journal article·2026

2-Aminobenzazolium chlorocuprate( ii ) complexes for memristive devices: structural studies, synaptic plasticity, and random number generation

Andrzej Sławek, Gisya Abdi, Ewelina Cechosz, Marta Janioł, Sidra Muzaffar, Krzysztof Mech, Alexey Maximenko, Anna Dołęga, Takuya Matsumoto, Konrad Szaciłowski

Journal of Materials Chemistry C· Volume 14· Issue 28
Publisher page

Abstract

Heteroatom engineering in hybrid chlorocuprate memristors tunes interfacial hybridisation and trap-state density, enabling stable Schottky-barrier-driven resistive switching, neuromorphic behaviour, and stochastic hardware random number generation.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short

Research context

OpenAlex topics: Advanced Memory and Neural Computing · Organic Light-Emitting Diodes Research · Synthesis and Properties of Aromatic Compounds

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Academic Centre for Materials and Nanotechnology, AGH University of Krakow, Kawiory 30, 30-055 Kraków, Poland

National Synchrotron Radiation Centre SOLARIS, Jagiellonian University, Czerwone Maki 98, 30-392 Kraków, Poland

Department of Inorganic Chemistry, Chemical Faculty, Gdansk University of Technology, ul. Narutowicza 11/12, 80-233 Gdańsk, Poland

Department of Chemistry, Graduate School of Science, Osaka University, 1-1 Machikaneyama, Osaka, Toyonaka, 560-0043, Japan

Forefront Research Center, Graduate School of Science, Osaka University, 1-1 Machikaneyama-cho, Toyonaka, Osaka 560-0043, Japan

Funding

Academic Computer Centre Cyfronet, AGH University of Science and Technology · Narodowym Centrum Nauki · Ministerstwo Edukacji i Nauki · Horizon 2020

References (100+)

