NiFe2O4 Spinel Protection Coating for High-Temperature Solid Oxide Fuel Cell Interconnect Application
Source abstract
Abstract
In the present study, Ni-Fe spinel powder was synthesized via a solid state reaction. In the next step, the electrophoretic deposition (EPD) method was used to apply the NiFe2O4 spinel, as an oxidation-resistant layer, on a commercially available stainless steel (SUS 430) in a potential range of 100 to 300 V. Microscopic studies of the deposited layers showed that crack-free NiFe2O4 films were obtained at 100 V. The coated and uncoated samples were then pre-sintered in air and 5% H2 bal Ar atmospheres at 900 °C for 3 h followed by cyclic oxidation at 800 °C for 500 h. The investigation of the oxidation resistance of the samples using Energy Dispersive Spectroscopy (EDS) revealed that the NiFe2O4 coating acted as an effective barrier against chromium migration into the coating. The oxidation resistance of 5% H2 bal Ar pre-sintered sample was enhanced with an oxidation rate constant (K P) of 8.9 × 10−15 g2 cm−4 s−1.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Electrophoretic Deposition in Materials Science · Advancements in Solid Oxide Fuel Cells · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (52)
Show source-provided references
1. Mark C. Williams, Joseph P. Strakey, and Wayne A. Surdoval, The U.S. Department of Energy, Office of Fossil Energy Stationary Fuel Cell Program, J. Power Sources, 2005, 143, p 191–19610.1016/j.jpowsour.2004.12.003 ↗
2. Wei Zhou, Ran Ran, and Zongping Shao, Progress in Understanding and Development of Ba0.5Sr0.5Co0.8Fe0.2O3-X-Based Cathodes for Intermediate-Temperature Solid-Oxide Fuel Cells: A Review, J. Power Sources, 2009, 192(2), p 231–24610.1016/j.jpowsour.2009.02.069 ↗
3. T. Brylewski, M. Nanko, T. Maruyama, and K. Przybylski, Application of Fe-16Cr Ferritic Alloy to Interconnector for a Solid Oxide Fuel Cell, Solid State Ion., 2001, 143(2), p 131–15010.1016/S0167-2738(01)00863-3 ↗
4. M.A. Callander, Material Issues for Fuel Cell Applications, Mater. High Temp., 2007, 24(3), p 197–20310.3184/096034007X267349 ↗
5. Zhu Wz and Deevi Sc, Opportunity of Metallic Interconnects for Solid Oxide Fuel Cells: A Status on Contact Resistance, Mater. Res. Bull., 2003, 38(6), p 957–97210.1016/S0025-5408(03)00076-X ↗
6. W.Z. Zhu and S.C. Deevi, Development of Interconnect Materials for Solid Oxide Fuel Cells, Mater. Sci. Eng. A, 2003, 348(1-2), p 227–24310.1016/S0921-5093(02)00736-0 ↗
7. Maria Jose Garcia-Vargas, Laurent Lelait, Vladislav Kolarik, Harald Fietzek, and Maria del Mar Juez-Lorenzo, Oxidation of Potential SOFC Interconnect Materials, Crofer 22 APU and Avesta 353 MA, in Dry and Humid Air Studied In Situ by X-ray Diffraction, Mater. High Temp., 2005, 22(3-4), p 245–25110.1179/mht.2005.028 ↗
