Unraveling the lithium loss mechanisms during the high-temperature solid-state synthesis of ternary lithium-ion cathode materials
Source abstract
Abstract
Lithium loss during NMC cathode synthesis is dominated by substrate reactions, not Li 2 O evaporation. Moisture in the calcination atmosphere provides a secondary loss pathway via LiOH (g) formation.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Materials, Textiles and Chemical Engineering, Ghent University, Technologiepark 46, 9052 Zwijnaarde (Gent), Belgium
Umicore Rechargeable Battery Materials Belgium, Watertorenstraat 33, 2250 Olen, Belgium
Department of Solid State Sciences, Ghent University, Krijgslaan 281 S1, 9000 Gent, Belgium
Funding
Fonds Wetenschappelijk Onderzoek · Agentschap Innoveren en Ondernemen
References (49)
Show source-provided references
1. Nitta · Mater. Today · 2015 · 18 · 25210.1016/j.mattod.2014.10.040 ↗
2. Schipper · J. Electrochem. Soc. · 2017 · 164 · A622010.1149/2.0351701jes ↗
3. Julien · Energies · 2020 · 13 · 636310.3390/en13236363 ↗
4. Malik · Mater. Today Energy · 2022 · 28 · 10106610.1016/j.mtener.2022.101066 ↗
5. Zhu · Cryst. Growth Des. · 2012 · 12 · 111810.1021/cg200565n ↗
6. Fröhlich · J. Solid State Electrochem. · 2017 · 21 · 340310.1007/s10008-017-3644-x ↗
7. Wang · Adv. Mater. · 2017 · 29 · 160671510.1002/adma.201606715 ↗
8. Bianchini · J. Mater. Chem. A · 2020 · 8 · 180810.1039/C9TA12073D ↗
9. Gao · Ionics · 2021 · 27 · 372910.1007/s11581-021-04068-z ↗
10. Jo · Adv. Mater. · 2023 · 35 · 220707610.1002/adma.202207076 ↗
11. Sata · Ceram. Int. · 1996 · 24 · 5310.1016/S0272-8842(96)00077-6 ↗
12. Antolini · Ceram. Int. · 1999 · 25 · 67710.1016/S0272-8842(98)00073-X ↗
13. McCalla · Solid State Ionics · 2012 · 219 · 1110.1016/j.ssi.2012.05.007 ↗
14. Li · Nano Mater. Sci. · 2023 · 5 · 40410.1016/j.nanoms.2022.09.001 ↗
15. Ashton · J. Mater. Chem. A · 2021 · 9 · 1047710.1039/D1TA01639C ↗
16. Guo · Nano Res. · 2022 · 15 · 896210.1007/s12274-022-4532-y ↗
17. Wu · ACS Appl. Mater. Interfaces · 2015 · 7 · 770210.1021/acsami.5b00645 ↗
18. Truong · Electrochim. Acta · 2021 · 391 · 13898210.1016/j.electacta.2021.138982 ↗
19. Kim · ACS Energy Lett. · 2021 · 6 · 94110.1021/acsenergylett.1c00086 ↗
20. Iida · J. Am. Ceram. Soc. · 1960 · 43 · 17110.1111/j.1151-2916.1960.tb14336.x ↗
21. Ikeda · J. Mass Spectrom. Soc. Jpn. · 1979 · 27 · 26310.5702/massspec1953.27.263 ↗
22. Konar · J. Eur. Ceram. Soc. · 2017 · 37 · 218910.1016/j.jeurceramsoc.2016.12.041 ↗
23. Antolini · J. Mater. Sci. · 1992 · 27 · 333510.1007/BF01116034 ↗
24. Antolini · J. Mater. Sci. Lett. · 1994 · 13 · 159910.1007/BF00704514 ↗
25. Antolini · Mater. Chem. Phys. · 2003 · 82 · 93710.1016/j.matchemphys.2003.08.006 ↗
26. Antolini · Mater. Lett. · 1993 · 16 · 28610.1016/0167-577X(93)90193-2 ↗
27. Wang · Chem. Mater. · 2019 · 31 · 273110.1021/acs.chemmater.8b04673 ↗
28. Klein · J. Mater. Chem. A · 2023 · 11 · 513510.1039/D2TA05957F ↗
29. Wu · Nat. Energy · 2025 · 10 · 60510.1038/s41560-025-01738-4 ↗
30. Estala-Rodriguez · Proc. Combust. Inst. · 2023 · 39 · 358310.1016/j.proci.2022.07.051 ↗
31. Nefedov · IOP Conf. Ser. Mater. Sci. Eng. · 2016 · 112 · 01202710.1088/1757-899X/112/1/012027 ↗
32. Yao · J. Electrochem. Soc. · 2013 · 160 · A82410.1149/2.069306jes ↗
33. Beyer · Phys. Chem. Chem. Phys. · 2013 · 15 · 1102510.1039/c3cp51056e ↗
34. Arkel · Can. J. Chem. · 1955 · 33 · 44610.1139/v55-053 ↗
35. Watari · J. Mater. Res. · 1999 · 14 · 1410.1557/JMR.1999.0191 ↗
36. Hoshino · Nucl. Mater. Energy · 2016 · 9 · 22110.1016/j.nme.2016.05.004 ↗
37. Lan · Int. J. Electrochem. Sci. · 2019 · 14 · 969510.20964/2019.10.22 ↗
38. Bale · Calphad · 2009 · 33 · 29510.1016/j.calphad.2008.09.009 ↗
39. Bale · Calphad · 2016 · 54 · 3510.1016/j.calphad.2016.05.002 ↗
40. Coessens · J. Eur. Ceram. Soc. · 2026 · 46 · 11812410.1016/j.jeurceramsoc.2025.118124 ↗
41. Kinnibrugh · Chem. Mater. · 2025 · 37 · 625610.1021/acs.chemmater.5c01173 ↗
42. Tran · ACS Sustainable Chem. Eng. · 2023 · 11 · 697810.1021/acssuschemeng.2c07428 ↗
43. M. W.Chase , NIST-JANAF Thermochemical Tables , in NIST-JANAF Thermochemical Tables , Journal of Physical and Chemical Reference Data, Monograph, American Institute of Physics , 1998 , 4th edn, pp. 1–1951 . https://janaf.nist.gov/janaf4pdf.html
44. Kurzhals · J. Electrochem. Soc. · 2022 · 169 · 05052610.1149/1945-7111/ac6c0b ↗
45. Dinh · J. Nucl. Mater. · 2005 · 347 · 3110.1016/j.jnucmat.2005.06.025 ↗
46. Sicklinger · J. Electrochem. Soc. · 2019 · 166 · A232210.1149/2.0011912jes ↗
47. Gurvich · J. Phys. Chem. Ref. Data · 1996 · 25 · 121110.1063/1.555982 ↗
48. Endah · Evergreen · 2024 · 11 · 226510.5109/7236869 ↗
49. Ben-Barak · J. Electrochem. Soc. · 2024 · 171 · 04053510.1149/1945-7111/ad3aa9 ↗