journal article·2024-09Open access

Design of Non-Heat Treatable High Pressure Die Casting Al Alloys: A Review

Hongyi Zhu, Cunjuan Xia, Huawei Zhang, Dechao Zhao, Mingliang Wang, Haowei Wang

Abstract

In recent years, Non-Heat Treatable High Pressure Die Casting Al alloys (NHT-HPDC Al alloys) have been proposed and developed for integrated die casting in the automotive industry. These alloys exhibit excellent castability and can achieve sufficient mechanical properties without the need for heat treatment. Despite their industrial significance, there is a lack of an updated and comprehensive description of such alloys. The insufficient availability of literature and the absence of a systematic design mentality have hindered their development. Therefore, this study reviews several aspects of NHT-HPDC Al alloys. Firstly, the NHT-HPDC Al alloys are divided into Al-Si, Al-Mg-Si and Al-Fe-Mg alloys, with the NHT-HPDC Al-Si alloys being the mainstream. The solidification behaviors of NHT-HPDC Al-Si-(Cu)-(Mg) alloys are discussed using phase diagram analyses. Secondly, the manipulation of critical phases is discussed, including: (i) impurity phase: Fe-rich phase (the neutralization treatment); (ii) strengthening phases: Eutectic Si phase (the modification treatment)/main alloying elements regulating phases/trace alloying elements regulating phases/ceramic particles. Thirdly, the typical three regions of NHT-HPDC Al-Si components and their formation mechanisms are identified and reviewed. Then, the influence of vacuum assistance and intensification pressure to the general quality of NHT-HPDC Al-Si components is comprehensively discussed. Finally, future challenges for NHT-HPDC Al-Si alloys are also proposed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Aluminum Alloy Microstructure Properties · Aluminum Alloys Composites Properties · Microstructure and mechanical properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. D. Castelvecchi, How the Hydrogen Revolution can Help Save the Planet — and How it can’t, Nature, 2022, 611, p 440–443. https://doi.org/10.1038/d41586-022-03699-010.1038/d41586-022-03699-0 ↗
2. A.I. Taub and A.A. Luo, Advanced Lightweight Materials and Manufacturing Processes for Automotive Applications, MRS Bull., 2015, 40, p 1045–1054. https://doi.org/10.1557/mrs.2015.26810.1557/mrs.2015.268 ↗
3. F. Czerwinski, Current Trends in Automotive Lightweighting Strategies and Materials, Materials, 2021, 14, p 6631. https://doi.org/10.3390/ma1421663110.3390/ma14216631 ↗
4. W. Zhang and J. Xu, Advanced Lightweight Materials for Automobiles: A Review, Mater. Des., 2022, 221, p 110994. https://doi.org/10.1016/j.matdes.2022.11099410.1016/j.matdes.2022.110994 ↗
5. F. Casarotto, A.J. Franke and R. Franke, High-pressure die-cast (HPDC) Aluminium Alloys for Automotive Applications, Advanced Materials in Automotive Engineering. J. Rowe Ed., Woodhead Publishing, 2012, p 109–14910.1533/9780857095466.109 ↗