Show source-provided references
1. Spackman · J. Appl. Crystallogr. · 2021 · 54 · 100610.1107/S1600576721002910 ↗
2. Egger · Acc. Chem. Res. · 2016 · 49 · 57310.1021/acs.accounts.5b00540 ↗
3. Yang · Mater. Des. · 2020 · 193 · 10886810.1016/j.matdes.2020.108868 ↗
4. Ye · J. Am. Chem. Soc. · 2015 · 137 · 1314810.1021/jacs.5b08290 ↗
5. Odenthal · Nat. Phys. · 2017 · 13 · 89410.1038/nphys4145 ↗
6. Gao · Chem. Soc. Rev. · 2019 · 48 · 153110.1039/C8CS00614H ↗
7. Jiang · Adv. Sci. · 2025 · 12 · 240929110.1002/advs.202409291 ↗
8. Peixiong · Mater. Today Energy · 2024 · 45 · 10169210.1016/j.mtener.2024.101692 ↗
9. Satapathi · Phys. Rev. Appl. · 2022 · 18 · 01700110.1103/PhysRevApplied.18.017001 ↗
10. Elseman · ACS Appl. Mater. Interfaces · 2018 · 10 · 1169910.1021/acsami.8b00495 ↗
11. Exploring Chemistry with Pyridine Derivatives , IntechOpen , Rijeka , 2023
12. Sahoo · ACS Mater. Au · 2022 · 2 · 12410.1021/acsmaterialsau.1c00046 ↗
13. Abdi · Dalton Trans. · 2023 · 52 · 1464910.1039/D3DT02910G ↗
14. Abdi · Adv. Electron. Mater. · 2025 · e0004910.1002/aelm.202500049 ↗
15. Antolini · Inorg. Chem. · 1988 · 27 · 219210.1021/ic00285a036 ↗
16. Kessentini · Spectrochim. Acta, Part A · 2015 · 134 · 2810.1016/j.saa.2014.06.073 ↗
17. Vishwakarma · J. Mol. Struct. · 2017 · 1141 · 9310.1016/j.molstruc.2017.03.076 ↗
18. Yang · J. Chem. Soc., Dalton Trans. · 2007 · 9 · 95510.1039/B617136B ↗
19. Okuniewski · Polyhedron · 2015 · 90 · 4710.1016/j.poly.2015.01.035 ↗
20. Spackman · Chem. Phys. Lett. · 1997 · 267 · 21510.1016/S0009-2614(97)00100-0 ↗
21. Rakitin · Russ. J. Coord. Chem. · 2007 · 33 · 89110.1134/S1070328407120044 ↗
22. Halvorson · Acta Crystallogr., Sect. B · 1990 · 46 · 50810.1107/S010876819000338X ↗
23. Valdés-Martínez · Polyhedron · 2002 · 21 · 40910.1016/S0277-5387(01)01006-3 ↗
24. Addison · J. Chem. Soc., Dalton Trans. · 1984 · 7 · 134910.1039/DT9840001349 ↗
25. Antolini · J. Am. Chem. Soc. · 1980 · 102 · 130310.1021/ja00524a013 ↗
26. Wang · Dalton Trans. · 2017 · 46 · 1046210.1039/C7DT01378G ↗
27. Baccar · Solid State Commun. · 2010 · 150 · 200510.1016/j.ssc.2010.08.018 ↗
28. L.Li , J. L.Wikaira and M. M.Turnbull , CCDC 2264169: Experimental Crystal Structure Determination, 2023
29. S.Parsons , M.Low and N.Robertson , CCDC 1417016: Experimental Crystal Structure Determination , 2015
30. El Glaoui · J. Struct. Chem. · 2018 · 59 · 161010.1134/S0022476618070120 ↗
31. Olshin · Chem. Phys. · 2018 · 503 · 1410.1016/j.chemphys.2018.01.020 ↗
32. J.Tauc , Amorphous and Liquid Semiconductors , 1 edn, Springer New York , NY , 197410.1007/978-1-4615-8705-7 ↗
33. S.Kasap , C.Koughia , J.Singh , H.Ruda and S.O'Leary , Optical Properties of Electronic Materials: Fundamentals and Characterization , in Springer Handbook of Electronic and Photonic Materials , ed. S. Kasap and P. Capper , Springer US , Boston, MA , 2007 , pp. 47–7710.1007/978-0-387-29185-7 ↗
34. K.Morigaki and C.Ogihara , Amorphous Semiconductors: Structure, Optical, and Electrical Properties . in Springer Handbook of Electronic and Photonic Materials , ed. S. Kasap and P. Capper , Springer International Publishing , Cham , 2017 , pp 1–1
