journal article·2004-05

Comparison of 55Mn NMR between two kinds of Mn12 molecular magnets: Mn12Ac and Mn12Ph

Takeji Kubo, Akinori Nagano, Takao Goto, Keiji Takeda, Kunio Awaga

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Abstract

Abstract The seven kinds of 55 Mn NMR observed for Mn 12 benzoate having the faster relaxation have been analyzed in comparison with those of Mn 12 acetate. It has been shown that the Mn 3+ ions at the Mn(7) sites are the probable cause of the fast relaxation with weakening the molecular anisotropy energy for the Mn 12 benzoate cluster.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes · Advanced NMR Techniques and Applications

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References (4)

Show source-provided references
1. Takeda · Phys. Rev. · 2002 · B65 · 09442410.1103/PhysRevB.65.094424 ↗
2. Kubo · Phys. Rev. · 2002 · B65 · 22442510.1103/PhysRevB.65.224425 ↗
3. Aubin · Polyhedron · 2001 · 20 · 113910.1016/S0277-5387(01)00585-X ↗
4. A. Abragam, B. Bleaney, Electron Paramagnetic Resonance of Transition Ions, Clarendon Press, Oxford, 1970, pp. 399, 434.