The crystal structure, and magnetic and resonant properties of decorated spin kagome system (CsCl)Cu ₅ As ₂ O ₁₀

Ilya V. Kornyakov; Marina V. Likholetova; Irina E. Lezova; Sergey V. Krivovichev; Harald O. Jeschke; Yasir Iqbal; Alexey V. Tkachev; Sergey V. Zhurenko; Andrey A. Gippius; Larisa V. Shvanskaya; Alexander N. Vasiliev

doi:10.1039/d5tc03217b

journal article·2026Open access

The crystal structure, and magnetic and resonant properties of decorated spin kagome system (CsCl)Cu ₅ As ₂ O ₁₀

Ilya V. Kornyakov, Marina V. Likholetova, Irina E. Lezova, Sergey V. Krivovichev, Harald O. Jeschke, Yasir Iqbal, Alexey V. Tkachev, Sergey V. Zhurenko, Andrey A. Gippius, Larisa V. Shvanskaya, Alexander N. Vasiliev

Journal of Materials Chemistry C· Volume 14· Issue 9

Publisher page Open full text

Source abstract

Abstract

As a structural and magnetic bridge between V- and P-based averievites, (CsCl)Cu ₅ As ₂ O ₁₀ reveals a 310 K trigonal–monoclinic transition followed by canted antiferromagnetic order at 21 K.

Only a short abstract or summary was supplied by the source.

Source: crossref · Quality: short

Research context

OpenAlex topics: Advanced Condensed Matter Physics · Physics of Superconductivity and Magnetism · Iron-based superconductors research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

St. Petersburg State University, St. Petersburg 199034, Russia

Kola Science Centre, RAS, Apatity 184209, Russia

Okayama University, Okayama 700-8530, Japan

Indian Institute of Technology Madras, Chennai 600036, India

Lebedev Physical Institute, RAS, Moscow, Russia

Moscow State University, Moscow 119991, Russia

National University of Science and Technology MISIS, Moscow 119049, Russia

Funding

Simons Foundation · Indian Institute of Technology Madras · Russian Science Foundation

References (68)

Show source-provided references

1. Anderson · Mater. Res. Bull. · 1973 · 8 · 15310.1016/0025-5408(73)90167-0 ↗

2. He · Chem. Commun. · 2025 · 61 · 626010.1039/D4CC06828A ↗

3. Braithwaite · Mineral. Mag. · 2004 · 68 · 52710.1180/0026461046830204 ↗

4. Lafontaine · J. Solid State Chem. · 1990 · 85 · 22010.1016/S0022-4596(05)80078-7 ↗

5. Guillemin · C. R. Hebd. Seances Acad. Sci. · 1955 · 240 · 2331

6. Pring · Am. Mineral. · 1990 · 75 · 1421

7. Krivovichev · Mineral. Petrol. · 2013 · 107 · 23510.1007/s00710-012-0238-2 ↗

8. Kahlenberg · Z. Anorg. Allg. Chem. · 2004 · 630 · 90010.1002/zaac.200400029 ↗

9. Pekov · Geology Ore Deposits · 2016 · 58 · 56810.1134/S1075701516070084 ↗

10. Starova · Mineral. Mag. · 1996 · 61 · 44110.1180/minmag.1997.061.406.09 ↗

11. Botana · Phys. Rev. B · 2018 · 98 · 05442110.1103/PhysRevB.98.054421 ↗

12. Kornyakov · Molecules · 2021 · 26 · 183310.3390/molecules26071833 ↗

13. Ginga · Phys. Chem. Miner. · 2022 · 49 · 3810.1007/s00269-022-01213-6 ↗

14. Winiarski · Inorg. Chem. · 2019 · 58 · 432810.1021/acs.inorgchem.8b03464 ↗

15. Liu · Chem. Mater. · 2024 · 36 · 951610.1021/acs.chemmater.4c01342 ↗

16. Dey · Phys. Rev. B · 2020 · 102 · 12510610.1103/PhysRevB.102.125106 ↗

17. Rausch · Scipost Phys. · 2022 · 12 · 14310.21468/SciPostPhys.12.5.143 ↗

18. Jyothis · J. Phys.: Condens. Matter · 2024 · 36 · 185801

19. PDXL 2, Rigaku Corporation, Tokyo, Japan, 2012

20. Gates-Rector · Powder Diffr. · 2019 · 34 · 35210.1017/S0885715619000812 ↗

21. Zagorac · J. Appl. Crystallogr. · 2019 · 52 · 91810.1107/S160057671900997X ↗

22. Coelho · J. Appl. Crystallogr. · 2019 · 51 · 21010.1107/S1600576718000183 ↗

23. Sheldrick · Acta Crystallogr., Sect. A: Found. Adv. · 2015 · 71 · 310.1107/S2053273314026370 ↗

24. Sheldrick · Acta Crystallogr., Sect. C: Struct. Chem. · 2015 · 71 · 310.1107/S2053229614024218 ↗

25. Dolomanov · J. Appl. Crystallogr. · 2009 · 42 · 33910.1107/S0021889808042726 ↗

26. Guchhait · Phys. Rev. B · 2024 · 110 · 17444710.1103/PhysRevB.110.174447 ↗

27. Mohanty · Phys. Rev. B · 2023 · 108 · 10442410.1103/PhysRevB.108.104424 ↗

28. Liu · Cryst. Growth Des. · 2024 · 24 · 970110.1021/acs.cgd.4c01195 ↗

29. M. F.Brigatti , D.Malferarri , A.Laurora and C.Elmi , in EMU Notes in Mineralogy: Layered Mineral Structures and their Application in Advanced Technologies , ed. M. F. Brigatti and A. Mottana , European Mineralogical Union and the Mineralogical Society of Great Britain & Ireland , Twickenham, Middlesex TW1 3HQ, United Kingdom , 1st edn, 2011 , ch. 1, pp. 1–73