6. M. Hartlieb, Aluminum Alloys for Structural Die Casting, Die Casting Engineer, 2013, 57, p 40–43.
7. T. Liu, Z. Pei, D. Barton, G.B. Thompson and L.N. Brewer, Characterization of Nanostructures in a high Pressure Die Cast Al-Si-Cu Alloy, Acta Mater., 2022, 224, p 117500. https://doi.org/10.1016/j.actamat.2021.11750010.1016/j.actamat.2021.117500 ↗
8. L. Wang, M. Makhlouf and D. Apelian, Aluminium Die Casting Alloys: Alloy Composition, Microstructure, and Properties-Performance Relationships, Int. Mater. Rev., 1995, 40, p 221–238. https://doi.org/10.1179/imr.1995.40.6.22110.1179/imr.1995.40.6.221 ↗
9. C.M. Dinnis, J.A. Taylor and A.K. Dahle, As-Cast Morphology of Iron-Intermetallics in Al-Si Foundry Alloys, Scr. Mater., 2005, 53, p 955–958. https://doi.org/10.1016/j.scriptamat.2005.06.02810.1016/j.scriptamat.2005.06.028 ↗
10. G. Ubertalli, F. D’Aiuto, S. Plano and D. De Caro, High Strain Rate Behavior of Aluminum Die Cast Components, Procedia Struct. Integrity, 2016, 2, p 3617–3624. https://doi.org/10.1016/j.prostr.2016.06.45110.1016/j.prostr.2016.06.451 ↗
11. J. Hirsch, Recent Development in Aluminium for Automotive Applications, Trans. Nonferrous Met. Soc. China, 2014, 24, p 1995–2002. https://doi.org/10.1016/S1003-6326(14)63305-710.1016/S1003-6326(14)63305-7 ↗
12. Z. Hu, L. Wan, S. Wu, H. Wu and X. Liu, Microstructure and Mechanical Properties of High Strength Die-Casting Al-Mg-Si-Mn Alloy, Mater. Des., 2013, 46, p 451–456. https://doi.org/10.1016/j.matdes.2012.10.02010.1016/j.matdes.2012.10.020 ↗
13. Y.M. Kim, S.W. Choi, Y.C. Kim, C.S. Kang and S.K. Hong, The Influence of the Additional Fe and Mn in Al Alloy on the Die Soldering Phenomenon, J. Nanosci. Nanotechnol., 2016, 16, p 11252–11255. https://doi.org/10.1166/jnn.2016.1348810.1166/jnn.2016.13488 ↗
14. G.K. Sigworth and R.J. Donahue, The Metallurgy of Aluminum Alloys for Structural High-Pressure Die Castings, Int. J. Metalcast., 2021, 15, p 1031–1046. https://doi.org/10.1007/s40962-020-00535-x10.1007/s40962-020-00535-x ↗
15. X.G. Hu, Q. Zhu, S.P. Midson, H.V. Atkinson, H.B. Dong, F. Zhang and Y.L. Kang, Blistering in Semi-Solid Die Casting of Aluminium Alloys and its Avoidance, Acta Mater., 2017, 124, p 446–455. https://doi.org/10.1016/j.actamat.2016.11.03210.1016/j.actamat.2016.11.032 ↗
16. J. Zhang, E. Cinkilic, X. Huang, G.G. Wang, Y. Liu, J.P. Weiler and A.A. Luo, Optimization of T5 Heat Treatment in high Pressure Die Casting of Al-Si-Mg-Mn Alloys by Using an Improved Kampmann-Wagner Numerical (KWN) Model, Mater. Sci. Eng. A, 2023, 865, p 144604. https://doi.org/10.1016/j.msea.2023.14460410.1016/j.msea.2023.144604 ↗
17. U.E.T. Baser and V. Akinci, New Trends in Aluminum Die Casting Alloys for Automotive Applications, EPSTEM, 2022, 21, p 79–87. https://doi.org/10.55549/epstem.122754110.55549/epstem.1227541 ↗
18. S.K. Das, H.W. Hayden and G.B. Barthold, Development of Non-Heat-Treatable Automotive Aluminum Sheet Alloys, Mater. Sci. Forum, 2000, 331–337, p 913–920. https://doi.org/10.4028/www.scientific.net/MSF.331-337.91310.4028/www.scientific.net/MSF.331-337.913 ↗
19. BEALS, Randolf, Scott, Process for Low-Cost tempering of Aluminum Casting, US patent 2022/0228242 A1, 2022 Jul 21.
20. L.Y. Yuan, P.W. Han, G. Asghar, B.L. Liu, J.P. Li, B. Hu, P.H. Fu and L.M. Peng, Development of High Strength and Toughness Non-Heated Al-Mg-Si Alloys for High-Pressure Die-Casting, Acta Metall. Sin. (Engl. Lett.), 2021, 34, p 845–860. https://doi.org/10.1007/s40195-020-01174-110.1007/s40195-020-01174-1 ↗
