Syntheses, structure and magnetization plateau of staircase kagome-lattice antiferromagnet Cu3Bi(TeO3)2O2Cl
Source abstract
Abstract
We have synthesized the single crystals of a spin-1/2 staircase kagome lattice compound Cu 3Bi(TeO 3) 2O 2Cl via a solid-state reaction. This compound crystallizes in the orthorhombic crystal system with space group Pnma. The magnetic susceptibility, specific heat and ESR measurements show that the compound undergoes an antiferromagnetic ordering at T 1 = 41.6 K and a short-range ordering at T 2 = 5.6 K. The Curie-Weiss temperature is about θ CW = − 20.8 K and frustration factor f = 0.5. The magnetization curve at 2 K presents a field-induced magnetic transition at H c1 = 3.1 T, followed by a magnetization plateau with its magnetization close to 1/3 of the saturation value. Thus, Cu 3Bi(TeO 3) 2O 2Cl is an weakly frustrated staircase kagome-lattice antiferromagnet exhibiting a 1/3-like magnetization plateau.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced Condensed Matter Physics · Physics of Superconductivity and Magnetism · High-pressure geophysics and materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (38)
Show source-provided references
1. Octa-Kagome lattice compounds showing quantum critical behaviors: spin gap ground state versus antiferromagnetic ordering10.1021/jacs.7b09246 ↗
2. Spin liquids in frustrated magnets10.1038/nature08917 ↗
3. Quantum spin liquids: a review10.1088/0034-4885/80/1/016502 ↗
4. One-third magnetization plateau with a preceding novel phase in volborthite10.1103/PhysRevLett.114.227202 ↗
5. Magnetization plateaus of the spin-1/2 kagome antiferromagnets volborthite and vesignieite10.1103/PhysRevB.83.180407 ↗
6. High-pressure synthesis and structure of SrCo6O11: pillared kagomé lattice system with a 1/3 magnetization plateau10.1021/cm050657p ↗
7. Magnetic behavior of volborthite Cu3V2O7(OH)2·2H2O determined by coupled trimers rather than frustrated Chains10.1103/PhysRevLett.117.037206 ↗
8. Skyrmion phase and competing magnetic orders on a breathing kagomé lattice10.1038/s41467-019-13675-4 ↗
9. CsV3Sb5: A Z2 topological kagome metal with a superconducting ground state10.1103/PhysRevLett.125.247002 ↗
10. Interplay of topological electrons and magnons in the Kagome magnet CoCu3(OH)6Cl210.1088/1367-2630/ac309b ↗
11. Magnetic and dielectric order in the kagomelike francisite Cu3Bi(SeO3)2O2Cl10.1103/PhysRevB.96.014413 ↗
12. spin dynamics of the spin-1/2 kagome lattice antiferromagnet ZnCu3(OH)6Cl210.1103/PhysRevLett.98.107204 ↗
13. Site specific x-ray anomalous dispersion of the geometrically frustrated kagomé magnet, herbertsmithite, ZnCu3(OH)6Cl210.1021/ja1070398 ↗
14. 17O NMR study of the intrinsic magnetic susceptibility and spin dynamics of the quantum Kagome antiferromagnet ZnCu3(OH)6Cl210.1103/PhysRevLett.100.087202 ↗
15. Quantum kagome antiferromagnet: ZnCu3(OH)6Cl2
16. Possible Dirac quantum spin liquid in the kagome quantum antiferromagnet YCu3(OH)6Br 2Brx(OH)1–x
17. Synthesis, structure, and magnetic properties of A2Cu5(TeO3)(SO4)3(OH)4 (A = Na, K): The first compounds with a 1D kagomé strip lattice10.1021/acs.inorgchem.5b01889 ↗
18. Co3(SeO3)(SO4)(OH)2: A selenite-sulfate compound with a distorted Kagomé lattice10.1021/acs.inorgchem.0c00316 ↗
19. (CsX)Cu5O2(PO4)2 (X = Cl, Br, I): A family of Cu2+ S = 1/2 compounds with capped-kagomé networks composed of OCu4 units10.1021/acs.inorgchem.8b03464 ↗
20. Spin liquid state in the S = 1/2 hyperkagomé antiferromagnet Na4Ir3O810.1103/PhysRevLett.99.137207 ↗
21. D. I. Badrtdinov, E. S. Kuznetsova, V. Yu. Verchenko, P. S. Berdonosov, V. A. Dolgikh, V. V. Mazurenko1, A. A. Tsirlin, Magnetism of coupled spin tetrahedra in ilinskite-type KCu5O2(SeO3)2Cl3,Sci. Rep. 8 (2018) 2379.10.1038/s41598-018-20350-z ↗
22. Layered Cu7(TeO3)2(SO4)2(OH)6 with Diluted Kagomé Net Containing Frustrated Corner-Sharing Triangles10.1021/acs.inorgchem.6b02209 ↗
23. Engelhauptite: A variant of S = 1/2 kagome antiferromagnet10.1103/PhysRevMaterials.3.064414 ↗
24. Syntheses, crystal structures and magnetic properties of francisite compounds Cu3Bi(SeO3)2O2X (X = Cl, Br and I)10.1039/b007920k ↗
25. A robust microporous 3D cobalt(II) coordination polymer with new magnetically frustrated 2D lattices: single-crystal transformation and guest modulation of cooperative magnetic properties
26. Magneto−Structural Correlation in a Metamagnetic Cobalt(II)-Based Pillared Trilayer Motif Constructed by Mixed Pyridyl-Type Carboxylate Ligands10.1021/ic901085p ↗
27. A Multifaceted Cage Cluster, [CoII6O12 ⊃ X-(X = Cl− or F−): Halide Template Effect and Frustrated Magnetism10.1021/cm1014459 ↗
28. High magnetic field induced phases and half-magnetization plateau in the S = 1 kagome compound Ni3V2O810.1103/PhysRevB.84.220407 ↗
29. Spin liquid state in the 3D frustrated antiferromagnet PbCuTe2O6: NMR and Muon spin relaxation studies10.1103/PhysRevLett.116.107203 ↗
30. Infrared phonon anomaly and magnetic excitations in single-crystal Cu3Bi(SeO3)2O2Cl10.1103/PhysRevB.86.174104 ↗
31. Crystal structure of Cu3Bi(TeO3)2O2Cl: a Kagomé lattice type compound10.1016/j.solidstatesciences.2004.10.045 ↗
32. Sheldrick · Acta Cryst. · 2015 · A71 · 3
33. Sheldrick · Acta Cryst. · 2015 · C71 · 3
34. OLEX2: A complete structure solution, refinement and analysis program10.1107/S0021889808042726 ↗
35. Specific heat data of high-Tc superconductors: Lattice and electronic contributions10.1016/0038-1098(89)90049-5 ↗
36. J. B. Goodenough, Magnetism and the Chemical Bond; John Wiley and Sons: New York, (1963).
37. Structural analysis of CuGeO3: Relation between nuclear structure and magnetic interaction10.1103/PhysRevB.54.1105 ↗
38. Magnetism of CuX2 frustrated chains (X = F, Cl, Br): Role of covalency10.1103/PhysRevB.87.155111 ↗