Limitations of scaling laws for determining the order of magnetic phase transitions in antiperovskite materials
Source abstract
Abstract
For materials with magnetic phase transition, researchers have tried to find a simple magnetic method that can replace the calorimetric technique for determining the type of phase transition. Recently, the researchers provide a quantitative characteristic of first-order magnetic phase transitions, which is believed to have wide application prospect. The maximum exponent n, calculated from field dependence of magnetic entropy change, is>2 only for first-order phase transitions. This method has been tested in Bean-Rodbell model and for various types of materials with first-order phase transitions from ferromagnetic to paramagnetic or antiferromagnetic to ferromagnetic state. However, in this work, the determination of the order of phase transitions based on field dependence of magnetic entropy change contradicts the results of calorimetric measurements in antiperovskite compounds Mn 3SnC and MnCu 0.97N. This discrepancy may be associated with a first-order magnetic transition from ferrimagnetic to paramagnetic state in antiperovskite materials.
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Research context
OpenAlex topics: Thermal Expansion and Ionic Conductivity · Solid-state spectroscopy and crystallography · Advanced Thermoelectric Materials and Devices
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (36)
Show source-provided references
1. Hysteresis design of magnetocaloric materials—from basic mechanisms to applications10.1002/ente.201800264 ↗
2. Deconvolution of overlapping first and second order phase transitions in a NiMnIn Heusler alloy using the scaling laws of the magnetocaloric effect10.1016/j.jallcom.2021.159621 ↗
3. L. E. L, Silva, J. C, Patiño, A. M, Gomes, On the structural and thermo-magnetic study of the magnetocaloric Heusler alloy Ni2Mn1- xCuxGa0.8Al0.2, J. Phys.: Condens. Matter. 33 (2021) 235701. https://doi.org/10.1088/1361-648X/abe89f.10.1088/1361-648X/abe89f ↗
4. Phase-transition-induced magneto-elastic coupling and negative thermal expansion in (Hf, Ta)Fe-1.98 Laves phase10.1016/j.jmmm.2020.167236 ↗
5. Regulation of magnetic phase transition and magnetocaloric effect of DyCo2-xCrx compounds10.1002/pssb.202000566 ↗
6. Successive magnetic transitions and magnetocaloric effects in intermetallic compounds RE7Rh3 (RE=Nd, Ho)10.1016/j.jallcom.2020.156379 ↗
7. Characterization of thermal hysteresis in magnetocaloric NiMnIn Heusler alloys by temperature first order reversal curves (TFORC)10.1016/j.jallcom.2021.159184 ↗
8. Giant magnetocaloric effect driven by first-order magnetostructural transition in cosubstituted Ni-Mn-Sb Heusler compounds: predictions from ab initio and Monte Carlo calculations10.1103/PhysRevB.103.054101 ↗
9. Calorimetric study of the giant magnetocaloric effect in (MnNiSi)0.56(FeNiGe)0.4410.1103/PhysRevB.103.104402 ↗
10. Effects of transitional hysteresis on the large magnetocaloric and magnetoresistance properties of Ni-Mn-Co-Sn Heusler alloy10.1016/j.jallcom.2020.158485 ↗
11. Predicting the thermal hysteresis behavior for a single-layer MnFeP1−xSix active magnetic regenerator10.1016/j.applthermaleng.2020.116173 ↗
12. Enhanced magnetocaloric effects in Gd2In1−xAlx (0.4 ≤x ≤1) system by the hysteresis-free metamagnetism10.1016/j.jmmm.2020.167648 ↗
13. Significant reduction of phase-transition hysteresis for magnetocaloric (La1-xCex)2Fe11Si2Hy alloys by microstructural manipulation10.1016/j.actamat.2021.116687 ↗
14. V, Basso, M, Kupferling, C, Curcio, C, Bennati, A, Barzca, M, Katter, M, Bratko, E, Lovell, J, Turcaud, L. F, Cohen, Specific heat and entropy change at the first order phase transition of La(Fe-Mn-Si)13-H compounds, J. Appl. Phys. 118 (2015) 053907. https://doi.org/10.1063/1.4928086.10.1063/1.4928086 ↗