21. G. Soares, R. Neto, R. Madureira, R. Soares, J. Silva, R.P. Silva and L. Araújo, Characterization of Al Alloys Injected Through Vacuum-Assisted HPDC and Influence of T6 Heat Treatment, Metals, 2023, 13, p 389. https://doi.org/10.3390/met1302038910.3390/met13020389 ↗
22. C. Hu, H. Zhu, Y. Wang, C. Xia, J. Geng, D. Chen, H. Zhang, M. Wang and H. Wang, Microstructure Features and Mechanical Properties of Non-Heat Treated HPDC Al9Si0.6Mn-TiB2 Alloys, J. Mater. Res. Technol., 2023, 27, p 2117–2131. https://doi.org/10.1016/j.jmrt.2023.10.06010.1016/j.jmrt.2023.10.060 ↗
23. N. Rokon, M.S. Haque and M. Kaiser, On the Mechanical Behaviour of Thermally Affected Non-Heat-Treatable Aluminium Alloys, J. Chem. Technol. Metall., 2023, 58, p 1153–1162. https://doi.org/10.59957/jctm.v58i6.15610.59957/jctm.v58i6.156 ↗
24. R.E. Sanders, S.F. Baumann and H.C. Stumpf, Wrought Non-Heat-Treatable Aluminum Alloy, Treatise on Materials Science & Technology. A.K. Vasudevan, R.D. Doherty Ed., Elsevier, NJ, 1989, p 65–105
25. M. Rix, B. Kujat, T. Meisen and S. Jeschke, An Agile Information Processing Framework for High Pressure Die Casting Applications in Modern Manufacturing Systems, Procedia CIRP, 2016, 41, p 1084–1089. https://doi.org/10.1016/j.procir.2015.12.13410.1016/j.procir.2015.12.134 ↗
26. Z. Niu, G. Liu, T. Li and S. Ji, Effect of High Pressure Die Casting on the Castability, Defects and Mechanical Properties of Aluminium Alloys in Extra-Large Thin-Wall Castings, J. Mater. Process. Technol., 2022, 303, p 117525. https://doi.org/10.1016/j.jmatprotec.2022.11752510.1016/j.jmatprotec.2022.117525 ↗
27. D. Blondheim and A. Monroe, Macro Porosity Formation: A Study in High pressure Die Casting, Int. J. Metalcast., 2022, 16, p 330–341. https://doi.org/10.1007/s40962-021-00602-x10.1007/s40962-021-00602-x ↗
28. R. Hu, C. Guo and M. Ma, A Study on High Strength High Plasticity, Non-Heat Treated Die-Cast Aluminum Alloy, Materials, 2022, 15, p 295.10.3390/ma15010295 ↗
29. X. Dong, H. Yang, X. Zhu and S. Ji, High Strength and Ductility Aluminium Alloy Processed by High Pressure Die Casting, J. Alloys Compd., 2019, 773, p 86–96. https://doi.org/10.1016/j.jallcom.2018.09.26010.1016/j.jallcom.2018.09.260 ↗
30. X. Zhu, X. Dong, P. Blake and S. Ji, Improvement in as-cast Strength of High Pressure Die-Cast Al-Si-Cu-Mg Alloys by Synergistic Effect of Q-Al5Cu2Mg8Si6 and θ-Al2Cu Phases, Mater. Sci. Eng. A, 2021, 802, p 140612. https://doi.org/10.1016/j.msea.2020.14061210.1016/j.msea.2020.140612 ↗
31. A. Graf, Aluminum Alloys for Lightweight Automotive Structures, Materials, Design and Manufacturing for Lightweight Vehicles, 2nd ed., P.K. Mallick Ed., Woodhead Publishing, NJ, 2021, p 97–12310.1016/B978-0-12-818712-8.00003-3 ↗
32. H.L. Chen, Q. Chen, Y. Du, J. Bratberg and A. EngstrÖM, Update of Al-Fe-Si, Al-Mn-Si and Al-Fe-Mn-Si Thermodynamic Descriptions, Trans. Nonferrous Met. Soc. China, 2014, 24, p 2041–2053. https://doi.org/10.1016/S1003-6326(14)63310-010.1016/S1003-6326(14)63310-0 ↗
33. RHEINFELDEN, Families of Alloys. https://rheinfelden-alloys.eu/en/alloys/, 2023 (accessed 6 September 2023).
34. Alcoa, Advanced Aluminum Alloys. https://www.alcoa.com/global/en/what-we-do/aluminum/cast-products/foundry-aluminum-alloys, 2023 (accessed 6 September 2023).
