 10−6 A cm−2), indicating good corrosion resistance under current experimental conditions. Therefore, density effect on the corrosion resistance of PM Ti6Al4V alloys is less significant. It is worth noting that the corrosion resistance and mechanical performance of PM Ti6Al4V alloys with nearly full densification are comparable to those of wrought alloys. Therefore, PM Ti alloys are promising candidates in the marine application.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Titanium Alloys Microstructure and Properties · Hydrogen embrittlement and corrosion behaviors in metals · Metal and Thin Film Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. C.Q. Xia, Z.G. Zhang, Z.H. Feng, B. Pan, X.Y. Zhang, M.Z. Ma, and R.P. Liu, Effect of Zirconium Content on the Microstructure and Corrosion Behavior of Ti-6Al-4 V-xZr Alloys, Corros. Sci., 2016, 112, p 687–69510.1016/j.corsci.2016.09.012 ↗
2. M.F. Erinosho, E.T. Akinlabi, and S. Pityana, Microstructure and Corrosion Behavior of Laser Metal Deposited Ti6Al4 V/Cu Composites in 3.5% Sea Water, Mater. Today Proc., 2015, 2(4–5), p 1166–117410.1016/j.matpr.2015.07.028 ↗
3. L. Bolzoni, E. Herraiz, E.M. Ruiz-Navas, and E. Gordo, Study of the Properties of Low-cost Powder Metallurgy Titanium Alloys by 430 Stainless Steel Addition, Mater. Des., 2014, 60, p 628–63610.1016/j.matdes.2014.04.019 ↗
4. Y.F. Yang, S.F. Li, M. Qian, Q.S. Zhu, C.Q. Hu, and Y. Shi, Enabling the Development of Ductile Powder Metallurgy Titanium Alloys by a Unique Scavenger of Oxygen and Chlorine, J. Alloys Compd., 2018, 764, p 467–47510.1016/j.jallcom.2018.06.110 ↗
5. F. Cao, K.S.R. Chandran, and P. Kumar, New Approach to Achieve High Strength Powder Metallurgy Ti-6Al-4 V Alloy through Accelerated Sintering at β-transus Temperature and Hydrogenation-dehydrogenation Treatment, Scripta Mater., 2017, 130, p 22–2610.1016/j.scriptamat.2016.11.005 ↗
6. C. Zhang, B.X. Lu, H.Y. Wang, Z.M. Guo, V. Paley, and A.A. Volinsky, Vacuum Pressure-less Sintering of Ti-6Al-4 V Alloy with Full Densification and Forged-like Mechanical Properties, J. Mater. Eng. Perform., 2018, 27(1–2), p 282–29210.1007/s11665-017-3019-6 ↗
7. M. Yan, M.S. Dargusch, T. Ebel, and M. Qian, A Transmission Electron Microscopy and Three-dimensional Atom Probe Study of the Oxygen-induced Fine Microstructure Features in As-sintered Ti-6Al-4 V and Their Impacts on Ductility, Acta Mater., 2014, 68(15), p 196–20610.1016/j.actamat.2014.01.015 ↗
8. B. Chen, J.H. Shen, X.X. Ye, J. Umeda, and K. Kondoh, Advanced Mechanical Properties of Powder Metallurgy Commercially Pure Titanium with a High Oxygen Concentration, J. Mater. Res., 2017, 32(19), p 3769–377610.1557/jmr.2017.338 ↗
9. H.Z. Niu, H.R. Zhang, Q.Q. Sun, and D.L. Zhang, Breaking through the Strength-ductility Trade-off Dilemma in Powder Metallurgy Ti-6Al-4 V Titanium Alloy, Mater. Sci. Eng., A, 2019, 754, p 361–36910.1016/j.msea.2019.03.089 ↗
10. B. Sun, S.F. Li, H. Imai, T. Mimoto, J. Umeda, and K. Kondoh, Fabrication of High-strength Ti Materials by In-process Solid Solution Strengthening of Oxygen via P/M Methods, Mater. Sci. Eng., A, 2013, 563, p 95–10010.1016/j.msea.2012.11.058 ↗
11. Y. Zou, J. Wang, and Y.Y. Zheng, Electrochemical Techniques for Determining Corrosion Rate of Rusted Steel in Seawater, Corros. Sci., 2011, 53, p 208–21610.1016/j.corsci.2010.09.011 ↗
12. J. Chen, Q. Zhang, Q.A. Li, S.L. Fu, and J.Z. Wang, Corrosion and Tribocorrosion Behaviors of AISI, 316 Stainless Steel and Ti6Al4 V Alloys in Artificial Seawater, Trans. Nonferrous Met. Soc. China, 2014, 24(4), p 1022–103110.1016/S1003-6326(14)63157-5 ↗
