journal article·2022-04-01

Creating custom-designed patterns of nanoscale graphene quantum dots

Qian Yang, Yu Zhang, Zhong-Qiu Fu, Yulong Chen, Zengfeng Di, Lin He

2D Materials· Volume 9· Issue 2
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Abstract

Abstract Graphene quantum dots (GQDs) have attracted extensive attention over the years because of their importance both in fundamental science and potential applications. However, fabricating patterns of the GQDs is still of great challenge in experiment. Here, we demonstrate a technique to create patterned nanometer-sized GQDs with nanoscale precision in their sites. By applying a voltage pulse from a scanning tunneling microscopy (STM) tip, we successfully create stationary nanoscale circular p–n junctions, i.e. GQDs, in a continuous graphene sheet on hydrogen terminated germanium (110) surface. With accurately tuning the coordinates of the STM tip, the designed patterns of the GQDs are successfully generated. Spatial-resolved measurements indicate that the patterns of the GQDs strongly affect the local electronic properties and two-dimensional distributions of local density of states in graphene.
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Research context

OpenAlex topics: Graphene research and applications · Graphene and Nanomaterials Applications · Carbon Nanotubes in Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. Quantum interference and Klein tunnelling in graphene heterojunctions10.1038/nphys1198 ↗
2. Chaotic dirac billiard in graphene quantum dots10.1126/science.1154663 ↗
3. Confined states and direction-dependent transmission in graphene quantum wells10.1103/PhysRevB.74.045424 ↗
4. Wave-function mapping of graphene quantum dots with soft confinement10.1103/PhysRevLett.108.046801 ↗
5. Quantum-confined electronic states in atomically well-defined graphene nanostructures10.1103/PhysRevLett.107.236803 ↗
6. Chiral tunnelling and the Klein paradox in graphene10.1038/nphys384 ↗
7. Evidence for Klein tunneling in graphene p-n junctions10.1103/PhysRevLett.102.026807 ↗
8. Klein tunnelling and electron trapping in nanometre-scale graphene quantum dots10.1038/nphys3806 ↗
9. Creating and probing electron whispering-gallery modes in graphene10.1126/science.aaa7469 ↗
10. Generating atomically sharp p-n junctions in graphene and testing quantum electron optics on the nanoscale10.1103/PhysRevB.97.045413 ↗
11. Nanoscale control of rewriteable doping patterns in pristine graphene/boron nitride heterostructures10.1021/acs.nanolett.5b04441 ↗
12. Quantum confinement of dirac quasiparticles in graphene patterned with sub-nanometer precision10.1002/adma.202001119 ↗
13. An on/off Berry phase switch in circular graphene resonators10.1126/science.aal0212 ↗
14. Interaction-driven quantum Hall wedding cake–like structures in graphene quantum dots10.1126/science.aar2014 ↗
15. Massless Dirac fermions trapping in a quasi-one-dimensional n-p-n junction of a continuous graphene monolayer10.1103/PhysRevB.95.201406 ↗
16. Spatial confinement, magnetic localization, and their interactions on massless Dirac fermions10.1103/PhysRevB.98.241401 ↗
17. Coulomb interaction in quasibound states of graphene quantum dots10.1103/PhysRevB.101.235310 ↗
18. Relativistic artificial molecules realized by two coupled graphene quantum dots10.1021/acs.nanolett.0c02623 ↗
19. Electrostatically confined monolayer graphene quantum dots with orbital and valley splittings10.1021/acs.nanolett.6b02548 ↗
20. Large tunable valley splitting in edge-free graphene quantum dots on boron nitride10.1038/s41565-018-0080-8 ↗
21. Tuning a circular p-n junction in graphene from quantum confinement to optical guiding10.1038/nnano.2017.181 ↗
22. Nanoscale detection of valley-dependent spin splitting around atomic defects of graphene10.1088/2053-1583/ab2074 ↗
23. Movable valley switch driven by berry phase in bilayer-graphene resonators10.1103/PhysRevLett.124.166801 ↗
24. Valley polarization and inversion in strained graphene via pseudo-landau levels, valley splitting of real landau levels, and confined states10.1103/PhysRevLett.124.106802 ↗
25. Imaging electrostatically confined Dirac fermions in graphene quantum dots10.1038/nphys3805 ↗
26. Spin qubits in graphene quantum dots10.1038/nphys544 ↗
27. Dirac gap-induced graphene quantum dot in an electrostatic potential10.1103/PhysRevB.83.165427 ↗
28. Wafer-scale growth of single-crystal monolayer graphene on reusable hydrogen-terminated germanium10.1126/science.1252268 ↗
29. Programmable graphene nanobubbles with three-fold symmetric pseudo-magnetic fields10.1038/s41467-019-11038-7 ↗
30. Field-induced nanometer- to atomic-scale manipulation of silicon surfaces with the STM10.1126/science.253.5016.173 ↗
31. Structure and energetics of the vacancy in graphite10.1103/PhysRevB.68.144107 ↗
32. Atomic-scale patterning of hydrogen terminated Ge(001) by scanning tunneling microscopy10.1088/0957-4484/20/49/495302 ↗
33. Electronic properties of STM-constructed dangling-bond dimer lines on a Ge(001)-(2 × 1): H surface10.1103/PhysRevB.86.125307 ↗
34. Inelastic transport of tunnel and field-emitted electrons through a single atom10.1103/PhysRevB.63.081305 ↗
35. Local removal of silicon layers on Si(100)-2 × 1 with chlorine-resist STM lithography10.1016/j.apsusc.2019.145235 ↗
36. Scanning tunneling microscopy (STM) studies of the chemical vapor deposition of Ge on Si(111) from Ge hydrides and a comparison with molecular beam epitaxy10.1063/1.466934 ↗
37. Control of etch pit formation for epitaxial growth of graphene on germanium10.1063/1.5108774 ↗
38. Tuning local electrical conductivity via fine atomic scale structures of two-dimensional interfaces10.1021/acs.nanolett.8b02921 ↗
39. Tuning the doping of epitaxial graphene on a conventional semiconductor via substrate surface reconstruction10.1021/acs.jpclett.0c03649 ↗