journal article·2022-01

Microstructure and Grain Boundary Corrosion Mechanism of Pearlitic Material

Zhaoliang Li, Wei Xue, Yiqing Chen, Wei Yu, Kui Xiao

Publisher page

Abstract

The influence mechanism of the localized corrosion initiation and expansion of the pearlite structure and the grain boundaries of low-alloy weathering steel S500AW was studied. The structure of the material was studied by means of metallographic microscope, XRD, SEM, TEM and EBSD spectrum. The surface potential between structures on the surface of low-alloy steel substrate was studied by SKPFM. The solution immersion experiment was used to study the material structure and grain boundary phenomena in corrosion initiation stage. The results showed that the existence of defects such as dislocations and high internal stress in the organization will lead to the preferential occurrence of corrosion. The ferrite inside the pearlite underwent corrosion process preferentially, while the surrounding ferrite underwent slow corrosion process. The MxCy precipitate at the grain boundary gradually fell off with this process to form pits. The presence of Cr in the precipitate would lead to the lack of Cr in the matrix, which would affect the corrosion resistance of the material.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Microstructure and Mechanical Properties of Steels · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. X.Q. Cheng, Z. Jin, M. Liu, and X.G. Li, Optimizing the Nickel Content in Weathering Steels to Enhance their Corrosion Resistance in Acidic Atmospheres, Corros. Sci., 2017, 115, p 135–142.10.1016/j.corsci.2016.11.016 ↗
2. W.M. Liu, J. Liu, H.B. Pan, F.B. Cao, Z.J. Wu, H.H. Lv, and Z.Y. Xu, Synergisic Effect of Mn, Cu, P with Cr Content on the Corrosion Behavior of Weathering Steel as a Train under the Simulated Industrial Atmosphere, J. Alloys. Compd., 2020, 834, p 155095.10.1016/j.jallcom.2020.155095 ↗
3. Z.H. Fang, J.F. Lian, L. Zhang, and Y.S. Wu, Study on the Micro-phase Electrochemical Behavior of 20 Steel and 16Mn Steel with Microelectrodes, Corros. Sci. Technol. Prot., 1996, 8, p 195–200.
4. Y. Zhang, F. Huang, Q. Hu, Z.X. Peng, J. Liu, and Yu. Zhang, Effect of Micro-phase Electrochemical Activity on the Initial Corrosion Dynamics of Weathering Steel, Mater. Chem. Phys., 2020, 241, p 122045.10.1016/j.matchemphys.2019.122045 ↗
5. S.B. Li, J. Guo, S.W. Yang, and X.L. He, Effect of Carbon Content and Structure Type on Corrosion Resistance of Low Alloy Steel, J. Univ. Sci. Technol. Beijing., 2008, 30, p 16–20.
6. P.P. Sarkar, P. Kumar, and M.K. Manna, Microstructural Influence on the Electrochemical Corrosion Behavior of Dual-phase Steels in 3.5% NaCl Solution, Mater. Lett., 2005, 59, p 2488–2451.10.1016/j.matlet.2005.03.030 ↗
7. J. Guo, S.W. Yang, and C.J. Shang, Influence of Carbon Content and Microstructure on Corrosion Behavior of Low Alloy Steels in a Cl- Containing Environment, Corros. Sci., 2008, 51, p 242–251.10.1016/j.corsci.2008.10.025 ↗
8. J.J. Dong, S.X. Zhang, and H.Y. Wang, Research on the Corrosion Performance of Ultra-low Carbon Bainite High Strength Steel, J. University. Sci. Technol. Wuhan., 2008, 31, p 127–131.
9. M. Ueda, H. Takabe, Effect of Environmental Factor and Microstructure on Morphology of Corrosion Products in CO2 Environments. In: Corrosion/99 [C]. Houston, Texas: NACE, (1999), 13.
10. A. Palacios and J.R. Shadley, Characteristics of Corrosion Scales on Steels in a CO2-Saturated NaCl Brine, Corrosion, 1991, 47, p 122–128.10.5006/1.3585227 ↗
11. A. Dugstad, H. Hemmer, and M. Seiersten, Effect of Steel Microstructure on Corrosion Rate and Protective Iron Carbonate Film Formation. In: Proceedings of NACE Corrosion/2000 (NACE 2000). (2000), 24.
12. Q. Hu, J. Liu, and Y. Wang et al., Corrosion Performance of Different Zones for Weld Joint of A710 Steel in 3.5% NaCl Solution, J. Chin. Soc. Corros. Prot., 2016, 36, p 611–616.
