journal article·2025Open access

Revealing complex magnetic interactions in Fe 2 P-based compounds: a study using Mössbauer spectroscopy and neutron diffraction

Karthika K. Thilakan, Sagar Ghorai, Wei Liu, Lennart Häggström, Fredrik Lindgren, Vladimir Pomjakushin, Premysl Beran, Oliver Gutfleisch, Peter Svedlindh, Johan Cedervall

Journal of Materials Chemistry A· Volume 13· Issue 36

Abstract

In Fe 2−2 x Mn 2 x P 1− x Si x , the magnetic properties have 4 different regions out of which 3 have ferromagnetic character. In region (ii), a glassy magnetic behaviour is found with an incommensurate ordering, exemplified with Fe 1.8 Mn 0.2 P 0.9 Si 0.1 .
The source flagged this abstract for review. Check formulas and completeness against the original publication.
Source: crossref · Quality: needs review · Source record ↗
Source flags: short_text

Research context

OpenAlex topics: Iron oxide chemistry and applications · Magnetic Properties and Synthesis of Ferrites · Magnetic properties of thin films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Ångström Laboratory, Uppsala University, Box 538, 751 21 Uppsala, Sweden

Institute of Materials Science, Technical University of Darmstadt, 64287 Darmstadt, Germany

Department of Physics and Astronomy, Uppsala University, Box 516, 751 20 Uppsala, Sweden

Laboratory for Neutron Scattering and Imaging, Paul Scherrer Institut, 5232 Villigen, Switzerland

European Spallation Source ESS ERIC, Box 176, 221 00, Lund, Sweden

Nuclear Physics Institute, ASCR, Hlavni 130, 25068 Rez, Czech Republic

Department of Materials Science and Engineering, Uppsala University, Box 35, 751 03 Uppsala, Sweden

WISE – Wallenberg Initiative Materials Science for Sustainability, Department of Materials Science and Engineering, Uppsala University, SE-751 03 Uppsala, Sweden

Funding

Stiftelsen Åforsk · Stiftelsen för Strategisk Forskning · Deutsche Forschungsgemeinschaft · European Commission

References (39)

Show source-provided references
1. Brück · J. Phys. D: Appl. Phys. · 2005 · 38 · R38110.1088/0022-3727/38/23/R01 ↗
2. Khovaylo · Phys. Status Solidi B · 2014 · 251 · 210410.1002/pssb.201451217 ↗
3. França · J. Magn. Magn. Mater. · 2016 · 401 · 108810.1016/j.jmmm.2015.10.138 ↗
4. Gschneidner · Int. J. Refrig. · 2008 · 31 · 94510.1016/j.ijrefrig.2008.01.004 ↗
5. Dung · Adv. Energy Mater. · 2011 · 1 · 121510.1002/aenm.201100252 ↗
6. Yibole · J. Phys. D: Appl. Phys. · 2014 · 47 · 07500210.1088/0022-3727/47/7/075002 ↗
7. Lundgren · Phys. Scr. · 1978 · 17 · 3910.1088/0031-8949/17/1/008 ↗
8. Trung · Appl. Phys. Lett. · 2009 · 94 · 10251310.1063/1.3095597 ↗
9. Guillou · Adv. Mater. · 2014 · 26 · 267110.1002/adma.201304788 ↗
10. Thanh · J. Appl. Phys. · 2008 · 103 · 07B31810.1063/1.2836958 ↗
11. Bacmann · J. Magn. Magn. Mater. · 1994 · 134 · 5910.1016/0304-8853(94)90073-6 ↗
12. Hudl · Phys. Rev. B · 2011 · 83 · 13442010.1103/PhysRevB.83.134420 ↗
13. Dung · Phys. Rev. B · 2012 · 86 · 04513410.1103/PhysRevB.86.045134 ↗
14. Malaman · J. Phys.: Condens. Matter · 1996 · 8 · 8653
15. Fruchart · Crystals · 2019 · 9 · 3710.3390/cryst9010037 ↗
16. Miao · Phys. Rev. B · 2014 · 89 · 17442910.1103/PhysRevB.89.174429 ↗
17. Jernberg · J. Solid State Chem. · 1984 · 53 · 31310.1016/0022-4596(84)90108-7 ↗
18. Wäppling · J. Solid State Chem. · 1975 · 13 · 25810.1016/0022-4596(75)90128-0 ↗
19. Ghorai · Phys. Rev. B · 2023 · 107 · 10440910.1103/PhysRevB.107.104409 ↗
20. Gottschall · Adv. Energy Mater. · 2019 · 9 · 190132210.1002/aenm.201901322 ↗
21. Höglin · J. Solid State Chem. · 2015 · 221 · 24010.1016/j.jssc.2014.10.013 ↗
22. Höglin · J. Solid State Chem. · 2011 · 184 · 243410.1016/j.jssc.2011.06.019 ↗
23. Katagiri · J. Alloys Compd. · 2013 · 553 · 28610.1016/j.jallcom.2012.11.127 ↗
24. Carlsson · J. Solid State Chem. · 1973 · 8 · 5710.1016/0022-4596(73)90021-2 ↗
25. Fischer · Phys. B · 2000 · 276–278 · 14610.1016/S0921-4526(99)01399-X ↗
26. Rietveld · J. Appl. Crystallogr. · 1969 · 2 · 6510.1107/S0021889869006558 ↗
27. Rodriguez-Carvajal · Phys. B · 1993 · 192 · 5510.1016/0921-4526(93)90108-I ↗
28. Wills · Phys. B · 2000 · 276–278 · 68010.1016/S0921-4526(99)01722-6 ↗
29. Neish · Phys. Rev. Lett. · 2015 · 114 · 10610110.1103/PhysRevLett.114.106101 ↗
30. Cedervall · Phys. Rev. B · 2019 · 99 · 17443710.1103/PhysRevB.99.174437 ↗
31. Ericsson · Phys. Scr. · 1980 · 21 · 21210.1088/0031-8949/21/2/020 ↗
32. Mugiraneza · Commun. Phys. · 2022 · 5 · 9510.1038/s42005-022-00853-y ↗
33. Ghorai · J. Alloys Compd. · 2022 · 895 · 16271410.1016/j.jallcom.2021.162714 ↗
34. Ghorai · J. Phys.: Condens. Matter · 2021 · 33 · 145801
35. Ou · J. Magn. Magn. Mater. · 2013 · 340 · 8010.1016/j.jmmm.2013.03.028 ↗
36. Miao · Rare Met. · 2018 · 37 · 72310.1007/s12598-018-1090-2 ↗
37. Miao · Phys. Rev. B · 2016 · 94 · 01442610.1103/PhysRevB.94.014426 ↗
38. Singh · Mater. Res. Express · 2019 · 6 · 06610710.1088/2053-1591/ab0ccc ↗
39. Li · Appl. Phys. Lett. · 2014 · 105 · 26240510.1063/1.4905270 ↗