Corrosion Inhibition of l-Methionine Amino Acid as a Green Corrosion Inhibitor for Stainless Steel in the H2SO4 Solution
Source abstract
Abstract
This study investigated the effect of l-methionine (LMT) on the corrosion behavior of AISI309S stainless steel in 1 M H2SO4 solution using electrochemical impedance spectroscopy (EIS), Tafel polarization, and electrochemical noise methods. The performance of corrosion inhibition was analyzed by scanning electron microscopy, atomic force microscopy, adsorption isotherms, x-ray photoelectron spectroscopy (XPS), and contact angle measurement. The electrochemical studies revealed a significant increase in the charge transfer resistance and a reduction in the corrosion current density in the presence of LMT in the acidic media. The results of the EIS and Tafel tests determined the corrosion inhibition efficiency to be about 97% and 95%, respectively. The microscopy analysis showed that the surface suffered lower corrosion damages in the presence of LMT. Besides, the adsorption of LMT on the anodic sites of the surface through its sulfur atom was verified by EIS and XPS studies.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · Concrete Corrosion and Durability
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
Show source-provided references
1. M. Mobin, M. Parveen, and M.Z.A. Rafiquee, Synergistic Effect of Sodium Dodecyl Sulfate and Cetyltrimethyl Ammonium Bromide on the Corrosion Inhibition Behavior of l-Methionine on Mild Steel in Acidic Medium, Arab. J. Chem., 2017, 10, p S1364–S1372. https://doi.org/10.1016/j.arabjc.2013.04.00610.1016/j.arabjc.2013.04.006 ↗
2. L. Hamadi, S. Mansouri, K. Oulmi, and A. Kareche, The Use of Amino Acids as Corrosion Inhibitors for Metals: A Review, Egypt. J. Pet., 2018, 27, p 1157–1165. https://doi.org/10.1016/j.ejpe.2018.04.00410.1016/j.ejpe.2018.04.004 ↗
3. J.A. Thangakani, S. Rajendran, J. Sathiabama, R.J. Rathish, and S. Santhanaprabha, Corrosion Inhibition of Carbon Steel in Well Water by l-Cysteine-Zn2+ System, Port. Electrochim. Acta, 2017, 35, p 13–25. https://doi.org/10.4152/pea.20170101310.4152/pea.201701013 ↗
4. M.S.S. Morad, A.E.-H.A. Hermas, and M.S. Abdel Aal, Effect of Amino Acids Containing Sulfur on the Corrosion of Mild Steel in Phosphoric Acid Solutions Polluted with Cl−, F− and Fe+3 Ions—Behaviour Near and at the Corrosion Potential, J. Chem. Technol. Biotechnol., 2002, 77, p 486–494. https://doi.org/10.1002/jctb.58810.1002/jctb.588 ↗
5. K.F. Khaled, Monte Carlo Simulations of Corrosion Inhibition of Mild Steel in 0.5 M Sulphuric Acid by Some Green Corrosion Inhibitors, J. Solid State Electrochem., 2009, 13, p 1743–1756. https://doi.org/10.1007/s10008-009-0845-y10.1007/s10008-009-0845-y ↗
6. E.B. Ituen, O. Akaranta, and S.A. Umoren, N-Acetyl Cysteine Based Corrosion Inhibitor Formulations for Steel Protection in 15% HCl Solution, J. Mol. Liq., 2017, 246, p 112–118. https://doi.org/10.1016/j.molliq.2017.09.04010.1016/j.molliq.2017.09.040 ↗
