journal article·2021-02

The Influence of High Temperature Ultrasonic Processing Time on the Microstructure and Mechanical Properties AZ91E Magnesium Alloy

P. Emadi, C. Ravindran

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Abstract

The reduction of harmful greenhouse gas emissions can be realized by utilizing lightweight structural metals, such as magnesium (Mg). Magnesium alloys have the potential to replace higher-density aluminum and ferrous components in automotive and aerospace industries, thereby decreasing vehicle weight and the associated fuel requirements. However, their strength and ductility must be improved to ensure widespread application. This goal can be achieved through ultrasonic processing, a technique that is gaining popularity in the manufacturing of light alloys. In this study, the effects of high-intensity ultrasonic vibration on the microstructure and mechanical properties of AZ91E were investigated. The molten alloys were subjected to 60, 120, 180 and 240 s of sonication at a frequency and amplitude of 20 kHz and 30 µm, respectively. The resultant castings were characterized using optical microscopy, scanning electron microscopy and tensile testing. Sonication was found to improve the mechanical properties of the alloy relative to the base condition. The improvement was attributed to the refinement of the Mg grain structure, decreased area fraction and average size of the brittle Mg17Al12 eutectic phase, in addition to increased area fraction, homogenous distribution and spheroidization of the Mn-Al intermetallic phase. The refinement in microstructure was determined to be a result of improved nucleation and cavitation-induced undercooling of the melt as well as a finer grain size. Therefore, ultrasonic processing can enhance the viability of Mg alloys as engineering materials, offering important opportunities for the production of greener, light-metal components.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Aluminum Alloy Microstructure Properties

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References (48)