35. J. Stucki, G. Pattinson, Q. Hamill, A. Prabhu, S. Palanivel, O. Lopez-Garri-Ty, Die Cast Aluminum Alloys for Structural Components, WO Patent 2021/150604 A1 2021
36. S. Ji, D. Watson, Z. Fan and M. White, Development of a Super Ductile Diecast Al-Mg-Si Alloy, Mater. Sci. Eng. A, 2012, 556, p 824–833. https://doi.org/10.1016/j.msea.2012.07.07410.1016/j.msea.2012.07.074 ↗
37. X. Dong, X. Zhu and S. Ji, Effect of Super Vacuum Assisted High Pressure Die Casting on the Repeatability of Mechanical Properties of Al-Si-Mg-Mn Die-Cast Alloys, J. Mater. Process. Technol., 2019, 266, p 105–113. https://doi.org/10.1016/j.jmatprotec.2018.10.03010.1016/j.jmatprotec.2018.10.030 ↗
38. F. Liu, H. Zheng, Y. Zhong, Y. Jiang, X. Li, B. Chen and H. Zhao, Effect of Cu/Mg-Containing Intermetallics on the Mechanical Properties of the As-Cast HVDC AlSiMgMnCu Alloys by SBFSEM at Nano-Scale, J. Alloys Compd., 2022, 926, p 166837. https://doi.org/10.1016/j.jallcom.2022.16683710.1016/j.jallcom.2022.166837 ↗
39. P. Zhang, Z. Li, B. Liu and W. Ding, Tensile Properties and Deformation Behaviors of a New Aluminum Alloy for High Pressure Die Casting, J. Mater. Sci. Technol., 2017, 33, p 367–378. https://doi.org/10.1016/j.jmst.2016.02.01310.1016/j.jmst.2016.02.013 ↗
40. X. Zhu, P. Blake, K. Dou and S. Ji, Strengthening Die-Cast Al-Mg and Al-Mg-Mn Alloys with Fe as a Beneficial element, Mater. Sci. Eng. A, 2018, 732, p 240–250. https://doi.org/10.1016/j.msea.2018.07.00510.1016/j.msea.2018.07.005 ↗
41. X. Fang, G. Shao, Y.Q. Liu and Z. Fan, Effects of Intensive Forced Melt Convection on the Mechanical Properties of Fe Containing Al-Si Based Alloys, Mater. Sci. Eng. A, 2007, 445–446, p 65–72. https://doi.org/10.1016/j.msea.2006.09.03810.1016/j.msea.2006.09.038 ↗
42. E. Samuel, A.M. Samuel, H.W. Doty, S. Valtierra and F.H. Samuel, Intermetallic Phases in Al-Si Based Cast Alloys: New Perspective, Int. J. Cast Met. Res., 2014, 27, p 107–114. https://doi.org/10.1179/1743133613Y.000000008310.1179/1743133613Y.0000000083 ↗
43. X. Dong, H. Youssef, Y. Zhang, S. Wang and S. Ji, High Performance Al/TiB2 Composites Fabricated by Nanoparticle Reinforcement and Cutting-Edge Super Vacuum Assisted Die Casting Process, Compos. B, 2019, 177, p 107453. https://doi.org/10.1016/j.compositesb.2019.10745310.1016/j.compositesb.2019.107453 ↗
44. J. Rakhmonov, G. Timelli and F. Bonollo, The Effect of Transition Elements on High-Temperature Mechanical Properties of Al-Si Foundry Alloys-a Review, Adv. Eng. Mater., 2016, 18, p 1096–1105. https://doi.org/10.1002/adem.20150046810.1002/adem.201500468 ↗
45. H.Y. Kim, T.Y. Park, S.W. Han and H.M. Lee, Effects of Mn on the Crystal Structure of α-Al(Mn, Fe)Si Particles in A356 Alloys, J. Cryst. Growth, 2006, 291, p 207–211. https://doi.org/10.1016/j.jcrysgro.2006.02.00610.1016/j.jcrysgro.2006.02.006 ↗
46. M.V. Kral, A Crystallographic Identification of Intermetallic Phases in Al-Si Alloys, Mater. Lett., 2005, 59, p 2271–2276. https://doi.org/10.1016/j.matlet.2004.05.09110.1016/j.matlet.2004.05.091 ↗
47. T.O. Mbuya, B.O. Odera and S.P. Ng’ang’a, Influence of Iron on Castability and Properties of Aluminium Silicon Alloys: Literature Review, Int. J. Cast Met. Res., 2003, 16, p 451–465. https://doi.org/10.1080/13640461.2003.1181962210.1080/13640461.2003.11819622 ↗
48. X.Y. Jiao, C.F. Liu, Z.P. Guo, G.D. Tong, S.L. Ma, Y. Bi, Y.F. Zhang and S.M. Xiong, The Characterization of Fe-Rich Phases in a High-Pressure Die Cast Hypoeutectic Aluminum-Silicon Alloy, J. Mater. Sci. Technol., 2020, 51, p 54–62. https://doi.org/10.1016/j.jmst.2020.02.04010.1016/j.jmst.2020.02.040 ↗
49. J.A. Taylor, Iron-Containing Intermetallic Phases in Al-Si Based Casting Alloys, Procedia, Mater. Sci., 2012, 1, p 19–33. https://doi.org/10.1016/j.mspro.2012.06.00410.1016/j.mspro.2012.06.004 ↗
