journal article·2018-01

Magnetic and magnetoelectric properties of NdCrTiO 5 revealed by systematically rare-earth doping

Qing Li, Zhenjie Feng, Cheng Cheng, Bojie Wang, Hao Chu, Ping Huang, Difei Wang, Xiaolong Qian, Chuan Yu, Guohua Wang, Dongmei Deng, Chao Jing, Shixun Cao, Jincang Zhang

Publisher page

Abstract

We have systematically synthesized polycrystalline samples of Nd_(0.9)A_(0.1)CrTiO_5 (A = Pr, Nd, Gd, Dy, Er, Tm, and Yb), and have investigated their crystal structure, polarization and magnetic susceptibility. The polarization values of doped samples are suppressed comparing to pure NdCrTiO_5 sample, which indicates that the polarization is highly dependence with the magnetic moments of doping ions. The T_N of Cr - Cr in Nd_(0.9)A_(0.1)CrTiO_5 are dominated by both the suppression effect caused by doped magnetic moment increment and the enhancement effect caused by c axis contracting. We conclude that the magnetic moments in the rare-earth Nd sites play an important role in the magnetoelectric effect in NdCrTiO_5 family. The substitution effect discussion here can help us well understand the intrinsic mechanism and provide a possible guidance in exploring new magnetoelectric coupling systems.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Advanced Condensed Matter Physics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (27)

Show source-provided references
1. Spintronics: a spin-based electronics vision for the future10.1126/science.1065389 ↗
2. Spintronics: fundamentals and applications10.1103/RevModPhys.76.323 ↗
3. Multiferroic and magnetoelectric materials10.1038/nature05023 ↗
4. Anisotropy of the magnetoelectric effect in Cr2O310.1103/PhysRevLett.6.607 ↗
5. Mechanism of the magnetoelectric effect in an antiferromagnet10.1103/PhysRevLett.6.609 ↗
6. Observation of the magnetically induced magnetoelectric effect and evidence for antiferromagnetic domains10.1103/PhysRevLett.7.310 ↗
7. Magnetoelectric coupling in MnTiO310.1103/PhysRevB.83.104416 ↗
8. Magnetoelectric control of frozen state in a toroidal glass10.1038/ncomms3063 ↗
9. Large magnetoelectric coupling in Co4Nb2O910.1038/srep03860 ↗
10. Magnetoelectric effect in NdCrTiO510.1103/PhysRevB.85.024415 ↗
11. Spiral magnets as magnetoelectrics10.1146/annurev.matsci.37.052506.084259 ↗
12. A thermodynamic theory of “weak” ferromagnetism of antiferromagnetics10.1016/0022-3697(58)90076-3 ↗
13. Anisotropic superexchange interaction and weak ferromagnetism10.1103/PhysRev.120.91 ↗
14. Theory of the role of covalence in the perovskite-type manganites [La, M(II)]MnO310.1103/PhysRev.100.564 ↗
15. Spiral spin structures and origin of the magnetoelectric coupling in YMn2O510.1103/PhysRevB.78.245115 ↗
16. Pyroelectric effect and possible ferroelectric transition of helimagnetic GdMn2O5, TbMn2O5 and YMn2O510.1088/0953-8984/8/15/016 ↗
17. Spin structure and magnetic frustration in multiferroic RMn2O5 (R=Tb, Ho, Dy)10.1103/PhysRevB.71.214402 ↗
18. Evidence for room temperature electric polarization in RMn2O5 multiferroics10.1103/PhysRevLett.114.117601 ↗
19. Etude par rayons X et neutrons de la serie isomorphe ATiTO5 (A = Cr, Mn, Fe, T = Terres Rares)10.1016/0022-3697(70)90326-4 ↗
20. Magnetoelectric compounds with two sets of magnetic sublattices: UCrO4 and NdCrTiO510.1016/0022-4596(74)90046-2 ↗
21. Evidence for multiferroic characteristics in NdCrTiO510.1016/j.jmmm.2014.02.008 ↗
22. Anomalous magnetic order in the magnetoelectric oxide NdCrTiO5 revealed by impurity effects10.1103/PhysRevB.91.144403 ↗
23. Influence of Sm3+ substitution on the mutiferroic effect in NdCrTiO510.1016/j.physb.2016.04.041 ↗
24. Implications of magnetic and magnetodielectric behavior of GdCrTiO510.1063/1.4937399 ↗
25. Magnetic properties, x-ray absorption spectroscopy and electronic structure of GdCrTiO510.1016/j.jallcom.2017.06.335 ↗
26. Intrinsic structural distortion and superexchange interaction in the orthorhombic rare-earth perovskites RCrO310.1103/PhysRevB.81.214115 ↗
27. Revival of the magnetoelectric effect10.1088/0022-3727/38/8/R01 ↗