Tunable negative and low thermal expansion in magnetic calcite-type Fe _{ 1− x } Cr _{ x } BO ₃ ( x = 0.0, 0.14, 1.0) borates: a comprehensive in situ study

Yaroslav P. Biryukov; Almaz L. Zinnatullin; Andrey P. Shablinskii; Yulia S. Gokhfeld; Margarita S. Avdontceva; Mikhail A. Cherosov; Natalia V. Kazak; Maria G. Krzhizhanovskaya; Maxim D. Kuznetsov; Valeriy L. Ugolkov; Sergey M. Zharkov; Galina M. Zeer; Valery V. Rudenko; Rimma S. Bubnova; Farit G. Vagizov; Stanislav K. Filatov

doi:10.1039/d6tc01009a

journal article·2026

Tunable negative and low thermal expansion in magnetic calcite-type Fe _{1− x} Cr _x BO ₃ ( x = 0.0, 0.14, 1.0) borates: a comprehensive in situ study

Yaroslav P. Biryukov, Almaz L. Zinnatullin, Andrey P. Shablinskii, Yulia S. Gokhfeld, Margarita S. Avdontceva, Mikhail A. Cherosov, Natalia V. Kazak, Maria G. Krzhizhanovskaya, Maxim D. Kuznetsov, Valeriy L. Ugolkov, Sergey M. Zharkov, Galina M. Zeer, Valery V. Rudenko, Rimma S. Bubnova, Farit G. Vagizov, Stanislav K. Filatov

Journal of Materials Chemistry C· Volume 14· Issue 28

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Source abstract

Abstract

Fe _{1− x} Cr _x BO ₃ borates demonstrate composition-tuned magnetic and thermal properties. All samples exhibit LTE, while NTE emerges exclusively at x = 0.14 near RT, promising for optical and magneto-optical applications.

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Research context

OpenAlex topics: Thermal Expansion and Ionic Conductivity · High-pressure geophysics and materials · Chemical Looping and Thermochemical Processes

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Silicate Chemistry, 199034 Saint Petersburg, Russian Federation

Kazan Federal University, 420008 Kazan, Russian Federation

Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russian Federation

Institute of Earth Sciences, St. Petersburg State University, 199034 St. Petersburg, Russian Federation

Siberian Federal University, 660041 Krasnoyarsk, Russian Federation

Funding

Russian Science Foundation · Ministry of Science and Higher Education of the Russian Federation

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