journal article·2022Open access

Organic–inorganic hybrid metallic conductors based on bis(ethylenedithio)tetrathiafulvalene cations and antiferromagnetic oxalate-bridged copper( ii ) dinuclear anions

Bin Zhang, Yan Zhang, Zheming Wang, Dongwei Wang, Deliang Yang, Zengqiang Gao, Guangcai Chang, Yanjun Guo, Takehiko Mori, Zhijuan Zhao, Fen Liu, Qiaolian Li, Daoben Zhu

Journal of Materials Chemistry C· Volume 10· Issue 7

Abstract

In (BEDT-TTF) 3 [Cu 2 (μ-C 2 O 4 )(C 2 O 4 ) 2 (CH 3 OH)(H 2 O)], BEDT-TTF stacks in β′′ mode and shows metallic conductivity. Hydrogen bonds between antiferromagnetic oxalate-bridged binuclear anions form a square lattice. No long range order observed to 2 K.
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Research context

OpenAlex topics: Organic and Molecular Conductors Research · Magnetism in coordination complexes · Advanced Condensed Matter Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Organic Solid Laboratory, BNLMS, CMS & Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

Institute of Condensed Matter and Material Physics, Department of Physics, Peking University, Beijing, 100871, P. R. China

State Key Laboratory of Rare Earth Materials Chemistry and Applications, BNLMS, College of Chemistry and Molecular Engineering, Peking University, Beijing, 100871, P. R. China

CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology, Beijing, 100190, P. R. China

CAS Research/Education Center for Excellence in Molecular Science, CMS & BNLMS, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

BSRF, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100047, P. R. China

Department of Materials Science and Engineering, Tokyo Institute of Technology, O-Okayama, Tokyo 152-8552, Japan

Funding

National Natural Science Foundation of China · Ministry of Science and Technology of the People's Republic of China · Chinese Academy of Sciences

References (58)