8. J. Yoo, S.-K. Woo, J.H. Yu, S. Lee, and G.W. Park, La0.8Sr0.2MnO3 and (Mn1.5Co1.5) O4 Double Layer Coated by Electrophoretic Deposition on Crofer22 APU for SOEC Interconnect Applications, Int. J. Hydrog. Energy, 2009, 34(3), p 1542–154710.1016/j.ijhydene.2008.12.005 ↗
9. K. Lai et al., A Quasi-Two-Dimensional Electrochemistry Modeling Tool for Planar Solid Oxide Fuel Cell Stacks, J. Power Sources, 2011, 196(6), p 3204–322210.1016/j.jpowsour.2010.11.123 ↗
10. J. Wu and X. Liu, Recent Development of SOFC Metallic Interconnect, J. Mater. Sci. Technol., 2010, 26(4), p 293–30510.1016/S1005-0302(10)60049-7 ↗
11. L.G.P. Andre, Cologna Marco, Sglavo Vincenzo, and Raj Rishi, Flash-Sintering of Co2MnO4 Spinel for Solid Oxide Fuel Cell Applications, J. Power Sources, 2011, 196, p 2061–206510.1016/j.jpowsour.2010.10.036 ↗
12. Cezarina C. Mardare, Henrik Asteman, Michael Spiegel, Alan Savan, and Alfred Ludwig, Investigation of thermally oxidized Mn-Co thin films for application in SOFC metallic interconnects, Appl. Surf. Sci., 2008, 255, p 1850–185910.1016/j.apsusc.2008.06.052 ↗
13. N. Shaigan, W. Qu, Dg Ivey, and W. Chen, A Review of Recent Progress in Coatings, Surface Modifications and Alloy Developments for Solid Oxide Fuel Cell Ferritic Stainless Steel Interconnects, J. Power Sources, 2010, 195(6), p 1529–154210.1016/j.jpowsour.2009.09.069 ↗
14. R. Gordon et al., Dual-Environment Effects on the Oxidation of Metallic Interconnects, J. Mater. Eng. Perform., 2006, 15(4), p 404–40910.1361/105994906X117198 ↗
15. Z. Yang, K.S. Weil, D.M. Paxton, and J.W. Stevenson, Selection and Evaluation of Heat-Resistant Alloys for SOFC Interconnect Applications, J. Electrochem. Soc., 2003, 150(9), p 1188–120110.1149/1.1595659 ↗
16. S. Elangovan et al., Evaluation of Ferritic Stainless Steel for Use as Metal Interconnects for Solid Oxide Fuel Cells, J. Mater. Eng. Perform., 2004, 13(3), p 265–27310.1361/10599490419153 ↗
17. Z. Yang et al. (Mn, Co)3O4 Spinel Coatings on Ferritic Stainless Steels for SOFC Interconnect Applications, Int. J. Hydrog. Energy, 2007, 32(16), p 3648–365410.1016/j.ijhydene.2006.08.048 ↗
18. J.W. Fergus, Metallic Interconnects for Solid Oxide Fuel Cells, Mater. Sci. Eng. A, 2005, 397(1-2), p 271–28310.1016/j.msea.2005.02.047 ↗
19. S. Geng, J. Zhu, M.P. Brady, H.U. Anderson, X.-D. Zhou, and Z. Yang, A Low-Cr Metallic Interconnect for Intermediate-Temperature Solid Oxide Fuel Cells, J. Power Sources, 2007, 172(2), p 775–78110.1016/j.jpowsour.2007.05.022 ↗
20. Z. Yang, G. Xia, P. Singh, and J.W. Stevenson, Electrical Contacts Between Cathodes and Metallic Interconnects in Solid Oxide Fuel Cells, J. Power Sources, 2006, 155(2), p 246–25210.1016/j.jpowsour.2005.05.010 ↗
21. M. Krumpelt, T. Kaun, T.A. Cruse, M.C. Hash. “SOFC Research and Development.” Office of Fossil Energy Fuel Cell Program. Annual Report (2004).