7. J.J. Fu, S.N. Li, Y. Wang, L.H. Cao, and L.D. Lu, Computational and Electrochemical Studies of Some Amino Acid Compounds as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution, J. Mater. Sci., 2010, 45, p 6255–6265. https://doi.org/10.1007/s10853-010-4720-010.1007/s10853-010-4720-0 ↗
8. Z. Zhang, W. Li, W. Zhang, X. Huang, L. Ruan, and L. Wu, Experimental, Quantum Chemical Calculations and Molecular Dynamics (MD) Simulation Studies of Methionine and Valine as Corrosion Inhibitors on Carbon Steel in Phase Change Materials (PCMs) Solution, J. Mol. Liq., 2018, 272, p 528–538. https://doi.org/10.1016/j.molliq.2018.09.08110.1016/j.molliq.2018.09.081 ↗
9. G.M.A. El-Hafez and W.A. Badawy, The Use of Cysteine, N-Acetyl Cysteine and Methionine as Environmentally Friendly Corrosion Inhibitors for Cu–10Al–5Ni Alloy in Neutral Chloride Solutions, Electrochim. Acta, 2013, 108, p 860–866. https://doi.org/10.1016/j.electacta.2013.06.07910.1016/j.electacta.2013.06.079 ↗
10. B. El Ibrahimi, A. Jmiai, L. Bazzi, and S. El Issami, Amino Acids and Their Derivatives as Corrosion Inhibitors for Metals and Alloys, Arab. J. Chem., 2017, https://doi.org/10.1016/j.arabjc.2017.07.01310.1016/j.arabjc.2017.07.013 ↗
11. M.S. Morad, Effect of Sulfur-Containing Amino Acids on the Corrosion of Mild Steel in Sulfide-Polluted Sulfuric Acid Solutions, J. Appl. Electrochem., 2007, 37, p 1191–1200. https://doi.org/10.1007/s10800-007-9386-110.1007/s10800-007-9386-1 ↗
12. M.A. Amin, K.F. Khaled, Q. Mohsen, and H.A. Arida, A Study of the Inhibition of Iron Corrosion in HCl Solutions by Some Amino Acids, Corros. Sci., 2010, 52, p 1684–1695. https://doi.org/10.1016/j.corsci.2010.01.01910.1016/j.corsci.2010.01.019 ↗
13. M. Zerfaouia, H. Oudda, B. Hammouti, S. Kertit, and M. Benkaddour, Inhibition of Corrosion of Iron in Citric Acid Media by Amino Acids, Prog. Org. Coat., 2004, 51, p 134–138. https://doi.org/10.1016/j.porgcoat.2004.05.00510.1016/j.porgcoat.2004.05.005 ↗
14. H. Ashassi-Sorkhabi, M.R. Majidi, and K. Seyyedi, Investigation of Inhibition Effect of Some Amino Acids Against Steel Corrosion in HCl Solution, Appl. Surf. Sci., 2004, 225, p 176–185. https://doi.org/10.1016/j.apsusc.2003.10.00710.1016/j.apsusc.2003.10.007 ↗
15. L.K.M.O. Goni, M.A.J. Mazumder, S.A. Ali, M.K. Nazal, and H.A. Al-Muallem, Biogenic Amino Acid Methionine-Based Corrosion Inhibitors of Mild Steel in Acidic Media, Int. J. Min. Metall. Mater., 2019, 26, p 467–482. https://doi.org/10.1007/s12613-019-1754-410.1007/s12613-019-1754-4 ↗
16. A.A. El-Shafei, M.N.H. Moussa, and A.A. El-Far, Inhibitory Effect of Amino Acids on Al Pitting Corrosion in 0.1 m NaCl, J. Appl. Electrochem., 1997, 27, p 1075–1078. https://doi.org/10.1023/A:101849072729010.1023/A:1018490727290 ↗
17. C. Zhu, H.X. Yang, Y.Z. Wang, D.Q. Zhang, and Y.C.X. Gao, Synergistic Effect Between Glutamic Acid and Rare Earth Cerium (III) as Corrosion Inhibitors on AA5052 Aluminum Alloy in Neutral Chloride Medium, Ionics, 2019, 25, p 1395–1406. https://doi.org/10.1007/s11581-018-2605-410.1007/s11581-018-2605-4 ↗