50. X. Shen, S. Liu, X. Wang, C. Cui, P. Gong, L. Zhao, X. Han and Z. Li, Effect of Cooling Rate on the Microstructure Evolution and Mechanical Properties of iron-Rich Al-Si Alloy, Materials, 2022, 15, p 411.10.3390/ma15020411 ↗
51. X. Zhang, D. Wang, Y. Zhou, X. Chong, X. Li, H. Zhang and H. Nagaumi, Exploring Crystal Structures, Stability and Mechanical Properties of Fe, Mn-Containing Intermetallics in Al-Si Alloy by Experiments and First-Principles Calculations, J. Alloys Compd., 2021, 876, p 160022. https://doi.org/10.1016/j.jallcom.2021.16002210.1016/j.jallcom.2021.160022 ↗
52. L.A. Narayanan, F.H. Samuel and J.E. Gruzleski, Crystallization Behavior of Iron-Containing Intermetallic Compounds in 319 Aluminum Alloy, Metall. Mater. Trans. A, 1994, 25, p 1761–1773. https://doi.org/10.1007/BF0266854010.1007/BF02668540 ↗
53. B. Wang, J. Wang, X. Liu, Q. Li and X. Liu, Uncovering the Effects of Neutralizing Elements (Co, Mn and Cr) on the Fe-Rich Intermetallic Formation in Al-Si-Cu Alloys, Mater. Sci. Eng. A, 2022, 858, p 144090. https://doi.org/10.1016/j.msea.2022.14409010.1016/j.msea.2022.144090 ↗
54. G. Gustafsson, T. Thorvaldsson and G.L. Dunlop, The Influence of Fe and Cr on the Microstructure of Cast Al-Si-Mg Alloys, Metall. Trans. A, 1986, 17, p 45–52. https://doi.org/10.1007/BF0264444110.1007/BF02644441 ↗
55. S.G. Shabestari, The Effect of Iron and Manganese on the Formation of Intermetallic Compounds in Aluminum-Silicon Alloys, Mater. Sci. Eng. A, 2004, 383, p 289–298. https://doi.org/10.1016/j.msea.2004.06.02210.1016/j.msea.2004.06.022 ↗
56. S. Ferraro, A. Bjurenstedt and S. Seifeddine, On the Formation of Sludge Intermetallic Particles in Secondary Aluminum Alloys, Metall. Mater. Trans. A, 2015, 46A, p 3713–3722. https://doi.org/10.1007/s11661-015-2942-010.1007/s11661-015-2942-0 ↗
57. Y. Fu, G.G. Wang, A. Hu, Y. Li, K.B. Thacker, J.P. Weiler and H. Hu, Formation, Characteristics and Control of Sludge in Al-Containing Magnesium Alloys: An Overview, J. Magnesium Alloys, 2022, 10, p 599–613. https://doi.org/10.1016/j.jma.2021.11.03110.1016/j.jma.2021.11.031 ↗
58. P.N. Crepeau, Effect of Iron in Al-Si Casting Alloys: a critical Review, AFS Transactions, 1995, 103, p 361–366.
59. S. Ferraro and G. Timelli, Influence of sludge particles on the Tensile Properties of Die-Cast Secondary Aluminum Alloys, Metall. Mater. Trans. B, 2015, 46, p 1022–1034. https://doi.org/10.1007/s11663-014-0260-310.1007/s11663-014-0260-3 ↗
60. M. Kohlhepp, P.J. Uggowitzer, M. Hummel and H.W. Höppel, Formation of Die Soldering and the Influence of Alloying Elements on the Intermetallic Interface, Materials, 2021, 14, p 1580.10.3390/ma14071580 ↗
61. Q. Han and S. Viswanathan, Analysis of the Mechanism of Die Soldering in Aluminum Die Casting, Metall. Mater. Trans. A, 2003, 34, p 139–146. https://doi.org/10.1007/s11661-003-0215-910.1007/s11661-003-0215-9 ↗
62. J.Y. Hwang, H.W. Doty and M.J. Kaufman, The Effects of Mn Additions on the Microstructure and Mechanical Properties of Al-Si-Cu Casting Alloys, Mater. Sci. Eng. A, 2008, 488, p 496–504. https://doi.org/10.1016/j.msea.2007.12.02610.1016/j.msea.2007.12.026 ↗
63. Z. Li, N. Limodin, A. Tandjaoui, P. Quaegebeur, P. Osmond and D. Balloy, Influence of Sr, Fe and Mn Content and Casting Process on the Microstructures and Mechanical Properties of AlSi7Cu3 Alloy, Mater. Sci. Eng. A, 2017, 689, p 286–297. https://doi.org/10.1016/j.msea.2017.02.04110.1016/j.msea.2017.02.041 ↗
64. B. Lin, H. Li, R. Xu, H. Xiao, W. Zhang and S. Li, Effects of Vanadium on Modification of Iron-Rich Intermetallics and Mechanical Properties in A356 cast Alloys with 1.5 wt.%Fe, J. Mater. Eng. Perform., 2019, 28, p 475–484. https://doi.org/10.1007/s11665-018-3798-410.1007/s11665-018-3798-4 ↗