13. J. Chen, J.Z. Wang, B.B. Chen, and F.Y. Yan, Tribocorrosion Behaviors of Inconel 625 Alloy Sliding against 316 Steel in Seawater, Tribol. Trans., 2011, 54(4), p 514–52210.1080/10402004.2011.571362 ↗
14. Q. Qu, S.L. Li, L. Li, L.M. Zuo, X. Ran, Y. Qu, and B.L. Zhu, Adsorption and Corrosion Behavior of Trichoderma Harzianum for AZ31B Magnesium Alloy in Artificial Seawater, Corros. Sci., 2017, 118, p 12–2310.1016/j.corsci.2017.01.005 ↗
15. L. Mohan, C. Anandan, and V.K.W. Grips, Corrosion Behavior of Titanium Alloy Beta-21S Coated with Diamond like Carbon in Hank’s Solution, Appl. Surf. Sci., 2012, 258(17), p 6331–634010.1016/j.apsusc.2012.03.032 ↗
16. X.J. Gong, Y.J. Cui, D.X. Wei, B. Liu, R.P. Liu, Y. Nie, and Y.P. Li, Building Direction Dependence of Corrosion Resistance Property of Ti-6Al-4 V Alloy Fabricated by Electron Beam Melting, Corros. Sci., 2017, 127, p 101–10910.1016/j.corsci.2017.08.008 ↗
17. M. Yan, Y. Liu, G.B. Schaffer, and M. Qian, In Situ Synchrotron Radiation to Understand the Pathways for the Scavenging of Oxygen in Commercially Pure Ti and Ti-6Al-4 V by Yttrium Hydride, Scripta Mater., 2013, 68(1), p 63–6610.1016/j.scriptamat.2012.09.024 ↗
18. L. Xu, R. Guo, and C. Bai, Effect of Hot Isostatic Pressing Conditions and Cooling Rate on Microstructure and Properties of Ti-6Al-4 V Alloy from Atomized Powder, J. Mater. Sci. Technol., 2014, 30(12), p 1289–129510.1016/j.jmst.2014.04.011 ↗
19. L. Bolzoni, E.M. Ruiz-Navas, and E. Gordo, Feasibility Study of the Production of Biomedical Ti-6Al-4V Alloy by Powder Metallurgy, Mater. Sci. Eng., C, 2015, 49(3), p 400–40710.1016/j.msec.2015.01.043 ↗
20. I. Milosev, G. Zerjav, J.M.C. Morenob, and M. Popa, Electrochemical Properties, Chemical Composition and Thickness of Passive Film Formed on Novel Ti-20Nb-10Zr-5Ta Alloy, Electrochim. Acta, 2013, 99, p 176–18910.1016/j.electacta.2013.03.086 ↗
21. Y. Bai, Y.L. Hao, S.J. Li, Y.Q. Hao, R. Yang, and F. Prima, Corrosion Behavior of Biomedical Ti-24Nb-4Zr-8Sn Alloy in Different Simulated Body Solutions, Mater. Sci. Eng., C, 2013, 33(4), p 2159–216710.1016/j.msec.2013.01.036 ↗
22. Y. Bai, S.J. Li, F. Prima, Y.L. Hao, and R. Yang, Electrochemical Corrosion Behavior of Ti-24Nb-4Zr-8Sn Alloy in a Simulated Physiological Environment, Appl. Surf. Sci., 2012, 258(8), p 4035–404010.1016/j.apsusc.2011.12.096 ↗
23. A. Biesiekierski, D.H. Ping, Y.Y. Yamabe-Mitarai, and C. Wen, Impact of Ruthenium on Microstructure and Corrosion Behavior of β-type Ti-Nb-Ru Alloys for Biomedical Application, Mater. Des., 2014, 59, p 303–30910.1016/j.matdes.2014.02.058 ↗
24. R. Chelariu, D. Mareci, and C. Munteanu, Preliminary Electrochemical Testing of Some Zr-Ti Alloys in 0.9% NaCl Solution, Mater. Corros., 2013, 64(7), p 585–59110.1002/maco.201206717 ↗
25. V. Totolin, V. Pejakovic, T. Csanyi, O. Hekele, M. Huber, and M.R. Ripoll, Surface Engineering of Ti6Al4V Surface for Enhanced Tribocorrosion Performance in Artificial Seawater, Mater. Des., 2016, 104, p 10–1810.1016/j.matdes.2016.04.080 ↗
26. Z.L. Jiang, X. Dai, and H. Middleton, Effect of Silicon on Corrosion Resistance of Ti-Si Alloys, Mater. Sci. Eng., B, 2011, 176(1), p 79–8610.1016/j.mseb.2010.09.006 ↗
27. M. Atapour, A. Pilchak, G.S. Frankel, J.C. Williams, M.H. Fathi, and M. Shamanian, Corrosion Behavior of Ti-6Al-4V with Different Thermomechanical Treatments and Microstructures, Corros. Sci. Sec., 2010, 66(6), p 065004-1-9