18. G. Gece and S. Bilgiç, A Theoretical Study on the Inhibition Efficiencies of Some Amino Acids as Corrosion Inhibitors of Nickel, Corros. Sci., 2010, 52, p 3435–3443. https://doi.org/10.1016/j.corsci.2010.06.01510.1016/j.corsci.2010.06.015 ↗
19. A.A. Aksüt and S. Bilgic, The Effect of Amino Acids on the Corrosion of Nickel in H2SO4, Corros. Sci., 1992, 33, p 379–387. https://doi.org/10.1016/0010-938X(92)90067-D10.1016/0010-938X(92)90067-D ↗
20. K. Barouni, L. Bazzi, R. Salghi, M. Mihit, B. Hammouti, A. Albourine, and S. El Issami, Some Amino Acids as Corrosion Inhibitors for Copper in Nitric Acid Solution, Mater. Lett., 2008, 62, p 3325–3327. https://doi.org/10.1016/j.matlet.2008.02.06810.1016/j.matlet.2008.02.068 ↗
21. K.F. Khaled, Corrosion Control of Copper in Nitric Acid Solutions Using Some Amino Acids—A Combined Experimental and Theoretical Study, Corros. Sci., 2010, 52, p 3225–3234. https://doi.org/10.1016/j.corsci.2010.05.03910.1016/j.corsci.2010.05.039 ↗
22. W.A. Badawy, K.M. Ismail, and A.M. Fathi, Corrosion Control of Cu–Ni Alloys in Neutral Chloride Solutions by Amino Acids, Electrochim. Acta, 2006, 51, p 4182–4189. https://doi.org/10.1016/j.electacta.2005.11.03710.1016/j.electacta.2005.11.037 ↗
23. H. Saifia, M.C. Bernard, S. Joiret, K. Rahmouni, H. Takenouti, and B. Talhi, Corrosion Inhibitive Action of Cysteine on Cu–30Ni Alloy in Aerated 0.5 M H2SO4, Mater. Chem. Phys., 2010, 120, p 661–669. https://doi.org/10.1016/j.matchemphys.2009.12.01110.1016/j.matchemphys.2009.12.011 ↗
24. X. Li, W. Li, S. Yang, and L. Hou, Using Methionine as an Environment-Friendly Corrosion Inhibitor for Copper–Nickel Alloy in a Chloride Solution, Mater. Express, 2017, 7, p 480–490. https://doi.org/10.1166/mex.2017.139710.1166/mex.2017.1397 ↗
25. N.A. Abdel Ghanyl, A.E. El-Shenawy, and W.A.M. Hussien, The Inhibitive Effect of Some Amino Acids on the Corrosion Behaviour of 316L Stainless Steel in Sulfuric Acid Solution, Mod. Appl. Sci., 2011, 5, p 19–30. https://doi.org/10.5539/mas.v5n4p1910.5539/mas.v5n4p19 ↗
26. S. Vikneshvaran and S. Velmathi, Adsorption of l-Tryptophan-Derived Chiral Schiff Bases on Stainless Steel Surface for the Prevention of Corrosion in Acidic Environment: Experimental, Theoretical and Surface Studies, Surf. Interfaces, 2017, 6, p 134–142. https://doi.org/10.1016/j.surfin.2017.01.00110.1016/j.surfin.2017.01.001 ↗
27. A.B. Silva, S.M.L. Agostinho, O.E. Barcia, G.G.O. Cordeiro, and E. D’Elia, The Effect of Cysteine on the Corrosion of 304L Stainless Steel in Sulphuric Acid, Corros. Sci., 2006, 48(11), p 3668–3674. https://doi.org/10.1016/j.corsci.2006.02.00310.1016/j.corsci.2006.02.003 ↗
28. L. Madkour and M. Ghoneim, Inhibition of the Corrosion of 16/14 Austenitic Stainless Steel by Oxygen and Nitrogen Containing Compounds, Bull. Electrochem., 1997, 13, p 1–7
29. W. Ye, Y. Li, and F. Wang, Effects of Nanocrystallization on the Corrosion Behavior of 309 Stainless Steel, Electrochim. Acta, 2006, 51, p 4426–4432. https://doi.org/10.1016/j.electacta.2005.12.03410.1016/j.electacta.2005.12.034 ↗