65. R. Qin, R.F. Yan, Z.P. Guan, G.Q. Zhang, J.W. Song, M.W. Ren and J.G. Wang, Effect of Vanadium on Fe-Rich Phase, Mechanical Properties and Thermal Conductivity of Hypoeutectic Al-Si Alloy, Mater. Res. Express, 2021, 8, p 026518. https://doi.org/10.1088/2053-1591/abe5f010.1088/2053-1591/abe5f0 ↗
66. S.S. Sreeja Kumari, R.M. Pillai, T.P.D. Rajan and B.C. Pai, Effects of Individual and Combined Additions of Be, Mn, Ca and Sr on the Solidification Behaviour, Structure and Mechanical Properties of Al-7Si-0.3Mg-0.8Fe Alloy, Mater. Sci. Eng. A, 2007, 460–461, p 561–573. https://doi.org/10.1016/j.msea.2007.01.08210.1016/j.msea.2007.01.082 ↗
67. M. Rejaeian, M. Karamouz, M. Emamy and M. Hajizamani, Effects of Be Additions on Microstructure, Hardness and Tensile Properties of A380 Aluminum Alloy, Nonferrous Met. Soc. China., 2015, 25, p 3539–3545. https://doi.org/10.1016/S1003-6326(15)63951-610.1016/S1003-6326(15)63951-6 ↗
68. M. Wang, Y. Guo, H. Wang and S. Zhao, Characterization of Refining the Morphology of Al-Fe-Si in A380 Aluminum Alloy Due to Ca Addition, Processes, 2022, 10, p 672.10.3390/pr10040672 ↗
69. M. Sha, S. Wu, X. Wang and L. Wan, Effects of Co Addition on Fe-Bearing Intermetallic Compounds and Mechanical Properties of AlSi20Cu2Ni1Fe0.7-1 Alloys, J. Alloys Compd., 2013, 551, p 468–474. https://doi.org/10.1016/j.jallcom.2012.10.18110.1016/j.jallcom.2012.10.181 ↗
70. B. Wan, W. Chen, L. Liu, X. Cao, L. Zhou and Z. Fu, Effect of Trace Yttrium Addition on the Microstructure and Tensile Properties of Recycled Al-7Si-0.3Mg-1.0Fe Casting Alloys, Mater. Sci. Eng. A, 2016, 666, p 165–175. https://doi.org/10.1016/j.msea.2016.04.03610.1016/j.msea.2016.04.036 ↗
71. G.K. Sigworth, The Modification of Al-Si Casting Alloys: Important Practical and Theoretical Aspects, Int. J. Metalcast., 2008, 2, p 19–40. https://doi.org/10.1007/BF0335542510.1007/BF03355425 ↗
72. M.R.S. Ganesh, N. Reghunath, M.J. Levin, A. Prasad, S. Doondi and K.V. Shankar, Strontium in Al-Si-Mg Alloy: A Review, Met. Mater. Int., 2022, 28, p 1–40. https://doi.org/10.1007/s12540-021-01054-y10.1007/s12540-021-01054-y ↗
73. S. Moniri and A.J. Shahani, Chemical Modification of Degenerate Eutectics: A Review of Recent Advances and Current Issues, J. Mater. Res., 2019, 34, p 20–34. https://doi.org/10.1557/jmr.2018.36110.1557/jmr.2018.361 ↗
74. S.C. Flood and J.D. Hunt, Modification of Al-Si Eutectic Alloys with Na, Metal, Science, 1981, 15, p 287–294. https://doi.org/10.1179/03063458179042681310.1179/030634581790426813 ↗
75. P. Srirangam, M.J. Kramer and S. Shankar, Effect of Strontium on Liquid Structure of Al-Si Hypoeutectic alloys Using High-Energy X-ray Diffraction, Acta Mater., 2011, 59, p 503–513. https://doi.org/10.1016/j.actamat.2010.09.05010.1016/j.actamat.2010.09.050 ↗
76. M. Timpel, N. Wanderka, R. Schlesiger, T. Yamamoto, N. Lazarev, D. Isheim, G. Schmitz, S. Matsumura and J. Banhart, The Role of Strontium in Modifying Aluminium-Silicon Alloys, Acta Mater., 2012, 60, p 3920–3928. https://doi.org/10.1016/j.actamat.2012.03.03110.1016/j.actamat.2012.03.031 ↗
77. L. Chang, Y. Ding, B. Guo, J. Ding, X. Xia, Y. Tang, C. Li, X. Sun, J. Guo, K. Song, L. Wang, K. Zhou, X. Chen and Y. Liu, Modification Mechanism and Tensile Property of Al-9Si-0.4Mg-0.1Cu Alloy, Mater. Charact., 2022, 184, p 111693. https://doi.org/10.1016/j.matchar.2021.11169310.1016/j.matchar.2021.111693 ↗
78. J.E. Gruzleski, B.M. Closset, A.F.s. Society, The Treatment of Liquid Aluminum-Silicon Alloys, American Foundrymen's Society Sigworth, 1990, https://api.semanticscholar.org/CorpusID:135795085.