15. Two different critical regimes enclosed in the Bean-Rodbell model and their implications for the field dependence and universal scaling of the magnetocaloric effect10.1039/C6CP06291A ↗
16. A, Anand, M, Manjuladevi, R. K, Veena, V. S, Veena, Y. S, Koshkid’ko, S, Sagar, A study on spin memory, nature of magnetic transition, and magnetocaloric effect in Nd0.5Ca0.5MnO3, J. Magn. Magn. Mater. 528 (2021) 167810. https://doi.org/10.1016/j.jmmm.2021.167810.10.1016/j.jmmm.2021.167810 ↗
17. S.K, Sarkar, S, Ahlawat, S.D, Kaushik, P.D, Babu, D, Sen, D, Honecker, A, Biswas, Magnetic ordering of the martensite phase in Ni–Co–Mn–Sn-based ferromagnetic shape memory alloys, J. Phys.: Condens. Matter. 32 (2020) 115801. https://doi.org/10.1088/1361-648X/ab5876.10.1088/1361-648X/ab5876 ↗
18. On a generalized approach to first and second order magnetic transitions10.1016/0031-9163(64)91158-8 ↗
19. V, Franco, J. S, Blázquez, A, Conde, Field dependence of the magnetocaloric effect in materials with a second order phase transition: A master curve for the magnetic entropy change, Appl. Phys. Lett. 89 (2006) 222512. https://doi.org/10.1063/1.2399361.10.1063/1.2399361 ↗
20. Magnetic properties of La0.7-xPrxCa0.3MnO3 single crystals: when is Banerjee criterion applicable?10.1016/j.jmmm.2013.10.033 ↗
21. Reversibility of the magnetocaloric effect in the Bean-Rodbell Model10.3390/magnetochemistry7050060 ↗
22. L. M, Moreno-Ramírez, J. S, Blázquez, I. A, Radulov, K. P, Skokov, O, Gutfleisch, V, Franco, A, Conde. Combined kinetic and Bean–Rodbell approach for describing field-induced transitions in LaFe11.6Si1.4 alloys, J. Phys. D: Appl. Phys. 54, (2021) 135003. https://doi.org/10.1088/1361-6463/abd583.10.1088/1361-6463/abd583 ↗
23. Scaling laws for the magnetocaloric effect in second order phase transitions: from physics to applications for the characterization of materials10.1016/j.ijrefrig.2009.12.019 ↗
24. Magnetocaloric effect in bulk amorphous Pd40Ni22.5Fe17.5P20 alloy10.1063/1.1456957 ↗
25. The magnetocaloric effect in soft magnetic amorphous alloys10.1063/1.2709409 ↗
26. A quantitative criterion for determining the order of magnetic phase transitions using the magnetocaloric effect10.1038/s41467-018-05111-w ↗
27. Landau model evaluation of the magnetic entropy change in magnetocaloric materials10.1016/j.jmmm.2021.167871 ↗
28. Analysis of the magnetic field dependence of the isothermal entropy change of inverse magnetocaloric materials10.1016/j.rinp.2021.103933 ↗
29. Relationship between spin ordering, entropy, and anomalous lattice variation in Mn3Sn1−εSiεC1−δ compounds10.1021/ic403063t ↗
30. Phase transitions and magnetocaloric effect in Mn3Cu0.89N0.9610.1016/j.actamat.2014.04.005 ↗
31. E, Mendive-Tapia, J. B, Staunton, Caloric effects around phase transitions in magnetic materials described by ab initio theory: The electronic glue and fluctuating local moments, J. Appl. Phys. 127 (2020) 113903. https://doi.org/10.1063/5.0003243.10.1063/5.0003243 ↗
32. Giant barocaloric effect enhanced by the frustration of the antiferromagnetic phase in Mn3GaN10.1038/nmat4117 ↗
33. Baromagnetic effect in antiperovskite Mn3Ga0.95N0.94 by neutron powder diffraction analysis10.1002/adma.201600310 ↗
34. Negative thermal expansion, magnetic and electronic transport properties in antiperovskite compounds Mn3Ga1-xAgxN (0≤x≤1.0)10.1016/j.jmmm.2020.167137 ↗
35. A. C, Larson, R. B, Von Dreele, General Structure Analysis System (GSAS), Technical Report LAUR 86−748 for Los Alamos National Laboratory: Los Alamos, NM, 2004.
36. Review of the magnetocaloric effect in manganite materials10.1016/j.jmmm.2006.07.025 ↗