journal article·2025-07-04

Durability and mechanical performance of copper azole-treated cross-laminated timber (CLT) in-ground-contact exposure for 6 months

Hasan Öztürk, Aydın Demir, Abdullah Uğur Birinci, Okan İlhan, Cenk Demirkir, Engin Derya Gezer

Publisher page

Abstract

Cross-laminated timber (CLT) is a sustainable engineered wood product increasingly used in outdoor and structural applications. However, its durability in-ground-contact environments remains a concern due to moisture and biological degradation risks. This study investigated the mechanical performance and durability of copper azole (CuAz)-treated CLT after six months of open-field ground-contact exposure. Scots pine timbers were impregnated with CuAz at three different retention levels (7.4, 8.1, and 9.4 kg/m³) and used to manufacture CLT. Both destructive (bending strength, modulus of elasticity, shear strength) and non-destructive (screw withdrawal resistance, dynamic modulus of elasticity) tests were applied before and after exposure. Results indicated that CuAz treatment enhanced biological durability but negatively affected mechanical properties, with greater strength losses at higher CuAz retention levels. Significant copper leaching was observed, especially in below-ground sections. The findings emphasize the need to balance preservative retention and mechanical performance and highlight the importance of long-term field evaluations for treated CLT in ground-contact applications. These findings contribute toward closing the knowledge gap in the field performance of preservative-treated CLT and provide foundational data to inform future standardization efforts.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Wood Treatment and Properties · Lignin and Wood Chemistry · Bamboo properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Karadeniz Technical University

HC Panel Forest Products Consulting Services Industry and Trade Limited Company

Funding

TUBITAK · The Scientific and Technical Research Council of Turkey · European Cooperation in Science and Technology

References (77)