35. Kessentini · Spectrochim. Acta, Part A · 2014 · 122 · 47610.1016/j.saa.2013.11.070 ↗
36. Sathyanarayanmoorthi · J. Chem. · 2013 · 1 · 25851910.1155/2013/258519 ↗
37. de Oliveira · Int. J. Polym. Sci. · 2018 · 1 · 4201681
38. Larsson · Powder Diffr. · 2017 · 32 · S2810.1017/S0885715617000756 ↗
39. Sano · Inorg. Chem. · 1992 · 31 · 45910.1021/ic00029a022 ↗
40. Kau · J. Am. Chem. Soc. · 1987 · 109 · 643310.1021/ja00255a032 ↗
41. Gutmańska · Chem. – Eur. J. · 2025 · 31 · e20250021510.1002/chem.202500215 ↗
42. Singh · Int. J. Energy Res. · 2020 · 44 · 284510.1002/er.5101 ↗
43. Smith · J. Chem. Soc. · 1969 · 0 · 170810.1039/J19690001708 ↗
44. Smith · J. Chem. Soc. · 1970 · 0 · 17610.1039/J19700000176 ↗
45. Nishikawa · Mem. SR Center Ritsumeikan Univ. · 2021 · 23 · 9
46. Amemiya · e-J. Surf. Sci. Nanotechnol. · 2022 · 20 · 13510.1380/ejssnt.2022-020 ↗
47. Shadle · Inorg. Chem. · 1994 · 33 · 423510.1021/ic00097a009 ↗
48. Durante · Adv. Func. Mater. · 2026 · 36 · e2633910.1002/adfm.202526339 ↗
49. Montero · Org. Electron. · 2009 · 10 · 30510.1016/j.orgel.2008.11.017 ↗
50. Rabiei · Nano Trends · 2026 · 13 · 10017810.1016/j.nwnano.2025.100178 ↗
51. Wlaźlak · ACS Appl. Electron. Mater. · 2020 · 2 · 32910.1021/acsaelm.9b00750 ↗
52. Wlaźlak · J. Mater. Chem. C · 2020 · 8 · 613610.1039/D0TC00679C ↗
53. Nath · Phys. Rev. Appl. · 2020 · 13 · 06402410.1103/PhysRevApplied.13.064024 ↗
54. Boltersdorf · CrystEngComm · 2014 · 17
55. Yang · Adv. Electron. Mater. · 2026 · e0066710.1002/aelm.202500667 ↗
56. Jäntsch · Solid State Electron. · 1968 · 11 · 26710.1016/0038-1101(68)90088-9 ↗
57. Vandamme · Phys. B · 2005 · 357 · 50710.1016/j.physb.2004.09.106 ↗
58. Nemirovsky · Solid State Electron. · 1997 · 41 · 181110.1016/S0038-1101(97)00156-1 ↗
59. Yang · Nat. Nanotech. · 2008 · 3 · 42910.1038/nnano.2008.160 ↗
60. Kumar · ACS Appl. Mater. Interfaces · 2016 · 8 · 821310.1021/acsami.5b12393 ↗
61. Liou · Jpn. J. Appl. Phys. · 1990 · 29 · 128310.1143/JJAP.29.1283 ↗
62. Kleinpenning · Phys. B + C · 1980 · 98 · 28910.1016/0378-4363(80)90045-5 ↗
63. G.Wang , T. W.Kim , T.Lee , W.Wang and M. A.Reed , 4.16 - Electronic Properties of Alkanethiol Molecular Junctions: Conduction Mechanisms, Metal–Molecule Contacts, and Inelastic Transport . In Comprehensive Nanoscience and Technology , ed Andrews, D. L. ; Scholes, G. D. ; Wiederrecht, G. P. , Academic Press , Amsterdam , 2011 , pp. 463–48710.1016/B978-0-12-374396-1.00138-0 ↗
64. Hwang · Small · 2024 · 20 · 230527110.1002/smll.202305271 ↗
65. Song · Chem. Phys. · 2020 · 528 · 11051410.1016/j.chemphys.2019.110514 ↗
66. Naha · ACS Appl. Electron. Mater. · 2025 · 7 · 1039610.1021/acsaelm.5c01886 ↗
67. Panda · Nanoscale · 2024 · 16 · 1614810.1039/D4NR01155D ↗
68. Abdi · Dalton Trans. · 2024 · 53 · 1461010.1039/D4DT01946F ↗
69. Mazur · Bionanoscience · 2025 · 15 · 40910.1007/s12668-025-02027-w ↗
70. Zhou · iScience · 2022 · 25 · 10524010.1016/j.isci.2022.105240 ↗
71. Khanas · Adv. Electron. Mater. · 2022 · 8 · 220042110.1002/aelm.202200421 ↗
72. Khanas · Adv. Electron. Mater. · 2024 · 10 · 230080310.1002/aelm.202300803 ↗