30. W. Ye, Y. Li, and F. Wang, The Improvement of the Corrosion Resistance of 309 Stainless Steel in the Transpassive Region by Nano-Crystallization, Electrochim. Acta, 2009, 54, p 1339–1349. https://doi.org/10.1016/j.electacta.2008.08.07310.1016/j.electacta.2008.08.073 ↗
31. K. Fushimi, A. Naganuma, K. Azumi, and Y. Kawahara, Current Distribution during Galvanic Corrosion of Carbon Steel Welded with Type-309 Stainless Steel in NaCl Solution, Corros. Sci., 2008, 50, p 903–911. https://doi.org/10.1016/j.corsci.2007.10.00310.1016/j.corsci.2007.10.003 ↗
32. A. Gharbi, A. Himour, S. Abderrahmane, and K. Abderrahim, Inhibition Effect of 2,2′-Bipyridyl on the Corrosion of Austenitic Stainless Steel in 0.5 M H2SO4, Orient. J. Chem., 2018, 34, p 314–325. https://doi.org/10.13005/ojc/34013410.13005/ojc/340134 ↗
33. S.Y. Kim, H.S. Kwon, and H. Kim, Effect of Delta Ferrite on Corrosion Resistance of Type 316L Stainless Steel in Acidic Chloride Solution by Micro-droplet Cell, Solid State Phenom., 2007, 124–126, p 1533–1536. https://doi.org/10.4028/www.scientific.net/SSP.124-126.153310.4028/www.scientific.net/SSP.124-126.1533 ↗
34. R.T. Loto and E. Özcan, Corrosion Resistance Studies of Austenitic Stainless Steel Grades in Molten Zinc–Aluminum Alloy Galvanizing Bath, J. Fail. Anal. Prev., 2016, 16, p 427–437. https://doi.org/10.1007/s11668-016-0103-410.1007/s11668-016-0103-4 ↗
35. T. Rabizadeh and S. Khameneh-Asl, Casein as a Natural Protein to Inhibit the Corrosion of Mild Steel in HCl Solution, J. Mol. Liq., 2019, 276, p 694–704. https://doi.org/10.1016/j.molliq.2018.11.16210.1016/j.molliq.2018.11.162 ↗
36. H. Ashassi-Sorkhabi and E. Asghari, Effect of Hydrodynamic Conditions on the Inhibition Performance of l-Methionine as a “Green” Inhibitor, Electrochim. Acta, 2008, 54, p 162–167. https://doi.org/10.1016/j.electacta.2008.08.02410.1016/j.electacta.2008.08.024 ↗
37. V. Shkirskiy, P. Keil, H. Hintze-Bruening, F. Leroux, F. Brisset, K. Ogle, and P. Volovitch, The Effects of l-Cysteine on the Inhibition and Accelerated Dissolution Processes of Zinc Metal, Corros. Sci., 2015, 100, p 101–112. https://doi.org/10.1016/j.corsci.2015.07.01010.1016/j.corsci.2015.07.010 ↗
38. M.A. Chidiebere, E.E. Oguzie, L. Liu, Y. Li, and F. Wang, Ascorbic Acid as Corrosion Inhibitor for Q235 Mild Steel in Acidic Environments, J. Ind. Eng. Chem., 2015, 26, p 182–192. https://doi.org/10.1016/j.jiec.2014.11.02910.1016/j.jiec.2014.11.029 ↗
39. M. Yeganeh, M. Omidi, and M. Eskandari, Superhydrophobic Surface of AZ31 Alloy Fabricated by Chemical Treatment in the NiSO4 Solution, J. Mater. Eng. Perform., 2018, 27, p 3951–3960. https://doi.org/10.1007/s11665-018-3479-310.1007/s11665-018-3479-3 ↗
40. M. Yeganeh, M. Eskandari, and S.R. Alavi-Zaree, A Comparison Between Corrosion Behaviors of Fine-Grained and Coarse-Grained Structures of High-Mn Steel in NaCl Solution, J. Mater. Eng. Perform., 2017, 26, p 2484–2490. https://doi.org/10.1007/s11665-017-2685-810.1007/s11665-017-2685-8 ↗
