journal article·2026Open access

Can solvothermal synthesis drive defectivity and unlock better electrochemical performance in Li-rich layered oxides?

Arcangelo Celeste, Valeria Lombardi, Marta Mirolo, Yan Lu, Rafal E. Dunin-Borkowski, Eric Hirschmann, Maik Butterling, Macie O. Liedke, Andreas Wagner, Antonino Santoni, Priscilla Reale, Maria Assunta Navarra, Sergio Brutti, Laura Silvestri

Journal of Materials Chemistry A· Volume 14· Issue 6

Abstract

Modulating the electrochemical performance of Li-rich layered oxides through solvothermal induced defects.
Only a short abstract or summary was supplied by the source.
Source: crossref · Quality: short

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185, Rome, Italy

Department of Energy Technologies and Renewable Sources, ENEA C. R. Casaccia, via Anguillarese 301, 00123, Rome, Italy

Material Research Institute (IMFAA), Aalen University, Beethovenstraße 1, 73430, Aalen, Germany

ESRF – The European Synchrotron, 71 Avenue des Martyrs, 38000 Grenoble, France

Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons, Forschungszentrum Jülich GmbH, Wilhelm-Johnen-Straße, 52428, Jülich, Germany

Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstraße 400, 01328, Dresden, Germany

Nuclear Department, ENEA C. R. Frascati, via E.Fermi 45, 00044 Frascati, Italy

Funding

Ministero dell'ambiente e della sicurezza energetica · UK Research and Innovation · European Commission

References (48)

Show source-provided references
1. Bruce · Angew. Chem., Int. Ed. · 2008 · 47 · 293010.1002/ANIE.200702505 ↗
2. Tarascon · Joule · 2020 · 4 · 161610.1016/J.JOULE.2020.06.003 ↗
3. Grey · Nat. Commun. · 2020 · 11 · 110.1038/s41467-020-19991-4 ↗
4. Murdock · Adv. Energy Mater. · 2021 · 11 · 210202810.1002/AENM.202102028 ↗
5. Dühnen · Small Methods · 2020 · 4 · 200003910.1002/SMTD.202000039 ↗
6. Yu · Adv. Energy Sustainability Res. · 2021 · 2 · 200010210.1002/AESR.202000102 ↗
7. Silvestri · Crystals · 2023 · 13 · 20410.3390/CRYST13020204 ↗
8. Wang · Adv. Energy Mater. · 2016 · 6 · 160090610.1002/AENM.201600906 ↗
9. Celeste · Small Methods · 2024 · 8 · 230146610.1002/SMTD.202301466 ↗
10. Erickson · J. Electrochem. Soc. · 2017 · 164 · A634110.1149/2.0461701JES ↗
11. Jarvis · Chem. Mater. · 2011 · 23 · 361410.1021/cm200831c ↗
12. Genevois · J. Phys. Chem. C · 2014 · 119 · 7510.1021/jp509388j ↗
13. Armstrong · J. Am. Chem. Soc. · 2006 · 128 · 869410.1021/JA062027 ↗
14. Pimenta · Chem. Mater. · 2017 · 29 · 992310.1021/ACS.CHEMMATER.7B03230 ↗
15. Celeste · Electrochim. Acta · 2022 · 428 · 14073710.1016/j.electacta.2022.140737 ↗
16. Zhao · Angew. Chem., Int. Ed. · 2025 · 64 · e20250898010.1002/anie.202419664 ↗
17. Hua · Angew. Chem. · 2024 · 136 · e20240318910.1002/anie.202403189 ↗
18. Fu · J. Alloys Compd. · 2015 · 618 · 67310.1016/J.JALLCOM.2014.08.191 ↗
19. Fu · Electrochem. Commun. · 2014 · 44 · 5410.1016/J.ELECOM.2014.04.013 ↗
20. Wang · ACS Appl. Mater. Interfaces · 2017 · 9 · 2535810.1021/ACSAMI.7B07095 ↗
21. Malik · Mater. Today Energy · 2022 · 28 · 10106610.1016/J.MTENER.2022.101066 ↗
22. Shao · ACS Appl. Energy Mater. · 2023 · 6 · 253110.1021/ACSAEM.2C03971 ↗
23. Yan · Electrochim. Acta · 2017 · 224 · 16110.1016/J.ELECTACTA.2016.12.035 ↗
24. Celeste · ChemElectroChem · 2023 · 10 · e20220107210.1002/CELC.202201072 ↗
25. Dejoie · Appl. Crystallogr. · 2018 · 51 · 172110.1107/S1600576718014589 ↗
26. Fitch · J. Synchrotron Radiat. · 2023 · 30 · 100310.1107/S1600577523004915 ↗
27. Casas-Cabanas · J. Appl. Crystallogr. · 2016 · 49 · 225910.1107/S1600576716014473 ↗
28. Wagner · AIP Conf. Proc. · 2018 · 1970 · 4000310.1063/1.5040215/660121 ↗
29. Hirschmann · J. Instrum. · 2021 · 16 · P0800110.1088/1748-0221/16/08/P08001 ↗
30. R.Krause-Rehberg and H. S.Leipner , Positron Annihilation in Semiconductors: Defect Studies , 1999 , vol. 127 , 10.1007/978-3-662-03893-210.1007/978-3-662-03893-2 ↗
31. Olsen · Phys. Status Solidi C · 2007 · 4 · 400410.1002/PSSC.200675868 ↗
32. Dryzek · Nucl. Instrum. Methods Phys. Res., Sect. B · 2008 · 266 · 400010.1016/J.NIMB.2008.06.033 ↗
33. Celeste · ACS Appl. Energy Mater. · 2021 · 4 · 1129010.1021/ACSAEM.1C02133 ↗
34. Ma · Adv. Sci. Technol. Res. J. · 2023 · 4 · 51510.56028/AETR.4.1.515.2023 ↗
35. Llovell · Fluid Phase Equilib. · 2013 · 360 · 36710.1016/J.FLUID.2013.10.002 ↗
36. Dong · Spectrochim. Acta, Part A · 2019 · 222 · 11718310.1016/J.SAA.2019.117183 ↗
37. Ma · Angew. Chem., Int. Ed. · 2016 · 55 · 366710.1002/ANIE.201511196 ↗
38. Bautista · Condens. Matter Phys. · 2024 · 27 · 2320110.5488/cmp.27.23201 ↗
39. Ghoufi · J. Phys. Chem. B · 2016 · 120 · 79310.1021/ACS.JPCB.5B11776 ↗
40. Cardona · J. Phys. Chem. B · 2018 · 122 · 150510.1021/ACS.JPCB.7B12220 ↗
41. Petong · J. Phys. Chem. A · 2000 · 104 · 742010.1021/JP001393R ↗
42. Navarkhele · Int. J. Thermodyn. · 2022 · 25 · 110.5541/IJOT.1017174 ↗
43. Pečar · Fluid Phase Equilib. · 2005 · 230 · 3610.1016/J.FLUID.2004.11.019 ↗
44. Yuan · ACS Appl. Energy Mater. · 2023 · 6 · 622710.1021/ACSAEM.3C00755 ↗
45. Badajoz · J. Chem. Eng. Data · 2021 · 66 · 92810.1021/ACS.JCED.0C00686 ↗
46. Kramer · Chem. Mater. · 2009 · 21 · 379910.1021/cm9008943 ↗
47. Haasch · Surf. Sci. Spectra · 2019 · 2610.1116/1.5080240 ↗
48. Ilton · Appl. Surf. Sci. · 2016 · 366 · 47510.1016/J.APSUSC.2015.12.159 ↗