Correlation driven a novel spin-polarized hourglass loop in monolayer VCl2

Hourglass loop in two-dimensional (2D) systems is typically vulnerable against spin–orbit coupling (SOC). Here, we explore 2D systems with a type of spin-polarized nodal loop that is robust under SOC and characteristic of an hourglass-type dispersion. Through first-principles calculations, we identify the monolayer VCl ₂ materials as a realistic material platform to realize an hourglass loop. There exist three phases, all of which are dynamically stable. For the γ-structure, as a new single spin hourglass loop material. It shows semiconducting and gapless properties in spin down and spin up channels, respectively. Moreover, it always exhibits an hourglass loop property in the absence and presence of SOC. It indicates that the hourglass has strong against SOC. Our work suggests a realistic material platform for investigating the novel physics associated with band crossings in 2D systems.