SiC Nanoparticles Toughened-SiC/MoSi2-SiC Multilayer Functionally Graded Oxidation Protective Coating for Carbon Materials at High Temperatures
Source abstract
Abstract
A SiC nanoparticle toughened-SiC/MoSi2-SiC functionally graded oxidation protective coating on graphite was prepared by reactive melt infiltration (RMI) at 1773 and 1873 K under argon atmosphere. The phase composition and anti-oxidation behavior of the coatings were investigated. The results show that the coating was composed of MoSi2, α-SiC and β-SiC. By the variations of Gibbs free energy (calculated by HSC Chemistry 6.0 software), it could be suggested that the SiC coating formed at low temperatures by solution-reprecipitation mechanism and at high temperatures by gas-phase reactions and solution-reprecipitation mechanisms simultaneously. SiC nanoparticles could improve the oxidation resistance of SiC/MoSi2-SiC multiphase coating. Addition of SiC nanoparticles increases toughness of the coating and prevents spreading of the oxygen diffusion channels in the coating during the oxidation test. The mass loss and oxidation rate of the SiC nanoparticle toughened-SiC/MoSi2-SiC-coated sample after 10-h oxidation at 1773 K were only 1.76% and 0.32 × 10−2 g/cm3/h, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Aluminum Alloys Composites Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (23)
Show source-provided references
1. J.D. Buckley and D.D. Edie, Carbon–Carbon Materials and Composites, William Andrew, 1993.
2. Q. Zhu, X. Qiu, and C. Ma, Oxidation Resistant SiC Coating for Graphite Materials, Carbon, 1999, 37(9), p 1475–148410.1016/S0008-6223(99)00010-X ↗
3. X. Yang, Q. Huang, Z. Su, X. Chang, L. Chai, C. Liu, L. Xue, and D. Huang, Resistance to Oxidation and Ablation of SiC Coating on Graphite Prepared by Chemical Vapor Reaction, Corros. Sci., 2013, 75, p 16–2710.1016/j.corsci.2013.05.009 ↗
4. J. Schulte-Fischedick, J. Schmidt, R. Tamme, U. Kröner, J. Arnold, and B. Zeiffer, Oxidation Behaviour of C/C-SiC Coated with SiC-B4C-SiC-Cordierite Oxidation Protection System, Mater. Sci. Eng. A, 2004, 386(1), p 428–43410.1016/j.msea.2004.07.055 ↗
5. X. Cao, X. Yin, X. Ma, X. Fan, L. Cheng, and L. Zhang, Oxidation Behavior of SiBC Matrix Modified C/SiC Composites with Different PyC Interphase Thicknesses, Ceram. Int., 2015, 41(1), p 1695–170010.1016/j.ceramint.2014.09.111 ↗
6. M. Aparicio and A. Duran, Yttrium Silicate Coatings for Oxidation Protection of Carbon–Silicon Carbide Composites, J. of the Am. Ceram. Soc., 2000, 83(6), p 1351–135510.1111/j.1151-2916.2000.tb01392.x ↗
7. M.C. Halbig, J.D. McGuffin-Cawley, A.J. Eckel, and D.N. Brewer, Oxidation Kinetics and Stress Effects for the Oxidation of Continuous Carbon Fibers Within a Microcracked C/SiC Ceramic Matrix Composite, J. Am. Ceram. Soc., 2008, 91(2), p 519–52610.1111/j.1551-2916.2007.02170.x ↗
8. F. Qian-Gang, L. He-Jun, S. Xiao-Hong, L. Ke-Zhi, W. Jian, and H. Min, Oxidation Protective Glass Coating for SiC Coated Carbon/Carbon Composites for Application at 1773 K, Mater. Lett., 2006, 60(3), p 431–43410.1016/j.matlet.2005.09.006 ↗
9. J. Kim, W.-J. Kim, D. Choi, J. Park, and W.-S. Ryu, Design of a C/SiC Functionally Graded Coating for the Oxidation Protection of C/C Composites, Carbon, 2005, 43(8), p 1749–175710.1016/j.carbon.2005.02.025 ↗