Show source-provided references
1. Day · J. Am. Chem. Soc. · 1992 · 114 · 1072210.1021/ja00053a007 ↗
2. Cassoux · Science · 1997 · 272 · 127710.1126/science.272.5266.1277 ↗
3. Kobayashi · J. Am. Chem. Soc. · 1996 · 118 · 36810.1021/ja9523350 ↗
4. Palacio · Nature · 2000 · 408 · 42110.1038/35044179 ↗
5. Kobayashi · Chem. Rev. · 2004 · 104 · 526510.1021/cr030657d ↗
6. Felthouse · Inorg. Chem. · 1977 · 16 · 107710.1021/ic50171a023 ↗
7. Julve · Inorg. Chem. · 1984 · 23 · 380810.1021/ic00191a028 ↗
8. Kahn · Angew. Chem., Int. Ed. Engl. · 1985 · 24 · 83410.1002/anie.198508341 ↗
9. Julve · Eur. J. Inorg. Chem. · 2018
10. Tamaki · J. Am. Chem. Soc. · 1992 · 114 · 697410.1021/ja00044a004 ↗
11. Mathoniere · J. Chem. Soc., Chem. Commun. · 1994 · 155110.1039/C39940001551 ↗
12. Graham · J. Chem. Soc., Chem. Commun. · 1995 · 206110.1039/C39950002061 ↗
13. Cassoux · Science · 1997 · 272 · 127710.1126/science.272.5266.1277 ↗
14. Benmansour · Magnetochemistry · 2021 · 7 · 9310.3390/magnetochemistry7070093 ↗
15. Coronado · Nature · 2000 · 408 · 44710.1038/35044035 ↗
16. Albertola · J. Am. Chem. Soc. · 2003 · 125 · 1077410.1021/ja035772k ↗
17. Zhang · Chem. Commun. · 2012 · 48 · 19710.1039/C1CC15227K ↗
18. Zhang · CrystEngComm. · 2013 · 15 · 352910.1039/c2ce26552d ↗
19. Clemente-Leon · Synth. Met. · 1999 · 103 · 227910.1016/S0379-6779(98)00239-2 ↗
20. Rashid · Inorg. Chem. · 2000 · 39 · 242610.1021/ic991409w ↗
21. Coronado · J. Chem. Soc., Dalton Trans. · 2000 · 2 · 20510.1039/a906893g ↗
22. Day · J. Am. Chem. Soc. · 1992 · 114 · 1077210.1021/ja00053a007 ↗
23. Kujiwara · J. Am. Chem. Soc. · 2001 · 123 · 30610.1021/ja002439x ↗
24. Zhang · J. Am. Chem. Soc. · 2002 · 124 · 998210.1021/ja026911l ↗
25. Kahn · Angew. Chem. · 1985 · 24 · 83410.1002/anie.198508341 ↗
26. O.Kahn , O.Kahn , Molecular Magnetism , VCH Publisher, Inc. , 1993 , p. 103
27. Cano · Chem. – Eur. J. · 1998 · 4 · 47610.1002/(SICI)1521-3765(19980310)4:3<476::AID-CHEM476>3.0.CO;2-8 ↗
28. Zhang · Sci. Rep. · 2014 · 4 · 0645110.1038/srep06451 ↗
29. Zhang · J. Am. Chem. Soc. · 2018 · 140 · 12210.1021/jacs.7b11179 ↗
30. A. C.Jacko and B. J.Powell , arXiv : 1805.05495
31. Zhang · Dalton Trans. · 2012 · 14 · 850910.1039/c2dt30818e ↗
32. Balents · Nature · 2010 · 464 · 19910.1038/nature08917 ↗
33. Anderson · Science · 1987 · 235 · 119610.1126/science.235.4793.1196 ↗
34. G. M.Sheldrick , SHELX97 , University of Göttingen , Göttingen, Germany , 1997
35. G. M.Sheldrick , SHELXL-2014/7 , University of Göttingen , Göttingen, Germany , 2014
36. O.Kahn , Molecular Magnetism , VCH Publisher, Inc. , 1993 , p. 3
37. Mori · Bull. Chem. Soc. Jpn. · 1998 · 71 · 250910.1246/bcsj.71.2509 ↗
38. T.Mori , Electronic Properties of Organic Conductors , Springer , 201610.1007/978-4-431-55264-2 ↗
39. Guionneau · Syn. Met. · 1997 · 86 · 197310.1016/S0379-6779(97)80983-6 ↗
40. Wang · J. Chem. Soc., Chem. Comm. · 1994 · 189310.1039/C39940001893 ↗
41. Yamamoto · J. Phys. Chem. B. · 2005 · 109 · 1522610.1021/jp050247o ↗
42. Kobayshi · Solid State Commun. · 1997 · 103 · 37110.1016/S0038-1098(97)00172-5 ↗
43. Zhang · Adv. Mater. · 2005 · 17 · 198810.1002/adma.200500766 ↗
44. Zhang · Inorg. Chem. · 2006 · 45 · 327510.1021/ic051870q ↗
45. Zhang · Eur. J. Inorg. Chem. · 2014 · 402810.1002/ejic.201402112 ↗
46. Zhang · Dalton Trans. · 2016 · 45 · 1656110.1039/C6DT01845A ↗
47. Mori · Chem. Rev. · 2004 · 104 · 494710.1021/cr030660x ↗
48. Takubo · Phy. Rev. Lett. · 2013 · 110 · 22740110.1103/PhysRevLett.110.227401 ↗
49. Mori · Bull. Chem. Soc. Jpn. · 1984 · 57 · 62710.1246/bcsj.57.627 ↗
50. Rothaemel · Phys. Rev. B: Condens. Matter Mater. Phys. · 1986 · 34 · 70410.1103/PhysRevB.34.704 ↗
51. Miyazaki · Phys. Rev. B: Condens. Matter Mater. Phys. · 1997 · 55 · 684710.1103/PhysRevB.55.6847 ↗
52. Zhang · ChemistryOpen · 2017 · 6 · 32010.1002/open.201700041 ↗
53. Bleaney · Proc. R. Soc. London · 1952 · 214 · 451
54. Journaux · Inorg. Chem. · 1985 · 24 · 406310.1021/ic00218a021 ↗
55. Soto · Inorg. Chem. · 1989 · 28 · 337810.1021/ic00316a028 ↗
56. O.Kahn , Molecular Magnetism , VCH Publisher, Inc. , 1993 , p. 104
57. Bergerat · Inorg. Chem. · 1994 · 33 · 204910.1021/ic00087a049 ↗
58. Romero · J. Am. Chem. Soc. · 2000 · 122 · 129810.1021/ja992673r ↗