journal article·2026

A supramolecular strategy for the control of thermal expansion in molecular crystals

Masato Haneda, Kiyonori Takahashi, Naohiro Hasuo, Rui-Kang Huang, Jia-bing Wu, Chen Xue, Shin-ichiro Noro, Seiji Tsuzuki, Sadafumi Nishihara, Takayoshi Nakamura

Journal of Materials Chemistry C· Volume 14· Issue 7
Publisher page

Abstract

Wheel-axle-type supramolecular cations assemble into two-dimensional layers via C–H⋯π interchain interactions, suppressing crown ether rotation and delivering uniaxial zero thermal expansion between 110 and 190 K.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short

Research context

OpenAlex topics: Thermal Expansion and Ionic Conductivity · Crystallography and molecular interactions · Energetic Materials and Combustion

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, Higashi-hiroshima, 739-8526, Japan

Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo, Hokkaido, 060-0810, Japan

Research Institute for Electronic Science, Hokkaido University, N20W10, Kita-ku, Sapporo, Hokkaido, 010-0020, Japan

Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 866-8555, Japan

School of Flexible Electronics (Future Technologies) and Institute of Advanced Materials, Nanjing Tech University, Nanjing, Jiangsu, 210009, P. R. China

Faculty of Environmental Earth Science, Hokkaido University, N10W5, Kita-ku, Sapporo, Hokkaido, 060-0810, Japan

Department of Applied Physics, The University of Tokyo, 113-8656, Tokyo, Japan

Chirality Research Center, Hiroshima University, 1-3-1, Kagamiyama, Higashi-hiroshima, Hiroshima 739-8526, Japan

Precursory Research for Embryonic Science and Technology, Japan Science and Technology Agency, 4-1-8, Honcho, Kawaguchi, Saitama 332-0012, Japan

Funding

Precursory Research for Embryonic Science and Technology · Ministry of Education, Culture, Sports, Science and Technology · ACT-X · JKA Foundation · Japan Society for the Promotion of Science

References (63)