22. A.M. Dayaghi et al., Pre-Treatment and Oxidation Behavior of Sol-Gel Co Coating on 430 Steel in 750 °C Air with Thermal Cycling, Surf. Coat. Technol., 2012, 206(16), p 3495–350010.1016/j.surfcoat.2012.02.023 ↗
23. R. Lacey et al., Evaluation of Co and Perovskite Cr-Blocking Thin Films on SOFC Interconnects, Solid State Ionics., 2010, 181(27-28), p 1294–130210.1016/j.ssi.2010.07.007 ↗
24. H. Kurokawa et al., Chromium Vaporization of Bare and of Coated Iron-Chromium Alloys at 1073 K, Solid State Ionics., 2007, 178(3-4), p 287–29610.1016/j.ssi.2006.12.010 ↗
25. J.W. Fergus, Synergism in the Design of Interconnect Alloy-Coating Combinations Solid for Oxide Fuel Cells, Scr. Mater. A., 2011, 65(2), p 73–7710.1016/j.scriptamat.2010.09.020 ↗
26. J. Wu et al., The Performance of Solid Oxide Fuel Cells with Mn-Co Electroplated Interconnects as Cathode Current Collector, J. Power Sources., 2009, 189(2), p 1106–111310.1016/j.jpowsour.2008.12.079 ↗
27. N. Shaigan et al., Co/LaCrO3 Composite Coatings for AISI, 430 Stainless Steel Solid Oxide Fuel Cell Interconnects, J. Power Sources., 2008, 185(1), p 331–33710.1016/j.jpowsour.2008.06.065 ↗
28. X. Deng et al., Cobalt Plating of High Temperature Stainless Steel Interconnects, J. Power Sources., 2006, 160(2), p 1225–122910.1016/j.jpowsour.2006.03.024 ↗
29. J. Froitzheim et al., Long Term Study of Cr Evaporation and High Temperature Corrosion Behaviour of Co Coated Ferritic Steel for Solid Oxide Fuel Cell Interconnects, J. Power Sources., 2012, 220, p 217–22710.1016/j.jpowsour.2012.06.092 ↗
30. M. Palcut et al., Efficient Dual Layer Interconnect Coating for High Temperature Electrochemical Devices, Int. J. Hydrogen Energy., 2012, 37(19), p 14501–1451010.1016/j.ijhydene.2012.07.038 ↗
31. J. Wu et al., Investigation of Mn/Co Coated T441 Alloy as SOFC Interconnect by On-Cell Tests, Int. J. Hydrogen Energy., 2011, 36(7), p 4525–452910.1016/j.ijhydene.2010.04.115 ↗
32. Å.H. Persson et al., Interaction Mechanisms Between Slurry Coatings and Solid Oxide Fuel Cell Interconnect Alloys During High Temperature Oxidation, J Alloys Compd., 2012, 521, p 16–2910.1016/j.jallcom.2011.12.095 ↗
33. A. Petric and H. Ling, Electrical Conductivity and Thermal Expansion of Spinels at Elevated Temperatures, J. Am. Ceram. Soc., 2007, 90, p 1515–152010.1111/j.1551-2916.2007.01522.x ↗
34. C.C. Mardare, H. Asteman, M. Spiegel, A. Savan, and A. Ludwig, Investigation of Thermally Oxidised Mn-Co Thin Films for Application in SOFC Metallic Interconnects, Appl. Surf. Sci., 2008, 255, p 1850–185910.1016/j.apsusc.2008.06.052 ↗
35. B. Hua, W. Zhang, J. Wu, J. Pu, B. Chi, and L. Jian, A Promising NiCo2O4 Protective Coating for Metallic Interconnects of Solid Oxide Fuel Cells, J. Power Sources., 2010, 195(21), p 7375–737910.1016/j.jpowsour.2010.05.031 ↗
36. Y. Liu and D.Y. Chen, Protective Coatings for Cr2O3-Forming Interconnects of Solid Oxide Fuel Cells, Int. J. Hydrogen Energy., 2009, 34(22), p 9220–922610.1016/j.ijhydene.2009.09.022 ↗
37. S. Geng, S. Qi, Q. Zhao, S. Zhu, and F. Wang, Electroplated Ni-Fe2O3 Composite Coating for Solid Oxide Fuel Cell Interconnect Application, Int. J. Hydrogen Energy., 2012, 37(14), p 10850–1085610.1016/j.ijhydene.2012.04.043 ↗