79. X.F. Bian, Z.H. Zhang, X.F. Liu, Effect of Strontium Modification on Hydrogen Content and Porosity Shape of Al-Si Alloys, Mater. Sci. Forum 331-337 (2000) 361-366, https://www.scientific.net/MSF.331-337.361.10.4028/www.scientific.net/MSF.331-337.361 ↗
80. W. Zhang, S. Ma, Z. Wei, P. Bai, The Relationship Between Residual Amount of Sr and Morphology of Eutectic Si Phase in A356 Alloy, Materials 12 (2019) 3222, https://www.mdpi.com/1996-1944/12/19/3222.10.3390/ma12193222 ↗
81. Q. Wang, Q. Hao and W. Yu, Effect of Strontium Modification on Porosity Formation in A356 Alloy, Int. J. Metalcast., 2019, 13, p 944–952. https://doi.org/10.1007/s40962-018-00300-110.1007/s40962-018-00300-1 ↗
82. P.D. Lee and S. Sridhar, Direct Observation of the Effect of Strontium on Porosity Formation During the Solidification of Aluminium-Silicon Alloys, Int. J. Cast Met. Res., 2000, 13, p 185–198. https://doi.org/10.1080/13640461.2000.1181940110.1080/13640461.2000.11819401 ↗
83. F. Mao, S. Wei, C. Chen, C. Zhang, X. Wang and Z. Cao, Modification of the Silicon Phase and Mechanical Properties in Al-40Zn-6Si Alloy with Eu Addition, Mater. Des., 2020, 186, p 108268. https://doi.org/10.1016/j.matdes.2019.10826810.1016/j.matdes.2019.108268 ↗
84. P. Pandee, U. Patakham and C. Limmaneevichitr, Microstructural Evolution and Mechanical Properties of Al-7Si-0.3Mg Alloys with Erbium Additions, J. Alloys Compd., 2017, 728, p 844–853. https://doi.org/10.1016/j.jallcom.2017.09.05410.1016/j.jallcom.2017.09.054 ↗
85. Z. Shi, Q. Wang, Y. Shi, G. Zhao and R. Zhang, Microstructure and Mechanical Properties of Gd-Modified A356 Aluminum Alloys, J. Rare Earths, 2015, 33, p 1004–1009. https://doi.org/10.1016/S1002-0721(14)60518-410.1016/S1002-0721(14)60518-4 ↗
86. R. Ahmad and M.B.A. Asmael, Influence of Lanthanum on Solidification, Microstructure, and Mechanical Properties of Eutectic Al-Si Piston Alloy, J. Mater. Eng. Perform., 2016, 25, p 2799–2813. https://doi.org/10.1007/s11665-016-2139-810.1007/s11665-016-2139-8 ↗
87. Y.C. Tsai, C.Y. Chou, S.L. Lee, C.K. Lin, J.C. Lin and S.W. Lim, Effect of Trace La Addition on the Microstructures and Mechanical Properties of A356 (Al-7Si-0.35Mg) Aluminum Alloys, J. Alloys Compd., 2009, 487, p 157–162. https://doi.org/10.1016/j.jallcom.2009.07.18310.1016/j.jallcom.2009.07.183 ↗
88. W. Liu, W. Xiao, C. Xu, M. Liu and C. Ma, Synergistic Effects of Gd and Zr on Grain Refinement and Eutectic Si Modification of Al-Si Cast Alloy, Mater. Sci. Eng. A, 2017, 693, p 93–100. https://doi.org/10.1016/j.msea.2017.03.09710.1016/j.msea.2017.03.097 ↗
89. H. Qiu, H. Yan and Z. Hu, Effect of Samarium (Sm) Addition on the Microstructures and Mechanical Properties of Al-7Si-0.7Mg Alloys, J. Alloys Compd., 2013, 567, p 77–81. https://doi.org/10.1016/j.jallcom.2013.03.05010.1016/j.jallcom.2013.03.050 ↗