28. S.B. Hong, N. Eliaz, E.M. Sachs, S.M. Allen, and R.M. Latanision, Corrosion Behavior of Advanced Titanium-based Alloys Made by Three-dimensional Printing (3DP ™) for Biomedical Applications, Corros. Sci., 2001, 43, p 1781–179110.1016/S0010-938X(00)00181-5 ↗
29. C.E.B. Marino, E.M. Oliveira, R.C. Rocha-Filho, and S.R. Biaggio, On the Stability of Thin-anodic-oxide Films of Titanium in Acid Phosphoric Media, Corros. Sci., 2001, 43, p 1465–147610.1016/S0010-938X(00)00162-1 ↗
30. P.S. Heljo, K. Wolff, K. Lahtonen, M. Valden, P.R. Berger, H.S. Majumdar, and D. Lupo, Anodic Oxidation of Ultra-thin Ti Layers on ITO Substrates and Their Application in Organic Electronic Memory Elements, Electrochim. Acta, 2014, 137, p 91–9810.1016/j.electacta.2014.05.157 ↗
31. M. Zhu, R. Wang, C. Chen, H.B. Zhang, and G.J. Zhang, Comparison of Corrosion Behavior of Ti3SiC2 and Ti3AlC2 in NaCl Solutions with Ti Anodic Oxidation of Ultra-thin Ti, Ceram. Int., 2017, 43(7), p 5708–571410.1016/j.ceramint.2017.01.111 ↗
32. Y. Abd-elrhman, M.A.H. Gepreel, A. Abdel-Moniem, and S. Kobayashi, Compatibility Assessment of New V-free Low-cost Ti-4.7Mo-4.5Fe Alloy for Some Biomedical Applications, Mater. Des., 2016, 97, p 445–45310.1016/j.matdes.2016.02.110 ↗
33. Y.H. Yang, C.Q. Xia, Z.H. Feng, X.J. Jiang, B. Pan, X.Y. Zhang, M.Z. Ma, and R.P. Liu, Corrosion and Passivation of Annealed Ti-20Zr-6.5Al-4V Alloy, Corros. Sci., 2015, 101, p 56–6510.1016/j.corsci.2015.08.038 ↗
34. J. Soltis, Passivation Breakdown, Pit Initiation and Propagation of Pits in Metallic Materials-Review, Corros. Sci., 2015, 50, p 5–2210.1016/j.corsci.2014.10.006 ↗
35. J. Liu, A. Alfantazi, and E. Asselin, Characterization of Anodized Titanium for Hydrometallurgical Applications-evidence for Reduction of Cupric on Titanium Dioxide, Appl. Surf. Sci., 2013, 283, p 705–71410.1016/j.apsusc.2013.06.168 ↗
36. A.C. Alves, F. Wenger, P. Ponthiaux, J.P. Celis, A.M. Pinto, L.A. Rocha, and J.C.S. Fernandes, Corrosion Mechanisms in Titanium Oxide-based Films Produced by Anodic Treatment, Electrochim. Acta, 2017, 234, p 16–2710.1016/j.electacta.2017.03.011 ↗
37. J. Jayaraj, A.R. Shankar, and U.K. Mudali, Electrochemical and Passive Characterization of a Beta Type Ti45Zr38Al17 Cast Rod in Nitric Acid Medium, Electrochim. Acta, 2012, 85, p 210–21910.1016/j.electacta.2012.08.047 ↗
38. D. Mareci, R. Chelariu, D.M. Gordin, G. Ungureanu, and T. Gloriant, Comparative Corrosion Study of Ti-Ta Alloys for Dental Applications, Acta Biometer., 2009, 5(9), p 3625–363910.1016/j.actbio.2009.05.037 ↗
39. J.L. Ma, J.B. Wen, G.X. Li, and C.H. Xu, The Corrosion Behavior of Al-Zn-In-Mg-Ti Alloy in NaCl Solution, Corros. Sci., 2010, 52, p 534–53910.1016/j.corsci.2009.10.010 ↗
40. W.M. Liu, Q.J. Zhou, L.S. Li, Z.J. Wu, F.B. Cao, and Z.F. Gao, Effect of Alloy Element on Corrosion Behavior of the Huge Crude Oil Storage Tank Steel in Seawater, J. Alloys Compd., 2014, 598(12), p 198–204
41. G. Bolat, D. Mareci, R. Chelariu, J. Izquierdo, S. Gonzalez, and R.M. Souto, Investigation of the Electrochemical Behavior of TiMo Alloys in Simulated Physiological Solutions, Electrochim. Acta, 2013, 113, p 470–48010.1016/j.electacta.2013.09.116 ↗
42. L. Li, Q. Qu, W. Bai, F.C. Yang, Y.J. Chen, S.W. Zhang, and Z.T. Ding, Sodium Diethyldithiocarbamate as a Corrosion Inhibitor of Cold Rolled Steel in 0.5 M Hydrochloric Acid Solution, Corros. Sci., 2012, 59, p 249–25710.1016/j.corsci.2012.03.008 ↗