Show source-provided references
1. A. Luo, Recent Magnesium Alloy Development for Elevated Temperature Applications, Int. Mater. Rev., 2004, 49, p 13–3010.1179/095066004225010497 ↗
2. E. Emley, Principles of Magnesium Technology, Pergamon Press, Oxford, UK, 1966
3. S. Kollamthodi, D. Kay, I. Skinner, C. Dun, and S. Hausberger, The Potential for Mass Reduction of Passenger Cars and Light Commercial Vehicles in Relation to Future CO2 Regulatory Requirements, Ricardo-AEA, Harwell, UK, 2015
4. C. Zhong, F. Liu, Y. Wu, J. Le, L. Liu, M. He, J. Zhu, and W. Hu, Protective Diffusion Coatings on Magnesium Alloys: A Review of Recent Developments, J. Alloys Compd., 2012, 520, p 11–2110.1016/j.jallcom.2011.12.124 ↗
5. D. St.John, Q. Ma, M. Easton, P. Cao, and Z. Hildebrand, Grain Refinement of Magnesium Alloys, Metall. Mater. Trans., 2005, 36, p 1669–167910.1007/s11661-005-0030-6 ↗
6. Y. Wang, X. Liao, and Y. Zhu, Grain Refinement and Growth Induced by Severe Plastic Deformation, Int. J. Mater. Res., 2009, 100(12), p 1632–163710.3139/146.110230 ↗
7. Q. Xu, A. Ma, Y. Li, J. Sun, Y. Yuan, J. Jiang, and C. Ni, Microstructure Evolution of AZ91 Alloy Processed by a Combination Method of Equal Channel Angular Pressing and Rolling, J. Magn. Alloys, 2020, 8, p 192–19810.1016/j.jma.2019.05.012 ↗
8. Y. Zhu, F. Liu, R. Xin, B. Song, and Q. Liu, Improving Mechanical Properties of an AZ91 Alloy by Properly Combining Aging Treatment and Torsion Deformation, Mater. Sci. Eng. A, 2020, 779, p 13915610.1016/j.msea.2020.139156 ↗
9. F. Zhong, H. Wu, Y. Jiao, R. Wu, J. Zhang, L. Hou, and M. Zhanga, Effect of Y and Ce on the Microstructure, Mechanical Properties and Anisotropy of As-Rolled Mg-8Li-1Al Alloy, J. Mater. Sci. Technol., 2020, 39, p 124–13410.1016/j.jmst.2019.04.045 ↗
10. S. Lv, X. Lü, F. Meng, Q. Yang, X. Qiu, P. Qin, Q. Duan, and J. Meng, Microstructures and Mechanical Properties in a Gd-Modified High-Pressure Die Casting Mg4Al-3La-0.3Mn Alloy, Mater. Sci. Eng. A, 2020, 773, p 13872510.1016/j.msea.2019.138725 ↗
11. A. Ramirez, M. Qian, B. Davis, T. Wilks, and D. St.John, Potency of High-Intensity Ultrasonic Treatment for Grain Refinement of Magnesium Alloys, Scr. Mater., 2008, 59(1), p 19–2210.1016/j.scriptamat.2008.02.017 ↗
12. M. Qian and P. Cao, Discussions on Grain Refinement of Magnesium Alloys by Carbon Innoculation, Scr. Mater., 2005, 52(5), p 415–41910.1016/j.scriptamat.2004.10.014 ↗
13. P. Cao, M. Qian, and D. St.John, Grain Refinement of Commercial Purity Mg-9%Al Alloys by Superheating, ed. by N. Neelameggham, H. Kaplan, and B. Powell. Magnesium Technology (Minerals, Metals & Materials Society (TMS), San Francisco, CA, USA, 2005), p 297–302
14. A. Chaturvedi, A. Sharma, and U. Pandel, Effect of Mechanical Vibrations on Grain Refinement of AZ91 Mg Alloy, Mater. Res. Express, 2017, 4(4), p 1–1110.1088/2053-1591/aa64f5 ↗
15. Y. Mizutani, T. Tamura, and K. Miwa, Microstructural Refinement Process of Pure Magnesium by Electromagnetic Vibrations, Mater. Sci. Eng. A, 2005, 413–414, p 205–21010.1016/j.msea.2005.09.009 ↗
16. X. Jian, T. Meek, T. Geer, and Q. Han, Effect of Power Ultrasound on Grain Refinement of Magnesium AM60B Alloy, ed. by A. Luo, N. Neelameggham, and R. Beals. Magnesium Technology (Minerals, Metals & Materials Society (TMS), San Antonio, TX, USA, 2006), p 103–107
17. Q. Gao, S. Wu, S. Lü, X. Xiong, R. Du, and P. An, Effects of Ultrasonic Vibration Treatment on Particles Distribution of TiB2 Particles Reinforced Aluminum Composites, Mater. Sci. Eng. A, 2017, 680, p 437–44310.1016/j.msea.2016.10.103 ↗
18. N.Q. Tuan, H. Puga, J. Barbosa, and A. Pinto, Grain Refinement of Al-Mg-Sc Alloy by Ultrasonic Treatment, Met. Mater. Int., 2015, 21(1), p 72–7810.1007/s12540-015-1008-6 ↗
19. A. Gnanavelbabu, K.T.S. Surendran, and S. Kumar, Influence of Ultrasonication Power on Grain Refinement, Mechanical Properties and Wear Behaviour of AZ91D/Nano-Al2O3 Composites, Mater. Res. Express, 2020, 7, p 01654410.1088/2053-1591/ab64d7 ↗
20. A. Brandes and B. Brook, Smithells Metals Reference Book, The Bath Press, Oxford, UK, 1992
21. R. Lide, CRC Handbook of Chemistry and Physics, 7th edn. CRC Press, Boca Raton, 2001
22. Z. Yin, Y. Chen, H. Yan, G.-H. Zhou, X.-Q. Wu, and Z. Hu, Effects of the Second Phases on Corrosion Resistance of AZ91-xGd Alloys Treated with Ultrasonic Vibration, J. Alloys Compd., 2019, 783, p 877–88510.1016/j.jallcom.2019.01.002 ↗
23. M. Zhao, M. Liu, G. Song, and A. Atrens, Influence of Microstructure on Corrosion of As-Cast ZE41, Adv. Eng. Mater., 2008, 10, p 104–11110.1002/adem.200700246 ↗
