journal article·2022-03

Investigation on magnetic properties of mechanically alloyed τ-MnAlC with Fe addition

Van Tang Nguyen, Frédéric Mazaleyrat, Florent Calvayrac, Quang Minh Ngo, Nirina Randrianantoandro

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Abstract

Abstract The influence of Fe addition on thermal stability, crystallography, and magnetic properties of τ-Mn51Al47C2 was investigated. Alloys with composition Mn51-xFexAl47C2 (x= 0, 0.5, 1, 2, and 4) were synthesized by mechanical alloying method. High purity of τ-Mn(Fe)AlC up to 98% could be obtained after 10h of milling, then annealed at 1050 oC for 1h, and followed by an aging process at appropriate temperatures from 515 to 540 oC for 50 minutes. It was found that the thermal stability of both e and τ phases was enhanced by the addition of Fe up to 4 at.% into MnAlC alloy through a shifting of e-to-τ transformation temperature to high temperature region and a reduction in c/a ratio of Fe doped τ-MnAlC compared to iron free τ-MnAlC. While the magnetization and Curie temperature of Fe doped τ-MnAlC showed a reduction compared to iron free τ-Mn51Al47C2, coercivity seems not to be significantly affected. Ab initio calculation showed a lower magnetic moment of Fe (μFe = 1.77 μB) compared to Mn (μMn_average = 2.36 μB) in τ-Mn(Fe)AlC when Fe substituted Mn position at 1a site.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic Properties of Alloys · Metallic Glasses and Amorphous Alloys · Rare-earth and actinide compounds

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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