journal article·2025Open access

Tuning the liquid crystal behavior of subphthalocyanines: effects of substitution, chirality, and hydrogen bonding

Jorge Labella, Elisa López-Serrano, Jorge Labrador-Santiago, Joaquín Barberá, César L. Folcia, Teresa Sierra, Tomás Torres

Journal of Materials Chemistry C· Volume 13· Issue 26

Abstract

We demonstrate that the liquid crystal behavior of subphthalocyanine bowl-shaped aromatics is governed by their chirality and the number and nature of peripheral substituents.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short

Research context

OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Molecular spectroscopy and chirality · Photochromic and Fluorescence Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, C/Francisco Tomás y Valiente 7, 28049 Madrid, Spain

Department of Molecular Engineering, Kyoto University Katsura, Kyoto 615-8510, Japan

Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, 50009 Zaragoza, Spain

Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Zaragoza, 50009 Zaragoza, Spain

Department of Physics, Faculty of Science and Technology, UPV/EHU, 48940 Bilbao, Spain

Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autonoma de Madrid, 28049 Madrid, Spain

IMDEA-Nanociencia, Campus de Cantoblanco, 28049 Madrid, Spain

Funding

Gobierno de Aragón · Consejería de Educación, Juventud y Deporte, Comunidad de Madrid · Ministerio de Ciencia e Innovación · NextGenerationEU · Ministerio de Ciencia, Innovación y Universidades · Ministerio de Educación, Cultura y Deporte

References (29)

Show source-provided references
1. Saito · Mater. Chem. Front. · 2018 · 2 · 63510.1039/C7QM00593H ↗
2. Martin · J. Phys. Chem. C · 2017 · 121 · 2715410.1021/acs.jpcc.7b09044 ↗
3. Wang · Liq. Cryst. Today · 2017 · 26 · 8510.1080/1358314X.2017.1398307 ↗
4. Mayoral · J. Am. Chem. Soc. · 2020 · 142 · 2101710.1021/jacs.0c07291 ↗
5. Kang · Science · 2015 · 347 · 64610.1126/science.aaa4249 ↗
6. Miyajima · J. Am. Chem. Soc. · 2009 · 131 · 4410.1021/ja808396b ↗
7. Miyajima · Science · 2012 · 336 · 20910.1126/science.1217954 ↗
8. Gorbunov · Sci. Adv. · 2017 · 3 · e170101710.1126/sciadv.1701017 ↗
9. Furukawa · Nat. Commun. · 2021 · 12 · 76810.1038/s41467-021-21019-4 ↗
10. Shoji · Sci. Adv. · 2023 · 9 · eadg820210.1126/sciadv.adg8202 ↗
11. Zhang · J. Am. Chem. Soc. · 2020 · 142 · 332610.1021/jacs.9b12710 ↗
12. Guilleme · Adv. Mater. · 2015 · 27 · 428010.1002/adma.201500238 ↗
13. Guilleme · J. Mater. Chem. C · 2015 · 3 · 98510.1039/C4TC02662D ↗
14. Lehmann · Adv. Funct. Mater. · 2021 · 31 · 210421710.1002/adfm.202104217 ↗
15. Labella · Trends Chem. · 2023 · 5 · 35310.1016/j.trechm.2023.02.003 ↗
16. Lavarda · Chem. Soc. Rev. · 2022 · 51 · 948210.1039/D2CS00280A ↗
17. Labella · ACS Mater. Lett. · 2023 · 2 · 54310.1021/acsmaterialslett.2c01132 ↗
18. Labella · CCS Chem. · 2024 · 6 · 27610.31635/ccschem.023.202303395 ↗
19. Cnops · Nat. Commun. · 2014 · 5 · 4406/110.1038/ncomms4406 ↗
20. Labella · Chem. Sci. · 2023 · 14 · 427310.1039/D3SC01069D ↗
21. van de Winckel · Adv. Funct. Mater. · 2018 · 28 · 170593810.1002/adfm.201705938 ↗
22. Demuth · J. Med. Chem. · 2021 · 64 · 1743610.1021/acs.jmedchem.1c01584 ↗
23. Gotfredsen · J. Am. Chem. Soc. · 2023 · 145 · 954810.1021/jacs.2c13353 ↗
24. Lavarda · Angew. Chem., Int. Ed. · 2018 · 57 · 1629110.1002/anie.201808652 ↗
25. Labella · J. Am. Chem. Soc. · 2022 · 144 · 1657910.1021/jacs.2c06377 ↗
26. Scott · J. Am. Chem. Soc. · 1992 · 114 · 192010.1021/ja00031a079 ↗
27. Amaya · Chem. Commun. · 2008 · 76510.1039/B712839H ↗
28. Gómez-Gómez · Chem. – Eur. J. · 2023 · 29 · e20230178210.1002/chem.202301782 ↗
29. Labella · Chem. Sci. · 2024 · 15 · 1376010.1039/D4SC03976A ↗