Show source-provided references
1. 10.1007/s00107-020-01609-710.1007/s00107-020-01609-7 ↗
2. 10.3390/polym1510234910.3390/polym15102349 ↗
3. ANSI, 2019. ANSI/APA PRG 320-2012: standard for performance-rated cross-laminated timber. Washington, DC: American National Standards Institute (ANSI). AL.
4. AWPA, 1991. AWPA p5: standard for waterborne preservative. Washington, DC: American Wood Preserves Association (AWPA). AL.
5. AWPA, 2013a. AWPA e7: standard field test for evaluating the effectiveness of wood preservatives in ground contact (UC4A, UC4B, UC4C). Birmingham, AL: American Wood Preserves Association (AWPA).
6. AWPA, 2013b. AWPA e8: standard field test for evaluating the effectiveness of wood preservatives in above-ground applications (UC3B). Birmingham, AL: American Wood Preserves Association (AWPA).
7. AWPA, 2024. AWPA a7: standard wet ashing procedures for preparing wood for chemical analysis. Birmingham, AL: American Wood Preserves Association (AWPA).
8. 10.1016/j.jobe.2021.10373110.1016/j.jobe.2021.103731 ↗
9. Ayanleye S.O. 2023. Development of preservative-treated cross-laminated timber and lignin-reinforced polyurethane-adhesive for glued laminated timber. Doctoral dissertation. Mississippi State University.10.1080/01694243.2023.2235799 ↗
10. 10.1186/s10086-022-02041-610.1186/s10086-022-02041-6 ↗
11. 10.3390/f1309138710.3390/f13091387 ↗
12. 10.15376/biores.15.4.8420-843310.15376/biores.15.4.8420-8433 ↗
13. 10.1007/s00107-015-0999-510.1007/s00107-015-0999-5 ↗
14. 10.3390/f1205059010.3390/f12050590 ↗
15. 10.1016/j.ibiod.2013.06.02210.1016/j.ibiod.2013.06.022 ↗
16. Brischke, C., and Rapp, A., 2010. Service life prediction of wooden components—Part 1: determination of dose-response functions for above ground decay. In: The international research group on wood protection 41st annual meeting, 9–13 May 2010, Biarritz, France. IRG/WP 10-20439.
17. CEN, 2014a. EN 252: field test method for determining the relative protective effectiveness of a wood preservative in ground contact. Brussels: The European Committee for Standardization (CEN).
18. CEN, 2014b. EN 408+A1: timber structures – structural timber and glued laminated timber – determination of some physical and mechanical properties. Brussels: The European Committee for Standardization (CEN).
19. CEN, 2016. EN 338: structural timber – strength classes. Brussels: The European Committee for Standardization (CEN).
20. 10.1201/978131564164510.1201/9781315641645 ↗
21. 10.1080/17480272.2025.249371010.1080/17480272.2025.2493710 ↗
22. 10.15376/biores.15.3.5725-573610.15376/biores.15.3.5725-5736 ↗
23. Diebold, R., Schleifer, A., and Glos, P., 2000. Machine grading of structural sawn timber from various softwood and hardwood species. In: Proceedings of the 12th international symposium on nondestructive testing of wood. Sopron: University of West Hungary, 139–146.
24. 10.1016/j.engstruct.2023.11702910.1016/j.engstruct.2023.117029 ↗
25. 10.1016/j.engstruct.2023.11702910.1016/j.engstruct.2023.117029 ↗
26. Evans, P.D., Lyon, F., and Cunningham, R.B., 2013. The effects of copper-based wood preservatives on mechanical properties of treated timber. Wood Science and Technology, 47 (2), 421–435.
27. Gagnon, S. and Pirvu, C.2011. CLT handbook: cross-laminated timber. Québec: FPInnovations.
28. Gezer E.D. et al. 2025. The effects of Cu-Az and Tarımbor treatment on the mechanical properties of CLT. Under review.
29. Hanhijärvi A. and Ranta-Maunus A. 2008. Development of strength grading of timber using combined measurement techniques: Report of the Combigrade project – phase 2. VTT Technical Research Centre of Finland.
30. Jin, J., et al., 2021. Comparative performance of solid wood and engineered wood products treated with copper-based preservatives. Journal of Wood Chemistry and Technology, 41 (3), 212–230.
31. Jusoh I.B. 2000. Microdistribution of chromated copper arsenate preservative in rubberwood (Hevea brasiliensis Muell. Arg.). Doctoral dissertation Michigan State University. ProQuest Dissertations & Theses. https://www.proquest.com/docview/304616107.
32. Kirker G.T. et al. 2024. Evaluation of mass timber materials for military and commercial trailer decking. In Proceedings of the IRG Annual Meeting (IRG/WP 24-41009). The International Research Group on Wood Protection.
33. Lebow S.T. 2010. Wood preservation. In: Wood handbook: wood as an engineering material (Centennial ed. Chapter 15 General Technical Report FPL-GTR-190). U.S. Department of Agriculture Forest Service Forest Products Laboratory 15.1–15.28. https://www.fpl.fs.usda.gov/documnts/fplgtr/fplgtr190/chapter_15.pdf.
