journal article·2002-05Open access

Many-spin effects and tunneling splittings in Mn12 magnetic molecules

H.A. De Raedt, A.H. Hams, V.V. Dobrovitski, M. Al-Saqer, M.I. Katsnelson, B.N. Harmon

Abstract

We calculate the tunneling splittings in a Mn$12$ magnetic molecule taking into account its internal many-spin structure. We discuss the precision and reliability of these calculations and show that restricting the basis (limiting the number of excitations taken into account) may lead to significant error (orders of magnitude) in the resulting tunneling splittings for the lowest energy levels, so that an intuitive picture of different decoupled energy scales does not hold in this case. Possible routes for further development of the many-spin model of Mn$12$ are discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetism in coordination complexes · Magnetic properties of thin films · Advanced Physical and Chemical Molecular Interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (23)

Show source-provided references
1. O. Kahn, Molecular Magnetism, VCH, New York, 1993.
2. Friedman · Phys. Rev. Lett. · 1996 · 76 · 383010.1103/PhysRevLett.76.3830 ↗
3. Thomas · Nature · 1996 · 383 · 14510.1038/383145a0 ↗
4. Wernsdorfer · Science · 1999 · 284 · 13310.1126/science.284.5411.133 ↗
5. Wernsdorfer · Phys. Rev. Lett. · 1999 · 82 · 390310.1103/PhysRevLett.82.3903 ↗
6. Barbara · J. Magn. Magn. Mater. · 1999 · 200 · 16710.1016/S0304-8853(99)00409-6 ↗
7. Chiorescu · Phys. Rev. Lett. · 2000 · 85 · 480710.1103/PhysRevLett.85.4807 ↗
8. Sangregorio · Phys. Rev. Lett. · 1997 · 78 · 464510.1103/PhysRevLett.78.4645 ↗
9. van Hemmen · Physica B · 1986 · 141 · 3710.1016/0378-4363(86)90347-5 ↗
10. Enz · J. Phys. C · 1986 · 19 · 176510.1088/0022-3719/19/11/014 ↗
11. Dobrovitski · J. Appl. Phys. · 1998 · 83 · 659910.1063/1.367849 ↗
12. Kashurnikov · Phys. Rev. B · 1999 · 59 · 116210.1103/PhysRevB.59.1162 ↗
13. De Raedt · Phys. Rep. · 1993 · 231 · 10710.1016/0370-1573(93)90015-6 ↗
14. De Raedt · 1999
15. Al-Saqer · J. Appl. Phys. · 2000 · 87 · 626810.1063/1.372675 ↗
16. Sessoli · J. Am. Chem. Soc. · 1993 · 115 · 180410.1021/ja00058a027 ↗
17. Barbara · J. Magn. Magn. Mater. · 1995 · 140–144 · 182510.1016/0304-8853(94)00585-0 ↗
18. Katsnelson · Phys. Rev. B · 1999 · 59 · 691910.1103/PhysRevB.59.6919 ↗
19. Hennion · Phys. Rev. · 1997 · 56 · 881910.1103/PhysRevB.56.8819 ↗
20. J.H. Wilkinson, The Algebraic Eigenvalue Problem, Clarendon Press, Oxford, 1965. (Extended precision calculations where done on a Cray C90, using 28-digit arithmetics and checked against 33-digit calculations of 1000×1000 problems on a Pentium III processor.)
21. Yosida · 1996
22. Levine · Phys. Rev. Lett. · 1995 · 75 · 414210.1103/PhysRevLett.75.4142 ↗
23. Mattis · 1965