Engineering Brønsted acidity in metal–organic gels via d 0 -electron configuration for wide-temperature anhydrous proton conduction
Source abstract
Abstract
We introduce the Brønsted acid sites through the dopant electronic structure into gel. This achieves exceptional anhydrous conductivity from 1.9 × 10 −3 S cm −1 at 233 K to 5.0 × 10 −2 S cm −1 at 433 K.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short
Research context
OpenAlex topics: Covalent Organic Framework Applications · Organic and Molecular Conductors Research · Inorganic Fluorides and Related Compounds
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, Heilongjiang Province and School of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, P. R. China
Faculty of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China
Funding
Natural Science Foundation of Heilongjiang Province
References (35)
Show source-provided references
1. Lim · Chem. Soc. Rev. · 2021 · 50 · 634910.1039/D1CS00004G ↗
2. Sahoo · Adv. Energy Mater. · 2021 · 11 · 210230010.1002/aenm.202102300 ↗
3. Guo · Langmuir · 2023 · 39 · 1116610.1021/acs.langmuir.3c01205 ↗
4. Zhang · Joule · 2025 · 9 · 10185310.1016/j.joule.2025.101853 ↗
5. Yue · Energy Environ. Sci. · 2025 · 18 · 693410.1039/D5EE01108F ↗
6. Xiang · ACS Appl. Mater. Interfaces · 2021 · 13 · 4136310.1021/acsami.1c10351 ↗
7. Zhang · Dalton Trans. · 2021 · 50 · 1805310.1039/D1DT02686K ↗
8. Zhuang · J. Colloid Interface Sci. · 2024 · 657 · 48210.1016/j.jcis.2023.12.026 ↗
9. Jiang · Nat. Synth. · 2025 · 4 · 62210.1038/s44160-025-00738-2 ↗
10. Mukherjee · J. Am. Chem. Soc. · 2025 · 147 · 551510.1021/jacs.4c14029 ↗
11. Inukai · J. Am. Chem. Soc. · 2016 · 138 · 850510.1021/jacs.6b03625 ↗
12. Hu · Coord. Chem. Rev. · 2025 · 537 · 21671610.1016/j.ccr.2025.216716 ↗
13. Daliran · Chem. Soc. Rev. · 2024 · 53 · 624410.1039/D3CS01057K ↗
14. Di Palma · Adv. Mater. Interfaces · 2025 · 12 · 250016610.1002/admi.202500166 ↗
15. Fu · Small · 2023 · 19
16. Qiu · ACS Appl. Mater. Interfaces · 2020 · 12 · 1978810.1021/acsami.0c02048 ↗
17. Chen · Inorg. Chem. Front. · 2020 · 7 · 376510.1039/D0QI00883D ↗
18. Si · J. Mater. Chem. A · 2022 · 10 · 123610.1039/D1TA09348G ↗
19. Gao · J. Colloid Interface Sci. · 2023 · 650 · 1910.1016/j.jcis.2023.06.134 ↗
20. Hirata · Chem. Sci. · 2024 · 15 · 272510.1039/D3SC05455A ↗
21. Ma · J. Mater. Chem. A · 2023 · 11 · 1157210.1039/D3TA01221B ↗
22. Lim · Chem. Rev. · 2020 · 120 · 841610.1021/acs.chemrev.9b00842 ↗
23. Tang · J. Colloid Interface Sci. · 2022 · 607 · 18110.1016/j.jcis.2021.08.159 ↗
24. Yang · Adv. Mater. · 2023 · 35 · 221023510.1002/adma.202210235 ↗
25. Shannon · Acta Cryst. · 1976 · 32 · 75110.1107/S0567739476001551 ↗
26. Li · Chem. Commun. · 2023 · 59 · 254110.1039/D2CC06948B ↗
27. Ronda-Lloret · Adv. Funct. Mater. · 2021 · 31 · 210258210.1002/adfm.202102582 ↗
28. Li · Environ. Sci. Technol. · 2021 · 55 · 13209
29. Driscoll · J. Phys. Chem. C · 2018 · 122 · 1458210.1021/acs.jpcc.8b03283 ↗
30. Ye · J. Mater. Chem. A · 2016 · 4 · 406210.1039/C5TA10765B ↗
31. Liu · Cryst. Growth Des. · 2018 · 18 · 372410.1021/acs.cgd.8b00545 ↗
32. Chen · Inorg. Chem. Commun. · 2017 · 81 · 110.1016/j.inoche.2017.04.019 ↗
33. Ponomareva · J. Am. Chem. Soc. · 2012 · 134 · 1564010.1021/ja305587n ↗
34. Umeyama · Angew. Chem., Int. Ed. · 2011 · 50 · 1170610.1002/anie.201102997 ↗
35. Atzori · Dalton Trans. · 2020 · 49 · 579410.1039/D0DT01023E ↗