30. Krivovichev · Minerals · 2025 · 15 · 1310.3390/min15010013 ↗

31. Zhurenko · Instrum. Exp. Tech. · 2021 · 64 · 42710.1134/S0020441221020202 ↗

32. Bussandri · J. Magn. Reson. · 1998 · 131 · 22410.1006/jmre.1998.1363 ↗

33. Clark · Rev. Sci. Instrum. · 1995 · 66 · 245310.1063/1.1145643 ↗

34. Rabis · Phys. B · 2005 · 359–361 · 119510.1016/j.physb.2005.01.343 ↗

35. Koepernik · Phys. Rev. B · 1999 · 59 · 174310.1103/PhysRevB.59.1743 ↗

36. Perdew · Phys. Rev. Lett. · 1996 · 77 · 386510.1103/PhysRevLett.77.3865 ↗

37. Liechtenstein · Phys. Rev. B · 1995 · 52 · R546710.1103/PhysRevB.52.R5467 ↗

38. Jeschke · Phys. Rev. B · 2015 · 92 · 09441710.1103/PhysRevB.92.094417 ↗

39. Chillal · Nat. Commun. · 2020 · 11 · 234810.1038/s41467-020-15594-1 ↗

40. Niggemann · Phys. Rev. B · 2023 · 108 · L24111710.1103/PhysRevB.108.L241117 ↗

41. Jaubert · Phys. Rev. Lett. · 2025 · 134 · 08670210.1103/PhysRevLett.134.086702 ↗

42. Krivovichev · Angew. Chem., Int. Ed. · 2014 · 53 · 65410.1002/anie.201304374 ↗

43. Krivovichev · Mineral. Mag. · 2023 · 86 · 18310.1180/mgm.2022.23 ↗

44. Turchenko · J. Energy Chem. · 2022 · 69 · 66710.1016/j.jechem.2021.12.027 ↗

45. CCDC 2480016: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nj410.25505/fiz.icsd.cc2p7nj4 ↗

46. CCDC 2480017: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nk510.25505/fiz.icsd.cc2p7nk5 ↗

47. CCDC 2480018: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nl610.25505/fiz.icsd.cc2p7nl6 ↗

48. CCDC 2480019: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nm710.25505/fiz.icsd.cc2p7nm7 ↗

49. CCDC 2480020: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nn810.25505/fiz.icsd.cc2p7nn8 ↗

50. CCDC 2480021: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7np910.25505/fiz.icsd.cc2p7np9 ↗

51. CCDC 2480022: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nqb10.25505/fiz.icsd.cc2p7nqb ↗

52. CCDC 2480023: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nrc10.25505/fiz.icsd.cc2p7nrc ↗

53. CCDC 2480024: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nsd10.25505/fiz.icsd.cc2p7nsd ↗

54. CCDC 2480025: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7ntf10.25505/fiz.icsd.cc2p7ntf ↗

55. CCDC 2480026: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nvg10.25505/fiz.icsd.cc2p7nvg ↗

56. CCDC 2480027: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nwh10.25505/fiz.icsd.cc2p7nwh ↗

57. CCDC 2480028: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nxj10.25505/fiz.icsd.cc2p7nxj ↗

58. CCDC 2480029: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nyk10.25505/fiz.icsd.cc2p7nyk ↗

59. CCDC 2480030: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7nzl10.25505/fiz.icsd.cc2p7nzl ↗

60. CCDC 2480031: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p0n10.25505/fiz.icsd.cc2p7p0n ↗

61. CCDC 2480032: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p1p10.25505/fiz.icsd.cc2p7p1p ↗

62. CCDC 2480033: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p2q10.25505/fiz.icsd.cc2p7p2q ↗

63. CCDC 2480034: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p3r10.25505/fiz.icsd.cc2p7p3r ↗

64. CCDC 2480035: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p4s10.25505/fiz.icsd.cc2p7p4s ↗

65. CCDC 2480036: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p5t10.25505/fiz.icsd.cc2p7p5t ↗

66. CCDC 2480037: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p6v10.25505/fiz.icsd.cc2p7p6v ↗

67. CCDC 2480038: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p7w10.25505/fiz.icsd.cc2p7p7w ↗

68. CCDC 2480039: Experimental Crystal Structure Determination , 2025 10.25505/fiz.icsd.cc2p7p8x10.25505/fiz.icsd.cc2p7p8x ↗