10. Y. Ye, H. Zhang, Y. Tong, and S. Bai, HfC-Based Coating Prepared by Reactive Melt Infiltration on C/C Composite Substrate, Ceram. Int., 2013, 39(5), p 5477–548310.1016/j.ceramint.2012.12.059 ↗
11. Z. Dong, S. Liu, X. Li, A. Westwood, G. Yuan, Z. Cui, and Y. Cong, Influence of Infiltration Temperature on the Microstructure and Oxidation Behavior of SiC-ZrC Ceramic Coating on C/C Composites Prepared by Reactive Melt Infiltration, Ceram. Int., 2015, 41(1), p 797–81110.1016/j.ceramint.2014.08.138 ↗
12. H.J. Li, Y.L. Zhang, Q.G. Fu, K.Z. Li, J. Wei, and D.S. Hou, Oxidation Behavior of SiC Nanoparticle-SiC Oxidation Protective Coating for Carbon/Carbon Composites at 1773K, Carbon, 2007, 45(13), p 2704–270710.1016/j.carbon.2007.08.013 ↗
13. A. Abdollahi and M. Mashhadi, Effect of B4C, MoSi2, Nano SiC and Micro-sized SiC on Pressureless Sintering Behavior, Room-Temperature Mechanical Properties and Fracture Behavior of Zr(Hf)B2-Based Composites, Ceram. Int., 2014, 40(7), p 10767–1077610.1016/j.ceramint.2014.03.066 ↗
14. A. Roine, HSC Chemistry for Windows, Version 6.0, Chemical Reaction and Equilibrium Software with Extensive Thermochemical Database (2006).
15. T. Morimoto, Y. Ogura, M. Kondo, and T. Ueda, Multilayer Coating for Carbon–Carbon Composites, Carbon, 1995, 33(4), p 351–35710.1016/0008-6223(94)00158-V ↗
16. J. Ness and T. Page, Microstructural Evolution in Reaction-Bonded Silicon Carbide, J. Mater. Sci., 1986, 21(4), p 1377–139710.1007/BF00553278 ↗
17. F. Qian-Gang, L. He-Jun, W. Yong-Jie, L. Ke-Zhi, and W. Heng, A Si-SiC Oxidation Protective Coating for Carbon/Carbon Composites Prepared by a Two-Step Pack Cementation, Ceram. Int., 2009, 35(6), p 2525–252910.1016/j.ceramint.2009.01.005 ↗
18. Y. Niu, H. Wang, Z. Liu, C. Hu, X. Wang, X. Zheng, and C. Ding, Microstructure Evolution of ZrB2-MoSi2 Composite Coatings at Middle and High Temperatures, Surf. Coat. Technol., 2015, 273, p 30–3810.1016/j.surfcoat.2015.03.029 ↗
19. Q. Fu, X. Zou, Y. Chu, H. Li, J. Zou, and C. Gu, A Multilayer MoSi2-SiC-B Coating to Protect SiC-Coated Carbon/Carbon Composites Against Oxidation, Vacuum, 2012, 86(12), p 1960–196310.1016/j.vacuum.2012.04.045 ↗
20. H. Li, Y. Wang, Q. Fu, and G. Sun, Improvement in Oxidation Properties of SiC-Coated Carbon/Carbon Composites Through Modification of the SiC/Carbon Interface, Surf. Coat. Technol., 2014, 245, p 49–5410.1016/j.surfcoat.2014.02.036 ↗
21. S.R. Levine, E.J. Opila, M.C. Halbig, J.D. Kiser, M. Singh, and J.A. Salem, Evaluation of Ultra-High Temperature Ceramics For aeropropulsion Use, J. Eur. Ceram. Soc., 2002, 22(14), p 2757–276710.1016/S0955-2219(02)00140-1 ↗
22. C. Huo, L. Guo, L. Feng, C. Wang, Z. Li, Y. Zhang, and G. Kou, Improving the Oxidation Resistance Under Thermal Shock Condition of SiC-Coated C/C Composites with Refined SiC Grain Size Using Ferrocene, Surf. Coat. Technol., 2017, 316, p 39–4710.1016/j.surfcoat.2017.03.019 ↗
23. L. Zhuang and Q.G. Fu, Bonding Strength, Thermal Shock and Oxidation Resistance of Interlocking (Zr, Hf) C-SiC/SiC Double-Layer Coating for C/C Composites, Surf. Coat. Technol., 2017, 315, p 436–44210.1016/j.surfcoat.2017.02.072 ↗