journal article·2022-04

Magnetocaloric properties in cryogenic temperature range of ferromagnetic CeSi1.3Ga0.7 alloy

K. Synoradzki, P. Skokowski, Ł. Frąckowiak, M. Koterlyn, T. Toliński

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Abstract

We present magnetocaloric properties of the CeSi 1.3Ga 0.7 alloy, a representative of the CeSi 2−xGa x series. Crystallographic studies revealed that the alloy crystallizes in the tetragonal I 4 1 / amd α -ThSi 2-type structure. Analysis of magnetic susceptibility denoted the magnetic phase transition at T C = 10.5 K. Based on the Arrott plot and the analysis of the critical exponents, it was determined that the phase transition is of the second-order type. From magnetization and specific heat results, we calculated following magnetocaloric parameters for a magnetic field change of 5 T: the magnetic entropy change - Δ S M = 5.7 J kg −1 K −1, the adiabatic temperature change Δ T ad = 3.4 K, the relative cooling power value RCP = 32.8 J kg −1, and the temperature averaged entropy change TEC ( 3 ) = 5.3 J kg −1 K −1 and TEC ( 10 ) = 3.4 J kg −1 K −1. Comparison of the master curves obtained from Δ S M based on the magnetization and specific heat analysis indicates that both methods of obtaining the magnetocaloric parameters give very similar results for this alloy.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Rare-earth and actinide compounds · Thermal Expansion and Ionic Conductivity

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