13. H.C. Ma, Z.Y. Liu, and C.W. Du et al., Stress Corrosion Cracking of E690 Steel as a Welded Joint in a Simulated Marine Atmosphere Containing Sulphur Dioxide, Corros. Sci., 2015, 100, p 627–641.10.1016/j.corsci.2015.08.039 ↗
14. V. Rault, V. Vignal, and H. Krawiec et al., Corrosion Behaviour of Heavily Deformed Pearlitic and Brass-coated Pearlitic Steels in Sodium Chloride Solutions, Corros. Sci.: J. Environ. Degrad. Mater. Control, 2014, 86, p 275–284.10.1016/j.corsci.2014.06.002 ↗
15. Y. Fan, W.X. Yang, and Y. Yang et al., Research on Initial Pitting Behavior Caused by Non Metallic Inclusions in Low Alloy Steels, Total Corros. Control, 2017, 31(01), p 65–70.
16. X.B. Liu, D. Zhang, H. Wang, Y. Yan, and X.F. Zhang, Regulating Solute Partitioning Utilized to Decorate Grain Boundary for Improving Corrosion Resistance in a Model Al-Cu-Mg Alloy, Corros. Sci., 2021, 181, p 0010-938X.10.1016/j.corsci.2020.109219 ↗
17. P.J. Wang, L.W. Ma, X.Q. Cheng, and X.G. Li, Effect of Grain Size and Crystallographic Orientation on the Corrosion Behaviors of Low Alloy Steel, J. Alloy. Compd., 2021, 857, p 0925–8388.
18. A. Lervik, S. Wenner, O. Lunder, C.D. Marioara, and R. Holmestad, Grain Boundary Structures and their Correlation with Intergranular Corrosion in an Extruded Al-Mg-Si-Cu Alloy, Mater. Charact., 2020, 170, p 1044–5803.10.1016/j.matchar.2020.110695 ↗
19. X.Y. Liu, D.Y. Zhang, C.C. Wang, X. Wang, Z.J. Zhao, M. Wu, and J.C. Huang, Effect of Grain Boundary Precipitation on Corrosion of Heating-aging Treated Al-4.47Zn-2.13Mg-1.20Cu Alloy, J. Mater. Res. Technol., 2020, 9, p 5815–5826.10.1016/j.jmrt.2020.03.106 ↗
20. L.G. Zheng, X.Q. Hu, X.H. Kang, and D.Z. Li, Precipitation Behavior of M23C6 and its Effects on Ductility and Toughness of a Novel Cr-Mn-N Austenitic Heat Resistant Steel, Acta Metall. Sin., 2013, 49(9), p 1081–1088.10.3724/SP.J.1037.2013.00198 ↗
21. B.F. Hu, H. Hkinoshita, K. Sakaguchi, and H. Takahashi, Irradiation Damage Behavior of Aging Precip-itated Carbide in Fe-Cr-Mn Steel, Acta Metall. Sin., 2006, 42(3), p 234–238.
22. B.Z. Sun, X.M. Zuo, X.Q. Cheng, and X.G. Li, The Role of Chromium Content in the Long-term Atmospheric Corrosion Process, npj Mater. Degrad., 2020 https://doi.org/10.1038/s41529-020-00142-510.1038/s41529-020-00142-5 ↗
23. Y. Sun, Z.Y. Zhang, L.H. Han, B. Zhang, M. Ning, Z.Q. Li, and H. Lu, Analysis of Microstructure and Precipitation Phase of Chromium-molybdenum Series Anti-corrosion Steel Pipe, Steel Pipe, 2011, 6, p 49–54.
24. F. Chai, S. Jiang, and C. Yang, Effect of Cr on Characteristic of Rust Layer Formed on Low Alloy Steel in Flow-accelerated Corrosion Environment, J. Iron. Steel. Res. Intl., 2016, 23, p 602–607.10.1016/S1006-706X(16)30094-2 ↗
25. K.T. Aust, U. Erb, and G. Palumbo, Interface Control for Resistance to Intergranular Cracking, Mater. Sci. Eng. A., 1994, 176, p 329–334.10.1016/0921-5093(94)90995-4 ↗
26. L. Peguet, B. Malki, and B. Baroux, Influence of Cold Working on the Pitting Corrosion Resistance of Stainless Steels, Corrs. Sci., 2007, 49, p 1933–1948.10.1016/j.corsci.2006.08.021 ↗
27. Y.T. Zhou, Y.J. Wang, S.J. Zheng, B. Zhang, and X.L. Ma, Strain-induced Preferential Dissolution at the Dislocation Emergences in MnS: an Atomic Scale Study, Philos. Mag., 2015, 95, p 2365–2375.10.1080/14786435.2015.1052030 ↗
28. R. Avci, B.H. Davis, M.L. Wolfenden, I.B. Beech, K. Lucas, and D. Paul, Mechanism of MnS-mediated Pit Initiation and Propagation in Carbon Steel in an Anaerobic Sulfidogenic Media, Corros. Sci., 2013, 76, p 267–274.10.1016/j.corsci.2013.06.049 ↗
29. X. Zhang, Y. Jiao, and Y. Yu, Intergranular Corrosion in AA2024-T3 Aluminium Alloy: The Influence of Stored Energy and Prediction, Corrs. Sci., 2019, 155, p 1–12.10.1016/j.corsci.2019.04.031 ↗