journal article·2026Open access

(3 + 2)D modulation governs vacancy ordering and oxide-ion transport in γ-type BIMEVOX conductors

Yajun Yue, Fengjin Qu, Aleksandra Dzięgielewska, Anucha Koedtruad, Qifeng Zheng, Wang Hay Kan, Stephen Hull, Marcin Malys, Marcin Krynski, Franciszek Krok, Takashi Honda, Shuki Torii, Vaclav Petricek, Isaac Abrahams, Ping Miao

Journal of Materials Chemistry A· Volume 14· Issue 27

Abstract

Incommensurate structural modulation in γ-type BICUVOX.10 constrains O 2− motion, elevating activation energy, while coupled apical–equatorial positional modulations generate versatile V/Cu coordination geometries and zig-zag oxide-ion diffusion.
Only a short abstract or summary was supplied by the source.
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Research context

OpenAlex topics: Advanced battery technologies research · Organic and Molecular Conductors Research · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Spallation Neutron Source Science Center, China Spallation Neutron Source, Dongguan, Guangdong, 523803, China

School of Chemistry, South China Normal University, Guangzhou 510006, Guangdong, China

Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, People's Republic of China

Faculty of Physics, Warsaw University of Technology, ul. Koszykowa 75, 00-662 Warsaw, Poland

Science and Technology Facilities Council, ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxon OX11 OQX, UK

Institute of Materials Structure Science, High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki 305-0801, Japan

Department of Structure Analysis, Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, 182 00 Prague 8, Czech Republic

Department of Chemistry, Queen Mary University of London, Mile End Road, London, E1 4NS, UK

Funding

National Natural Science Foundation of China · Basic and Applied Basic Research Foundation of Guangdong Province · Guangdong Provincial Introduction of Innovative Research and Development Team · Science and Technology Facilities Council · Japan Proton Accelerator Research Complex · Politechnika Warszawska

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