34. 10.2737/FPL-RP-62010.2737/FPL-RP-620 ↗
35. 10.1016/j.conbuildmat.2019.11720810.1016/j.conbuildmat.2019.117208 ↗
36. Lisperguer, J.H., and Becker, P.H., 2005. Strength and durability of phenol-resorcinol formaldehyde bonds to CCA-treated radiata pine wood. Forest Products Journal, 55 (12), 113–116.
37. 10.1007/s00107-024-02184-x10.1007/s00107-024-02184-x ↗
38. Lorenz, L.F., and Frihart, C.R., 2006. Adhesive bonding of wood treated with ACQ and copper azole preservatives. Forest Products Journal, 56 (9), 90–93. https://www.fpl.fs.usda.gov/documnts/pdf2006/fpl_2006_lorenz001.pdf.
39. 10.1163/156856198X0028110.1163/156856198X00281 ↗
40. 10.3390/polym1208163810.3390/polym12081638 ↗
41. 10.3390/f1112128410.3390/f11121284 ↗
42. Meteorological General Directorate (MGM) 2025. Turkish State Meteorological Service. Rainfall Forecast Map Trabzon. https://www.mgm.gov.tr/tahmin/yagistahmin.aspx.
43. Mitsuhashi Gonzalez J.M. 2007. Limiting copper loss from treated wood in or near aquatic environments. Master's thesis Oregon State University. Oregon State University Library. https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/qz20sv42h.
44. 10.3390/ijerph1811551810.3390/ijerph18115518 ↗
45. Morris, P.I., and Ingram, J.K., 2015. Field testing in Canada XXIV: Ten years inspection of profiled decking. In: Proceedings of the thirty sixth annual meeting Canadian wood preservation association [CD ROM], October. Ottawa, ON, Canada, 27–28.
46. 10.1080/17480272.2021.187194910.1080/17480272.2021.1871949 ↗
47. 10.32604/jrm.2022.01963410.32604/jrm.2022.019634 ↗
48. 10.1016/j.prostr.2018.11.03210.1016/j.prostr.2018.11.032 ↗
49. 10.3390/f1212173410.3390/f12121734 ↗
50. 10.1155/2015/52549610.1155/2015/525496 ↗
51. 10.1016/j.culher.2012.10.00110.1016/j.culher.2012.10.001 ↗
52. 10.1007/BF0034991710.1007/BF00349917 ↗
53. 10.1016/j.conbuildmat.2015.12.10710.1016/j.conbuildmat.2015.12.107 ↗
54. 10.13073/FPJ-D-23-0003110.13073/FPJ-D-23-00031 ↗
55. 10.1080/02773813.2023.228416110.1080/02773813.2023.2284161 ↗
56. 10.1016/j.engstruct.2024.11855210.1016/j.engstruct.2024.118552 ↗
57. Richardson, P., 2007. A benchmark for Glasfryn: a small Welsh sawmill is making a name for itself by growing, processing and treating all its own timber. TTJ-The Timber Industry Magazine, 422 (6606), 26–27.
58. 10.1016/j.conbuildmat.2012.02.00910.1016/j.conbuildmat.2012.02.009 ↗
59. 10.1016/j.conbuildmat.2019.05.01310.1016/j.conbuildmat.2019.05.013 ↗
60. 10.13073/FPJ-D-21-0006710.13073/FPJ-D-21-00067 ↗
61. 10.1016/j.ijadhadh.2024.10392410.1016/j.ijadhadh.2024.103924 ↗
62. 10.13073/FPJ-D-20-0007610.13073/FPJ-D-20-00076 ↗
63. 10.5772/6575910.5772/65759 ↗
64. 10.1007/s00107-002-0351-810.1007/s00107-002-0351-8 ↗
65. Van den Bulcke, J., et al., 2010. Improved analysis of field test data related to service life prediction of tropical wood species. In: Proceedings of the 41st annual meeting of the international research group on wood protection (IRG/WP 10-20458). Biarritz, France.
66. Vick, C.B., and Kuster, T.A., 1992. Mechanical interlocking of adhesive bonds to CCA-treated southern pine: a scanning electron-microscopic study. Wood and Fiber Science, 24 (1), 36–46.
67. Vidrine C.L. 2008. Copper compounds for durable composites: effects on material properties. Doctoral dissertation. Oregon State University. https://ir.library.oregonstate.edu/concern/graduate_thesis_or_dissertations/ft848s866.
68. 10.15376/biores.9.3.3869-388210.15376/biores.9.3.3869-3882 ↗
69. 10.22382/wfs-2018-04510.22382/wfs-2018-045 ↗
70. 10.15376/biores.19.4.9497-950910.15376/biores.19.4.9497-9509 ↗
71. Winandy, J.E., 1995. Effects of waterborne preservative treatment on mechanical properties: a review. In: Proceedings of the 91st annual meeting of the American wood-preservers’ association (Vol. 91) New York: American Wood-Preservers' Association, 17–34.
72. Winandy, J.E., and Lebow, P.K., 2001. Modeling strength loss in wood by chemical composition. Part I: an individual component model for southern pine. Wood and Fiber Science, 33 (2), 239–254.
73. 10.1007/s13595-017-0625-210.1007/s13595-017-0625-2 ↗
74. 10.1007/s00107-011-0584-510.1007/s00107-011-0584-5 ↗
75. 10.1016/j.buildenv.2004.01.03210.1016/j.buildenv.2004.01.032 ↗
76. 10.1007/s00107-020-01644-410.1007/s00107-020-01644-4 ↗
77. 10.1016/j.compositesb.2016.12.02710.1016/j.compositesb.2016.12.027 ↗