Show source-provided references
1. Chen · Chem. Soc. Rev. · 2015 · 44 · 352210.1039/C4CS00461B ↗
2. Liu · Ceram. Int. · 2012 · 38 · 54110.1016/j.ceramint.2011.07.041 ↗
3. Okahisa · Compos. Sci. Technol. · 2009 · 69 · 195810.1016/j.compscitech.2009.04.017 ↗
4. Panda · Sci. Rep. · 2016 · 6 · 2961010.1038/srep29610 ↗
5. Dharmarwardana · Proc. Natl. Acad. Sci. U. S. A. · 2021 · 118 · e210657211810.1073/pnas.2106572118 ↗
6. Wu · Chem. Sci. · 2025 · 16 · 884510.1039/D4SC08032G ↗
7. Ding · Angew. Chem. · 2023 · 135 · e20230619810.1002/ange.202306198 ↗
8. Negi · Chem. – Asian J. · 2024 · 19 · e20240080410.1002/asia.202400804 ↗
9. Ge · Sci. Rep. · 2016 · 6 · 2483210.1038/srep24832 ↗
11. Singh · Adv. Mater. · 2005 · 17 · 231510.1002/adma.200501109 ↗
12. Sirringhaus · Adv. Mater. · 2005 · 17 · 241110.1002/adma.200501152 ↗
13. Dong · J. Mater. Sci. Technol. · 2025 · 213 · 9010.1016/j.jmst.2024.06.025 ↗
14. Shen · Adv. Eng. Mater. · 2023 · 4 · 1
15. Lin · Cell Rep. Phys. Sci. · 2023 · 4 · 10125410.1016/j.xcrp.2023.101254 ↗
16. Wang · Phys. Chem. Chem. Phys. · 2018 · 20 · 2872610.1039/C8CP05755A ↗
17. Zhu · J. Am. Chem. Soc. · 2018 · 140 · 740310.1021/jacs.8b03232 ↗
18. Peterson · Angew. Chem., Int. Ed. · 2010 · 49 · 58510.1002/anie.200903366 ↗
19. Liu · Phys. Chem. Chem. Phys. · 2017 · 19 · 2443610.1039/C7CP03937A ↗
20. DeVries · J. Am. Chem. Soc. · 2011 · 133 · 1484810.1021/ja2032822 ↗
21. Panda · Nat. Commun. · 2014 · 5 · 481110.1038/ncomms5811 ↗
22. Iwai · CrystEngComm · 2022 · 24 · 588010.1039/D2CE00878E ↗
23. Balestra · Chem. Mater. · 2016 · 28 · 829610.1021/acs.chemmater.6b03457 ↗
24. Shi · Cell Rep. Phys. Sci. · 2023 · 4 · 10145110.1016/j.xcrp.2023.101451 ↗
25. Takahashi · J. Mater. Chem. C · 2023 · 11 · 189110.1039/D2TC04874D ↗
26. Li · Chem. Mater. · 2023 · 35 · 242110.1021/acs.chemmater.2c03552 ↗
27. Ge · Chem. Mater. · 2023 · 35 · 431110.1021/acs.chemmater.3c00358 ↗
28. Haneda · J. Mater. Chem. C · 2024 · 12 · 1939810.1039/D4TC03992K ↗
29. Cliffe · J. Appl. Cryst. · 2012 · 45 · 132110.1107/S0021889812043026 ↗
30. M.Bougoin and J.Lavenac , Optical Manufacturing and Testing IX , SPIE , 2011 , vol. 8126, pp. 248–257
31. Hartmann · JATIS · 2021 · 7 · 020901
32. Zhou · Nat. Commun. · 2015 · 6 · 691710.1038/ncomms7917 ↗
33. Gładysiak · CrystEngComm · 2019 · 21 · 529210.1039/C9CE00941H ↗
34. Burtch · Adv. Funct. Mater. · 2019 · 29 · 190466910.1002/adfm.201904669 ↗
35. Boström · APL Mater. · 2022 · 10 · 07110610.1063/5.0091091 ↗
36. Liu · Adv. Funct. Mater. · 2025 · 35 · 241329010.1002/adfm.202413290 ↗
37. Liu · CCS Chem. · 2025 · 0 · 1
38. Baxter · J. Am. Chem. Soc. · 2019 · 141 · 1284910.1021/jacs.9b06109 ↗
39. Han · J. Phys. Chem. C · 2007 · 111 · 1518510.1021/jp075389s ↗
40. Nishio · CrystEngComm · 2009 · 11 · 175710.1039/b902318f ↗
41. Umezawa · Bull. Chem. Soc. Jpn. · 1998 · 71 · 120710.1246/bcsj.71.1207 ↗
42. Grimme · J. Chem. Phys. · 2010 · 132 · 15410410.1063/1.3382344 ↗
43. Landee · J. Coord. Chem. · 2014 · 67 · 37510.1080/00958972.2014.889294 ↗
44. J. C.Scott , in Semiconductors and Semimetals , ed. E. Conwell , Elsevier , 1988 , vol. 27, pp. 385–436
45. Akutagawa · Thin Solid Films · 1998 · 331 · 26410.1016/S0040-6090(98)00929-8 ↗
46. Akutagawa · Coord. Chem. Rev. · 2002 · 226 · 310.1016/S0010-8545(01)00432-5 ↗
47. Mori · Bull. Chem. Soc. Jpn. · 1984 · 57 · 62710.1246/bcsj.57.627 ↗
48. Kobayashi · J. Am. Chem. Soc. · 1996 · 118 · 36810.1021/ja9523350 ↗
49. Mori · J. Phys. Soc. Jpn. · 2002 · 71 · 82610.1143/JPSJ.71.826 ↗
50. CCDC 2444930: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24qm10.5517/ccdc.csd.cc2n24qm ↗
51. CCDC 2444931: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24rn10.5517/ccdc.csd.cc2n24rn ↗
52. CCDC 2444932: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24sp10.5517/ccdc.csd.cc2n24sp ↗
53. CCDC 2444933: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24tq10.5517/ccdc.csd.cc2n24tq ↗
54. CCDC 2444934: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24vr10.5517/ccdc.csd.cc2n24vr ↗
55. CCDC 2444935: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24ws10.5517/ccdc.csd.cc2n24ws ↗
56. CCDC 2444936: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24xt10.5517/ccdc.csd.cc2n24xt ↗
57. CCDC 2444937: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24yv10.5517/ccdc.csd.cc2n24yv ↗
58. CCDC 2444938: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n24zw10.5517/ccdc.csd.cc2n24zw ↗
59. CCDC 2444939: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n250y10.5517/ccdc.csd.cc2n250y ↗
60. CCDC 2444940: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n251z10.5517/ccdc.csd.cc2n251z ↗
61. CCDC 2444941: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n252010.5517/ccdc.csd.cc2n2520 ↗
62. CCDC 2444942: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n253110.5517/ccdc.csd.cc2n2531 ↗
63. CCDC 2444943: Experimental Crystal Structure Determination , 2026 10.5517/ccdc.csd.cc2n254210.5517/ccdc.csd.cc2n2542 ↗