73. Hu · Adv. Func. Mater. · 2021 · 31 · 200558210.1002/adfm.202005582 ↗
74. Roldán · Adv. Intellig. Syst. · 2023 · 5 · 220033810.1002/aisy.202200338 ↗
75. Alonso · Chaos, Solitons Fractals · 2021 · 143 · 11046110.1016/j.chaos.2020.110461 ↗
76. Acal · ACS Appl. Mater. Interfaces · 2023 · 15 · 1910210.1021/acsami.2c22617 ↗
77. Zhou · Adv. Electron. Mater. · 2022 · 8 · 210112710.1002/aelm.202101127 ↗
78. Moon · Mater. Horiz. · 2024 · 11 · 484010.1039/D4MH00675E ↗
79. Ding · Commun. Mater. · 2025 · 6 · 14910.1038/s43246-025-00876-2 ↗
80. Song · Adv. Intellig. Syst. · 2023 · 5 · 220035810.1002/aisy.202200358 ↗
81. Li · Adv. Func. Mater. · 2021 · 31 · 210217210.1002/adfm.202102172 ↗
82. Stavrinides · Chaos, Solitons Fractals · 2022 · 160 · 11222410.1016/j.chaos.2022.112224 ↗
83. Ranjan · ACS Appl. Electron. Mater. · 2022 · 4 · 390910.1021/acsaelm.2c00559 ↗
84. Otto · J. Sci. Instrum. · 1938 · 15 · 2410.1088/0950-7671/15/1/305 ↗
85. J.Walker , ENT: A Pseudorandom Number Sequence Test Program , https://www.fourmilab.ch/random/ , 2008
86. de Tacconi · J. Phys. Chem. B · 1997 · 101 · 1015110.1021/jp9723224 ↗
87. G. M.Sheldrick , SHELXL-2018 (2018) Program for Crystal Structure Refinement , University of Göttingen , Göttingen , 2018
88. Dolomanov · J. Appl. Crystallogr. · 2009 · 42 · 33910.1107/S0021889808042726 ↗
89. Farrugia · J. Appl. Crystallogr. · 2012 · 45 · 84910.1107/S0021889812029111 ↗
90. Macrae · J. Appl. Crystallogr. · 2006 · 39 · 45310.1107/S002188980600731X ↗
91. Szlachetko · Eur. Phys. J. Plus · 2023 · 138 · 1010.1140/epjp/s13360-022-03592-9 ↗
92. Ravel · J. Synchrotron Radiat. · 2005 · 12 · 53710.1107/S0909049505012719 ↗
93. Hohenberg · Phys. Rev. · 1964 · 136 · B86410.1103/PhysRev.136.B864 ↗
94. Kohn · Phys. Rev. · 1965 · 140 · A113310.1103/PhysRev.140.A1133 ↗
95. Francis · J. Phys.: Condens. Matter · 1990 · 2 · 4395
96. M. J.Frisch , G. W.Trucks , H. B.Schlegel , G. E.Scuseria , M. A.Robb , J. R.Cheeseman , G.Scalmani , V.Barone , G. A.Petersson , H.Nakatsuji , X.Li , M.Caricato , A. V.Marenich , J.Bloino , B. G.Janesko , R.Gomperts , B.Mennucci , H. P.Hratchian , J. V.Ortiz , A. F.Izmaylov , J. L.Sonnenberg , Williams , F.Ding , F.Lipparini , F.Egidi , J.Goings , B.Peng , A.Petrone , T.Henderson , D.Ranasinghe , V. G.Zakrzewski , J.Gao , N.Rega , G.Zheng , W.Liang , M.Hada , M.Ehara , K.Toyota , R.Fukuda , J.Hasegawa , M.Ishida , T.Nakajima , Y.Honda , O.Kitao , H.Nakai , T.Vreven , K.Throssell , J. A.Montgomery Jr. , J. E.Peralta , F.Ogliaro , M. J.Bearpark , J. J.Heyd , E. N.Brothers , K. N.Kudin , V. N.Staroverov , T. A.Keith , R.Kobayashi , J.Normand , K.Raghavachari , A. P.Rendell , J. C.Burant , S. S.Iyengar , J.Tomasi , M.Cossi , J. M.Millam , M.Klene , C.Adamo , R.Cammi , J. W.Ochterski , R. L.Martin , K.Morokuma , O.Farkas , J. B.Foresman and D. J.Fox , Gaussian 16 Rev. A.03 , Wallingford, CT , 2016
97. Weigend · Phys. Chem. Chem. Phys. · 2006 · 8 · 105710.1039/b515623h ↗
98. Weigend · Phys. Chem. Chem. Phys. · 2005 · 7 · 329710.1039/b508541a ↗
99. Segall · J. Phys.: Condens. Matter · 2002 · 14 · 2717
100. Clark · Z. Kristallogr. · 2005 · 220 · 56710.1524/zkri.220.5.567.65075 ↗