journal article·2025-02

Magnetic properties of the RNiIn4 (R = Ce, Pr, Nd) series of intermetallic compounds grown by the metallic flux method

D.N. Possidonio, A.M. Caffer, S.G. Mercena, W.O. Santos, G.S. Freitas, P.G. Pagliuso, C.B.R. Jesus

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Abstract

This work focuses on the synthesis, structural and magnetic characterization, and the effects of the Crystal Electric Field (CEF) of RNiIn 4 (R = Ce, Pr, Nd) compounds. By using the metal flux technique, high-quality single crystals were obtained and analyzed X-ray diffraction and confirmed the formation of a single phase for all compounds and revealed their crystallization in a orthorhombic structure. Magnetic susceptibility measurements revealed antiferromagnetic in order ing temperatures ( T N ) at 4.02 K, 2.37 K and 4.06 for Ce, Pr, and Nd, respectively. Specific heat data corroborated these findings. The results indicate the easy axis of magnetization lies in the a b -plane for Ce and Nd, and along the c -axis for Pr.
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Research context

OpenAlex topics: Rare-earth and actinide compounds · Magnetic Properties of Alloys · Inorganic Chemistry and Materials

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