Anomalous properties of PrMg3 with the cubic Γ3 ground state
Source abstract
Abstract
Abstract The electrical resistivity ρ ( T ) has been measured on a single crystal of PrMg 3 . PrMg 3 shows a Kondo-like broad anomaly in the specific heat C P ( T ) at low T arising from multipole (quadrupole and octupole) degrees of freedom of the non-magnetic, non-Kramers Γ 3 doublet ground state of Pr 3+ ions. Observed non-Kondo-like behavior of ρ ( T ) is discussed in connection with similar behavior in closely related PrAg 2 In, where we show that the characteristic band structure and the symmetry properties of the hybridization between conduction and f electrons can explain the seemingly contradictory behavior between C P ( T ) and ρ ( T ).
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Rare-earth and actinide compounds · Thermodynamic and Structural Properties of Metals and Alloys · Advanced Chemical Physics Studies
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References (14)
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