journal article·2022-05

Novel compounds Bi2Ni(SeO3)4 and Bi2Ni(SeO3)4·2H2O with cubic-like magnetic lattice and intriguing magnetic behavior

Bing Yu, Kui Xu, Yang Shen, Yurui Zhang, Lin Sun, Weibin Lei, Shuai Yang, Fangyu Yue, Zaiyong Zhang, Chungang Duan, Qiuxiang Zhu, Qingbiao Zhao

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Abstract

Two novel compounds Bi 2Ni(SeO 3) 4 and Bi 2Ni(SeO 3) 4·2H 2 O were synthesized by hydrothermal method and their crystal structures were solved via single crystal diffraction. The magnetic Ni 2+ ions are arranged in a cubic-like mode, while both Bi 2Ni(SeO 3) 4 and Bi 2Ni(SeO 3) 4·2H 2O exhibit magnetic frustration. Notably, the magnetic measurement shows that Bi 2Ni(SeO 3) 4 has a Weiss temperature of −21 K but does not exhibit any magnetic ordering down to 2 K. This study provides a scheme for realizing magnetic frustration with compounds of cubic-like magnetic lattice. In the future, it is intriguing to uncover the ground magnetic state of Bi 2Ni(SeO 3) 4.
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Research context

OpenAlex topics: Advanced Condensed Matter Physics · High-pressure geophysics and materials · Magnetic and transport properties of perovskites and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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