41. S. Zor, F. Kandemirli, and M. Bingu, Inhibition Effects of Methionine and Tyrosine on Corrosion of Iron in HCl Solution: Electrochemical, FTIR, and Quantum-Chemical Study, Prot. Met. Phys. Chem. Surf., 2009, 45, p 46–5310.1134/S2070205109010079 ↗
42. K. Barouni, A. Kassale, A. Albourine, O. Jbara, B. Hammouti, and L. Bazzi, Amino Acids as Corrosion Inhibitors for Copper in Nitric Acid Medium: Experimental and Theoretical Study, J. Mater. Environ. Sci., 2014, 5, p 456–463
43. K. Wan, P. Feng, B. Hou, and Y. Li, Enhanced Corrosion Inhibition Properties of Carboxymethyl Hydroxypropyl Chitosan for Mild Steel in 10 M HCl Solution, RSC Adv., 2016, 6, p 77515–77524. https://doi.org/10.1039/C6RA12975G10.1039/C6RA12975G ↗
44. S. Jagadeesan, P. Sounthari, K. Parameswari, and S. Chitra, Acenaphtho[1,2-b]quinoxaline and Acenaphtho[1,2-b]pyrazine as Corrosion Inhibitors for Mild Steel in Acid Medium, Measurement, 2015, 77, p 175–186. https://doi.org/10.1016/j.measurement.2015.09.00810.1016/j.measurement.2015.09.008 ↗
45. E.E. Oguzie, Y. Li, and F.H. Wang, Corrosion Inhibition and Adsorption Behavior of Methionine on Mild Steel in Sulfuric Acid and Synergistic Effect of Iodide Ion, J. Colloid Interface Sci., 2007, 310, p 90–98. https://doi.org/10.1016/j.jcis.2007.01.03810.1016/j.jcis.2007.01.038 ↗
46. M. Saremi and M. Yeganeh, Corrosion Behavior of Copper Thin Films Deposited by EB-PVD Technique on Thermally Grown Silicon Dioxide and Glass in Hydrochloric Acid Media, Mater. Chem. Phys., 2010, 123, p 456–462. https://doi.org/10.1016/j.matchemphys.2010.04.04110.1016/j.matchemphys.2010.04.041 ↗
47. D.Q. Zhang, B. Xie, L.X. Gao, H.G. Joo, and K.Y. Lee, Inhibition of Copper Corrosion in Acidic Chloride Solution by Methionine Combined with Cetrimonium Bromide/Cetylpyridinium Bromide, J. Appl. Electrochem., 2011, 41, p 491–498. https://doi.org/10.1007/s10800-011-0259-210.1007/s10800-011-0259-2 ↗
48. M. Saremi and M. Yeganeh, Investigation of Corrosion Behaviour of Nanostructured Copper Thin Film Produced by Radio Frequency Sputtering, Micro Nano Lett., 2010, 5, p 70–75. https://doi.org/10.1049/mnl.2009.011110.1049/mnl.2009.0111 ↗
49. M.A. Amin, Weight Loss, Polarization, Electrochemical Impedance Spectroscopy, SEM and EDX Studies of the Corrosion Inhibition of Copper in Aerated NaCl Solutions, J. Appl. Electrochem., 2006, 36, p 215–226. https://doi.org/10.1007/s10800-005-9055-110.1007/s10800-005-9055-1 ↗
50. R. Solmaz, Investigation of Corrosion Inhibition Mechanism and Stability of Vitamin B1 on Mild Steel in 0.5 M HCl Solution, Corros. Sci., 2014, 81, p 75–84. https://doi.org/10.1016/j.corsci.2013.12.00610.1016/j.corsci.2013.12.006 ↗
51. A.R. Hoseinzadeh, I. Danaee, and M.H. Maddahy, Thermodynamic and Adsorption Behaviour of Vitamin B1 as a Corrosion Inhibitor for AIS 4130 Steel Alloy in HCl Solution, Z. Phys. Chem., 2013, 227, p 403–417. https://doi.org/10.1524/zpch.2013.027610.1524/zpch.2013.0276 ↗