38. S. Geng, Q. Wang, W. Wang, S. Zhu, and F. Wang, Sputtered Ni Coating on Ferritic Stainless Steel for Solid Oxide Fuel Cell Interconnect Application, Int. J. Hydrogen Energy., 2012, 37(1), p 916–92010.1016/j.ijhydene.2011.03.160 ↗
39. C. Kaya, F. Kaya, B. Su, B. Thomas, and A.R. Boccaccini, Structural and Functional Thick Ceramic Coatings by Electrophoretic Deposition, Surf. Coat. Technol., 2005, 191(2-3), p 303–31010.1016/j.surfcoat.2004.03.042 ↗
40. L. Besra and M. Liu, A Review on Fundamentals and Applications of Electrophoretic Deposition (EPD), Prog. Mater. Sci., 2007, 52(1), p 1–6110.1016/j.pmatsci.2006.07.001 ↗
41. F. Tang, T. Uchikoshi, K. Ozawa, and Y. Sakka, Effect of Poly Ethylene Imine on the Dispersion and Electrophoretic Deposition of Nano-Sized Titania Aqueous Suspensions, J. Eur. Ceram. Soc., 2006, 26, p 1555–156010.1016/j.jeurceramsoc.2005.03.240 ↗
42. C.C. Chen, C.S. Jwo, and T.P. Teng, Decomposition of Formaldehyde by EPD Photo Catalyst Filters in HVAC, Particuology., 2011, 9(5), p 497–50110.1016/j.partic.2011.02.008 ↗
43. A.A. Sadeghi, T. Ebadzadeh, B. Raissi, S. Ghashghaie, and S.M.A. Fateminia, Application of the Multi-Step EPD Technique to Fabricate Thick TiO2 Layers: Effect of Organic Medium Viscosity on the Layer Microstructure, J. Phys. Chem. B., 2013, 117(6), p 1731–173710.1021/jp306976p ↗
44. W.J. Quadakkers, J. Piron-Abellan, V. Shemet, and L. Singheiser, Metallic Interconnectors for Solid Oxide Fuel Cells: A Review, Mater. High Temp., 2003, 20, p 115
45. C. Wagner, Z. Phys. Chem. B, 1933, 21, p 4210.1515/zpch-1933-2106 ↗
46. W. Qu et al., Yttrium, Cobalt and Yttrium/Cobalt Oxide Coatings on Ferritic Stainless Steels for SOFC Interconnects, J. Power Sources., 2006, 157(1), p 335–35010.1016/j.jpowsour.2005.07.052 ↗
47. H. Ebrahimifar and M. Zandrahimi, Oxidation and Electrical Behavior of AISI, 430 Coated with Cobalt Spinels for SOFC Interconnect Applications, Surf. Coat. Technol., 2011, 206(1), p 75–8110.1016/j.surfcoat.2011.06.046 ↗
48. B. Hua et al., Cyclic oxidation of Mn-Co spinel coated SUS 430 alloy in the cathodic atmosphere of solid oxide fuel cells, Journal of Power Sources., 2008, 185(1), p 419–42210.1016/j.jpowsour.2008.06.055 ↗
49. W. Wei et al., Oxidation Resistance and Electrical Properties of Anodically Electrodeposited Mn-Co Oxide Coatings for Solid Oxide Fuel Cell Interconnect Applications, J. Power Sources., 2009, 186(2), p 428–43410.1016/j.jpowsour.2008.09.114 ↗
50. X. Chen et al., Protective Coatings on Stainless Steel Interconnect for SOFCs: Oxidation Kinetics and Electrical Properties, Solid State Ionics., 2005, 176(5-6), p 425–43310.1016/j.ssi.2004.10.004 ↗
51. P. Jian et al., Oxidation Kinetics and Phase Evolution of a Fe-16Cr Alloy in Simulated SOFC Cathode Atmosphere, J. Power Sources., 2006, 158(1), p 354–36010.1016/j.jpowsour.2005.09.056 ↗
52. S. Geng et al., Evaluation of Electrodeposited Fe-Ni Alloy on Ferritic Stainless Steel Solid Oxide Fuel Cell Interconnect, J. Power Sources., 2010, 195(10), p 3256–326010.1016/j.jpowsour.2009.12.007 ↗