90. S.Z. Lu and A. Hellawell, The Mechanism of Silicon Modification in Aluminum-Silicon Alloys: Impurity Induced Twinning, Metall. Trans. A, 1987, 18, p 1721–1733. https://doi.org/10.1007/BF0264620410.1007/BF02646204 ↗
91. K. Nogita, H. Yasuda, M. Yoshiya, S.D. McDonald, K. Uesugi, A. Takeuchi and Y. Suzuki, The Role of Trace Element Segregation in the Eutectic Modification of Hypoeutectic Al-Si Alloys, J. Alloys Compd., 2010, 489, p 415–420. https://doi.org/10.1016/j.jallcom.2009.09.13810.1016/j.jallcom.2009.09.138 ↗
92. J.H. Li, X.D. Wang, T.H. Ludwig, Y. Tsunekawa, L. Arnberg, J.Z. Jiang and P. Schumacher, Modification of Eutectic Si in Al-Si Alloys with Eu Addition, Acta Mater., 2015, 84, p 153–163. https://doi.org/10.1016/j.actamat.2014.10.06410.1016/j.actamat.2014.10.064 ↗
93. Q. Zheng, L. Zhang, H. Jiang, J. Zhao and J. He, Effect Mechanisms of Micro-Alloying Element La on Microstructure and Mechanical Properties of Hypoeutectic Al-Si alloys, J. Mater. Sci. Technol., 2020, 47, p 142–151. https://doi.org/10.1016/j.jmst.2019.12.02110.1016/j.jmst.2019.12.021 ↗
94. Q. Li, S. Zhao, B. Li, Y. Zhu, J. Liu, D. Liu, Y. Lan and T. Xia, Modification of Multi-Component Al-Si Casting Piston Alloys by Addition of Rare Earth Yttrium, Mater. Res. Express, 2019, 6, p 106525. https://doi.org/10.1088/2053-1591/ab36fc10.1088/2053-1591/ab36fc ↗
95. L. Shuai, X. Zou, Y. Rao, X. Lu and H. Yan, Synergistic Effects of La and Y on the Microstructure and Mechanical Properties of Cast Al-Si-Cu Alloys, Materials, 2022, 15, p 7283.10.3390/ma15207283 ↗
96. Y. Cao, X. Chen, Z. Wang, K. Chen, S. Pan, Y. Zhu and Y. Wang, Synergistic Influence of La and Zr on Microstructure and Mechanical Performance of an Al-Si-Mg Alloy at Casting State, J. Alloys Compd., 2022, 902, p 163829. https://doi.org/10.1016/j.jallcom.2022.16382910.1016/j.jallcom.2022.163829 ↗
97. M.G. Mahmoud, Y. Zedan, A.M. Samuel, V. Songmene and F.H. Samuel, The Use of Rare Earth Metals in Al-Si-Cu Casting Alloys, Int. J. Metalcast., 2022, 16, p 535–552. https://doi.org/10.1007/s40962-021-00640-510.1007/s40962-021-00640-5 ↗
98. U. Heo, D.W. Han, S. Kim and C.B. Mo, Microstructure, Mechanical, and Corrosion Properties of Al-10Si and Al-10Si-2Cu Alloys with Different La Contents, Mater. Today Commun., 2022, 32, p 104005. https://doi.org/10.1016/j.mtcomm.2022.10400510.1016/j.mtcomm.2022.104005 ↗
99. A.M. Samuel, E.M. Elgallad, M.G. Mahmoud, H.W. Doty, S. Valtierra and F.H. Samuel, Rare Earth Metal-Based Intermetallics Formation in Al-Cu-Mg and Al-Si-Cu-Mg Alloys: A Metallographic Study, Adv. Mater. Sci. Eng., 2018, 2018, p 7607465. https://doi.org/10.1155/2018/760746510.1155/2018/7607465 ↗
100. H. Yi, D. Zhang, T. Sakata and H. Mori, Microstructures and La-Rich Compounds in a Cu-Containing Hypereutectic Al-Si Alloy, J. Alloys Compd., 2003, 354, p 159–164. https://doi.org/10.1016/S0925-8388(03)00022-710.1016/S0925-8388(03)00022-7 ↗