52. M. Özcan, F. Karadağ, and İ. Dehric, Investigation of Adsorption Characteristics of Methionine at Mild Steel/Sulfuric Acid Interface: An Experimental and Theoretical Study, Colloid Surf. A Physicochem. Eng. Aspects, 2008, 316, p 55–61. https://doi.org/10.1016/j.colsurfa.2007.08.02310.1016/j.colsurfa.2007.08.023 ↗
53. M. Yeganeh, M. Omidi, and T. Rabizadeh, Anti-corrosion Behavior of Epoxy Composite Coatings Containing Molybdate-Loaded Mesoporous Silica, Prog. Org. Coat., 2019, 126, p 18–27. https://doi.org/10.1016/j.porgcoat.2018.10.01610.1016/j.porgcoat.2018.10.016 ↗
54. R. Naderi and M.M. Attar, Effect of Zinc-Free Phosphate-Based Anticorrosion Pigment on the Cathodic Disbondment of Epoxy-Polyamide Coating, Prog. Org. Coat., 2014, 77, p 830–83510.1016/j.porgcoat.2014.01.012 ↗
55. B.P. Markhali, R. Naderi, M. Mahdavian, M. Sayebani, and S.Y. Arman, Electrochemical Impedance Spectroscopy and Electrochemical Noise Measurements as Tools to Evaluate Corrosion Inhibition of Azole Compounds on Stainless Steel in Acidic Media, Corros. Sci., 2013, 75, p 269–27910.1016/j.corsci.2013.06.010 ↗
56. A. Dehghani, G. Bahlakeh, B. Ramezanzadeh, and M. Ramezanzadeh, A Combined Experimental and Theoretical Study of Green Corrosion Inhibition of Mild Steel in HCl Solution by Aqueous Citrullus lanatus Fruit (CLF) Extract, J. Mol. Liq., 2019, 279, p 603–624. https://doi.org/10.1016/j.molliq.2019.02.01010.1016/j.molliq.2019.02.010 ↗
57. A. Dehghani, G. Bahlakeh, and B. Ramezanzadeh, A Detailed Electrochemical/Theoretical Exploration of the Aqueous Chinese Gooseberry Fruit Shell Extract as a Green and Cheap Corrosion Inhibitor for Mild Steel in Acidic Solution, J. Mol. Liq., 2019, 282, p 366–384. https://doi.org/10.1016/j.molliq.2019.03.01110.1016/j.molliq.2019.03.011 ↗
58. S.S. Abd El Rehim, S.M. Sayyah, M.M. El-Deeb, S.M. Kamal, and R.E. Azooz, Adsorption and Corrosion Inhibitive Properties of P(2-aminobenzothiazole) on Mild Steel in Hydrochloric Acid Media, Int. J. Ind. Chem., 2016, https://doi.org/10.1007/s40090-015-0065-510.1007/s40090-015-0065-5 ↗
59. N.A. Odewunmi, S.A. Umoren, and Z.M. Gasem, Utilization of Watermelon Rind Extract as a Green Corrosion Inhibitor for Mild Steel in Acidic Media, J. Ind. Eng. Chem., 2015, 21, p 239–247. https://doi.org/10.1016/j.jiec.2014.02.03010.1016/j.jiec.2014.02.030 ↗
60. A. Singh, K.R. Ansari, M.A. Quraishi, H. Lgaz, and Y. Lin, Synthesis and Investigation of Pyran Derivatives as Acidizing Corrosion Inhibitors for N80 Steel in Hydrochloric Acid: Theoretical and Experimental Approaches, J. Alloys Compd., 2018, 762, p 347–362. https://doi.org/10.1016/j.jallcom.2018.05.23610.1016/j.jallcom.2018.05.236 ↗
61. N. Asadi, M. Ramezanzadeha, G. Bahlakeh, and B. Ramezanzadeh, Utilizing Lemon Balm Extract as an Effective Green Corrosion Inhibitor for Mild Steel in 1 M HCl Solution: A Detailed Experimental, Molecular Dynamics, Monte Carlo and Quantum Mechanics Study, J. Taiwan Inst. Chem. Eng., 2019, 95, p 252–272. https://doi.org/10.1016/j.jtice.2018.07.01110.1016/j.jtice.2018.07.011 ↗