24. M. Zhao, P. Uggowitzer, M. Liu, P. Schmutz, G. Song, and A. Atrens, Corrosion of AZ91—Influence of the β-Phase Morphology, Mater. Sci. Forum, 2009, 618–619, p 473–47810.4028/www.scientific.net/MSF.618-619.473 ↗
25. R. Arrabal, A. Pardo, M. Merino, K. Paucar, M. Mohedano, P. Casajús, and G. Garcés, Influence of Gd on the Corrosion Behavior of AM50 and AZ91D Magnesium Alloys, Corros. Sci., 2012, 68(5), p 398–40110.5006/0010-9312-68.5.398 ↗
26. D. Gao, Z. Li, Q. Han, and Q. Zhai, Effect of Ultrasonic Power on Microstructure and Mechanical Properties of AZ91 Alloy, Mater. Sci. Eng. A, 2009, 502(1–2), p 2–510.1016/j.msea.2008.12.005 ↗
27. D. Li, H.-S. Xue, and G. Yang, Microstructure and Mechanical Properties of Mg-6Zn-0.5Y Magnesium Alloy Prepared with Ultrasonic Treatment, Rare Met., 2017, 36(8), p 622–62610.1007/s12598-015-0553-y ↗
28. H. Puga, V. Carneiro, and J.B.V. Vieira, Effect of Ultrasonic Treatment in the Static and Dynamic Mechanical Behavior of AZ91D Mg Alloy, Metals, 2015, 5(4), p 2210–222110.3390/met5042210 ↗
29. X. Liu, Y. Osawa, S. Takamori, and T. Mukai, Microstructure and Mechanical Properties of AZ91 Alloy Produced with Ultrasonic Vibration, Mater. Sci. Eng. A, 2008, 487(1–2), p 120–12310.1016/j.msea.2007.09.071 ↗
30. G. Zhong, S. Wu, H. Jiang, and P. An, Effects of Ultrasonic Vibration on the Iron-Containing Intermetallic Compounds of High Silicon Aluminum Alloy with 2% Fe, J. Alloys Compd., 2010, 492(1–2), p 482–48710.1016/j.jallcom.2009.11.145 ↗
31. J. Lan, Y. Yang, and X. Li, Microstructure and Microhardness of SiC Nanoparticles Reinforced Magnesium Composites Fabricated by Ultrasonic Method, Mater. Sci. Eng. A, 2004, 386(1–2), p 284–29010.1016/S0921-5093(04)00936-0 ↗
32. Y.-J. Chen, W.-N. Hsu, and J.-R. Shih, The Effect of Ultrasonic Treatment on Microstructural and Mechanical Properties of Cast Magnesium Alloys, Mater. Trans., 2009, 50(2), p 401–40810.2320/matertrans.MER2008273 ↗
33. J. Campbell, Effects of Vibration During Solidification, Int. Mater. Rev., 1981, 26(1), p 71–10810.1179/imr.1981.26.1.71 ↗
34. S. Yu, H. Feng, Y. Li, and L. Gong, Study on the Properties of Al-23%Si Alloy Treated by Ultrasonic Wave, J. Alloys Compd., 2009, 484(1–2), p 360–36410.1016/j.jallcom.2009.04.104 ↗
35. G.I. Eskin, Ultrasonic Treatment of Light Alloy M, Gordon & Breach, Amsterdam, 199810.1201/9781498701792 ↗
36. Standard Specification for Aluminum-Alloy Permanent Mold Castings, ASTM B108 - 19, ASTM, 2019
37. Standard Practice for Heat Treatment of Magnesium Alloys, ASTM B661 - 12, ASTM, 2012
38. Standard Test Methods for Determining Average Grain Size, ASTM E112 - 13, ASTM, 2013
39. S. Zhang, Y. Zhao, X. Cheng, G. Chen, and Q. Dai, High-Energy Ultrasonic Field Effects on the Microstructure and Mechanical Behaviors of A356 Alloy, J. Alloys Compd., 2009, 470(1–2), p 168–17210.1016/j.jallcom.2008.02.091 ↗
40. Y. Li, H. Feng, F. Cao, Y. Chen, and L. Gong, Effect of High Density Ultrasonic on the Microstructure and Refining Property of Al-5Ti-0.25C Grain Refiner Alloy, Mater. Sci. Eng. A, 2008, 487(1–2), p 518–52310.1016/j.msea.2007.11.067 ↗
41. M. Avedesian and H. Baker, Magnesium and Magnesium Alloys, ASM International, Materials Park, 1999, p 7–8
42. A. Zhang, H. Hao, and X. Zhang, Grain Refinement Mechanism of Al-5C Master Alloy in AZ31 Magnesium Alloy, Trans. Nonferrous Met. Soc. China, 2013, 23(11), p 3167–317210.1016/S1003-6326(13)62848-4 ↗
43. E.O. Hall, The Deformation and Ageing of Mild Steel: III, Discussion of Results, Proc. Phys. Soc., 1951, 64(9), p 747–75510.1088/0370-1301/64/9/303 ↗
44. N.J. Petch, The Cleavage Strength of Polycrystals, J. Iron Steel Inst., 1953, 174(1), p 25–28
45. H. Ryou, J.W. Drazin, K.J. Wahl, S.B. Qadri, E.P. Gorzkowski, B.N. Feigelson, and J.A. Wollmershauser, Below the Hall–Petch Limit in Nanocrystalline Ceramics, ACS Nano, 2018, 12(4), p 3083–309410.1021/acsnano.7b07380 ↗
46. C. Kim, I. Sohn, M. Nezafati, J.B. Ferguson, B.F. Schultz, Z. Bajestani-Gohari, P.K. Rohatgi, and K. Cho, Prediction Models for the Yield Strength of Particle-Reinforced Unimodal Pure Magnesium (Mg) Metal Matrix Nanocomposites (MMNCs), J. Mater. Sci., 2013, 48, p 4191–420410.1007/s10853-013-7232-x ↗
47. A. Redsten, E. Klier, A. Brown, and D. Dunand, Mechanical Properties and Microstructure of Cast Oxide-Dispersion-Strengthened Aluminum, Mater. Sci. Eng. A, 1995, 201, p 88–10210.1016/0921-5093(94)09741-0 ↗
48. E. Tolouie and R. Jamaati, Effect of β-Mg17Al12 phase on Microstructure, Texture and Mechanical Properties of AZ91 Alloy Processed by Asymmetric Hot Rolling, Mater. Sci. Eng. A, 2018, 738, p 81–8910.1016/j.msea.2018.09.086 ↗