journal article·2025

A computational and Raman spectroscopic study of successive phase transitions in Co 3 TeO 6 under high pressure and high temperature

Yijie Zeng, Pengfei Tan, Tao Han, Ke Liu, Peiyang Mu, Binbin Yue, Huiyang Gou, Yonggang Wang, Dao-Xin Yao, Weidong Sang, Na Wang, Man-Rong Li

Journal of Materials Chemistry C· Volume 13· Issue 35
Publisher page

Abstract

A R 3 to P 2 1 / n transition is predicted for Co 3 TeO 6 under 16 GPa (FM) or 19 GPa (AFM), while ex situ XRD data show phase coexistence of R 3 (72%) and P 2 1 / n (28%), which indicates a high energy barrier in the kinetic process of the phase transition.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Catalysis and Oxidation Reactions · Thermal and Kinetic Analysis · Chemical Thermodynamics and Molecular Structure

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Science, Hangzhou Dianzi University, Hangzhou 310018, China

Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, China

Center for High Pressure Science and Technology Advanced Research (HPSTAR), Beijing 100193, China

School of Materials Science and Engineering, Peking University, Beijing 100871, China

State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, School of Physics, Sun Yat-sen University, Guangzhou 510275, China

School of Chemistry and Chemical Engineering, Hainan University, Haikou 570228, China

Funding

China Scholarship Council · National Natural Science Foundation of China · National Key Research and Development Program of China · Natural Science Foundation of Zhejiang Province · Guangdong Provincial Introduction of Innovative Research and Development Team · Basic and Applied Basic Research Foundation of Guangdong Province · Leading Talents Program of Guangdong Province · Hangzhou Dianzi University

References (43)

Show source-provided references
1. Zhao · Inorg. Chem. · 2019 · 58 · 159910.1021/acs.inorgchem.8b03114 ↗
2. Solana-Madruga · Dalton Trans. · 2015 · 44 · 2044110.1039/C5DT03445K ↗
3. Li · Nat. Commun. · 2017 · 8 · 203710.1038/s41467-017-02003-3 ↗
4. Han · npj Quantum Mater. · 2020 · 5 · 9210.1038/s41535-020-00294-2 ↗
5. Oh · Nat. Commun. · 2014 · 5 · 320110.1038/ncomms4201 ↗
6. Li · J. Am. Chem. Soc. · 2014 · 136 · 850810.1021/ja502774v ↗
7. Bartel · Sci. Adv. · 2019 · 5 · eaav069310.1126/sciadv.aav0693 ↗
8. Solana-Madruga · J. Solid State Chem. · 2022 · 315 · 12347010.1016/j.jssc.2022.123470 ↗
9. Ivanov · Mater. Res. Bull. · 2012 · 47 · 6310.1016/j.materresbull.2011.10.003 ↗
10. Cai · Chem. Mater. · 2017 · 29 · 544710.1021/acs.chemmater.7b01567 ↗
11. Tokura · Rep. Prog. Phys. · 2014 · 77 · 07650110.1088/0034-4885/77/7/076501 ↗
12. Ye · Phys. Rev. B · 2016 · 93 · 13430310.1103/PhysRevB.93.134303 ↗
13. Solana-Madruga · Chem. Commun. · 2021 · 57 · 251110.1039/D0CC07487J ↗
14. Inaguma · J. Am. Chem. Soc. · 2014 · 136 · 274810.1021/ja408931v ↗
15. Zhao · Chem. Mater. · 2021 · 34 · 18610.1021/acs.chemmater.1c03073 ↗
16. Su · J. Mater. Chem. C · 2019 · 7 · 1230610.1039/C9TC03367J ↗
17. Arevalo-Lopez · Chem. Commun. · 2019 · 55 · 1447010.1039/C9CC07733B ↗
18. Xu · Chem. Sci. · 2022 · 13 · 32910.1039/D1SC04239D ↗
19. Mao · Rev. Mod. Phys. · 2018 · 90 · 01500710.1103/RevModPhys.90.015007 ↗
20. Li · Chem. Mater. · 2016 · 28 · 314810.1021/acs.chemmater.6b00755 ↗
21. Li · Angew. Chem., Int. Ed. · 2015 · 54 · 1206910.1002/anie.201506456 ↗
22. Frank · Chem. Commun. · 2019 · 55 · 333110.1039/C9CC00038K ↗
23. Arévalo-López · Phys. Rev. B · 2018 · 98 · 21440310.1103/PhysRevB.98.214403 ↗
24. Li · Chem. Mater. · 2018 · 30 · 450810.1021/acs.chemmater.8b00250 ↗
25. Ivanov · Mater. Res. Bull. · 2011 · 46 · 187010.1016/j.materresbull.2011.07.041 ↗
26. Numan · Phys. Rev. B · 2022 · 106 · 21443710.1103/PhysRevB.106.214437 ↗
27. Ivanov · Chem. Mater. · 2013 · 25 · 93510.1021/cm304095s ↗
28. Šmejkal · Phys. Rev. X · 2022 · 12 · 031042
29. Perdew · Phys. Rev. Lett. · 1996 · 77 · 386510.1103/PhysRevLett.77.3865 ↗
30. Blöchl · Phys. Rev. B: Condens. Matter Mater. Phys. · 1994 · 50 · 1795310.1103/PhysRevB.50.17953 ↗
31. Kresse · Phys. Rev. B: Condens. Matter Mater. Phys. · 1999 · 59 · 175810.1103/PhysRevB.59.1758 ↗
32. Dudarev · Phys. Rev. B: Condens. Matter Mater. Phys. · 1998 · 57 · 150510.1103/PhysRevB.57.1505 ↗
33. Coelho · J. Appl. Crystallogr. · 2018 · 51 · 21010.1107/S1600576718000183 ↗
34. Mathieu · Eur. Phys. J. B · 2013 · 86 · 36110.1140/epjb/e2013-40152-x ↗
35. Zhao · Phys. Status Solidi RRL · 2015 · 9 · 73010.1002/pssr.201510347 ↗
36. For AFM of R 3̄ the C 3 symmetry is preserved, while the S6 symmetry in real space is combined with C 2 in spin space. The overall result is the structure still belongs to rhombohedral system
37. Johnsson · Acta Crystallogr., Sect. C: Cryst. Struct. Commun. · 2006 · 62 · i6710.1107/S010827010602347X ↗
38. Li · Phys. Rev. B: Condens. Matter Mater. Phys. · 2012 · 85 · 09443110.1103/PhysRevB.85.094431 ↗
39. Zivkovic · J. Phys.: Condens. Matter · 2010 · 22 · 056002
40. Selb · J. Mater. Chem. C · 2021 · 9 · 548610.1039/D0TC05210H ↗
41. Liu · Inorg. Chem. · 2020 · 59 · 1812210.1021/acs.inorgchem.0c02571 ↗
42. Wang · Nat. Commun. · 2018 · 9 · 191410.1038/s41467-018-04326-1 ↗
43. Kawamoto · J. Am. Chem. Soc. · 2014 · 136 · 1529110.1021/ja507958z ↗