journal article·2020-12

Understanding the composition effects on the hot-deformed Nd-Fe-B magnets based on two different melt spun powders

Yukun Liu, Jiayi He, Hongya Yu, Xichun Zhong, Yunzhong Liu, Xiaoqiang Li, Zhongwu Liu

Publisher page

Abstract

Abstract The properties of RE-rich phase have important effects on the process and magnetic properties of NdFeB magnets. In this work, two MQ powders with different compositions were employed to fabricate hot pressed and hot-deformed magnets. The hot-deformed magnets produced from MQP-01 powders with Pr containing and Zr/Nb-free composition exhibit lower coercivity and less pinning effect compared to those from MQP-02 powders with Pr-free and Zr/Nb-containing composition, though the former has high rare earth (RE) content. These differences are attributed to the different mobilities of the RE-rich phase in the grain boundaries due to the composition difference. The RE-rich phase in MQP-01 powders has relatively good mobility, which leads to the aggregation of RE-rich phase and the open recoil loops for deformed magnets. On the contrary, relatively poor mobility of RE-rich phase in MQP-02 powders results in the thick and continuously distributed grain boundary phase in the hot-deformed magnets, which contributes to the strong pining effect and the high coercivity. The present results provide reference for optimizing the magnetic properties of hot deformed NdFeB type magnets.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Magnetic Properties of Alloys · Magnetic Properties and Applications · Magnetic properties of thin films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. New material for permanent magnets on a base of Nd and Fe (invited)10.1063/1.333572 ↗
2. Pr-Fe and Nd-Fe-based materials: a new class of high-performance permanent magnets (invited)10.1063/1.333571 ↗
3. Prospect for HRE-free high coercivity Nd-Fe-B permanent magnets10.1016/j.scriptamat.2018.03.012 ↗
4. Magnetic materials and devices for the 21st century: stronger, lighter, and more energy efficient10.1002/adma.201002180 ↗
5. Grain boundary diffusion of different rare earth elements in Nd-Fe-B sintered magnets by experiment and FEM simulation10.1016/j.actamat.2016.11.034 ↗
6. Coercivity and thermal stability improvement in sintered Nd–Fe–B permanent magnets by intergranular addition of Dy-Mn alloy10.1016/j.jmmm.2016.01.085 ↗
7. Boundary structure modification and magnetic properties enhancement of Nd-Fe-B sintered magnets by diffusing (PrDy)–Cu alloy10.1016/j.scriptamat.2016.02.019 ↗
8. Enhancing the coercivity of Nd-Fe-B sintered magnets by consecutive heat treatment–induced formation of Tb-diffused microstructures10.1016/j.jallcom.2018.11.412 ↗
9. Rare earths supply chains: current status, constraints and opportunities10.1016/j.resourpol.2014.03.004 ↗
10. Simultaneous enhancement of the coercivity and remanence at high temperatures in a sintered Nd-Fe-B magnet after grain boundary diffusion with Dy60Co40 alloy10.1016/j.matchar.2018.08.012 ↗
11. Coercivity and its thermal stability of Nd Fe B hot-deformed magnets enhanced by the eutectic grain boundary diffusion process10.1016/j.actamat.2018.09.018 ↗
12. Hot-pressed neodymium-iron-boron magnets10.1063/1.95884 ↗
13. Processing of Neodymium-Iron-Boron melt-spun ribbons to fully dense magnets10.1109/TMAG.1985.1064031 ↗
14. Improvement of magnetic performance of hot-deformed Nd-Fe-B magnets by secondary deformation process after Nd-Cu eutectic diffusion10.1016/j.actamat.2016.08.001 ↗
15. Coercivity improvement of hot-deformed Nd-Fe-B magnets by stress-induced Pr–Cu eutectic diffusion10.1016/j.actamat.2018.06.039 ↗
16. Grain size dependence of coercivity of hot-deformed Nd-Fe-B anisotropic magnets10.1016/j.actamat.2014.09.021 ↗
17. Dissolution of two types of grain boundary phases in a hot-deformed Nd-Fe-B magnet by high-temperature annealing10.1016/j.matchar.2019.02.041 ↗
18. Strategy for high-coercivity Nd–Fe–B magnets10.1016/j.scriptamat.2012.06.038 ↗
19. Correlation between the microstructure and magnetic configuration in coarse-grain inhibited hot-deformed Nd Fe B magnets10.1016/j.actamat.2019.01.025 ↗
20. Anisotropic behavior of grain boundary diffusion in hot-deformed Nd-Fe-B magnet10.1016/j.scriptamat.2016.10.017 ↗
21. Effect of Nd content on the microstructure and coercivity of hot-deformed Nd–Fe–B permanent magnets10.1016/j.actamat.2013.05.027 ↗
22. Coercivities of hot-deformed magnets processed from amorphous and nanocrystalline precursors10.1016/j.actamat.2016.10.026 ↗
23. Effects of hot pressing temperature on the alignment and phase composition of hot-deformed nanocrystalline Nd-Fe-B magnets10.1016/j.jmmm.2019.165353 ↗
24. Origins of inhomogeneous microstructure of hot-deformed nanocrystalline cylindrical Nd-Fe-B magnets and its effects on magnetization behaviors10.1016/j.jallcom.2019.04.076 ↗
25. Diffusion of Nd-rich phase in the spark plasma sintered and hot deformed nanocrystalline NdFeB magnets10.1063/1.3682471 ↗
26. The effects of Nd-rich phase distribution on deformation ability of hydrogenation-disproportionation-desorption-recombination powders and magnetic properties of the final die-upset Nd-Fe-B magnets10.1016/j.jmmm.2018.12.111 ↗
27. Effects of Nd-rich phase on the improved properties and recoil loops for hot deformed Nd-Fe-B magnets10.1016/j.actamat.2016.06.015 ↗
28. Strong texture in nanograin bulk Nd-Fe-B magnets via slow plastic deformation at low temperatures10.1039/C9NR00107G ↗
29. Low temperature diffusion process using rare earth-Cu eutectic alloys for hot-deformed Nd-Fe-B bulk magnets10.1063/1.4869062 ↗
30. Experimental investigation and thermodynamic description of the Fe–Nd–Pr system10.1016/j.tca.2019.178357 ↗
31. Suppression of non-oriented grains in Nd-Fe-B hot-deformed magnets by Nb doping10.1016/j.scriptamat.2017.12.032 ↗
32. Magnetic properties and microstructure studies of hot-deformed Nd-Fe-B magnets with Zr addition10.1109/TMAG.2010.2041554 ↗
33. Texture in Nd Fe B magnets analysed on the basis of the determination of Nd2Fe14B single crystals easy growth axis10.1016/0038-1098(87)90913-6 ↗
34. Quasi-periodic layer structure of die-upset NdFeB magnets10.1016/S1002-0721(12)60342-1 ↗
35. Grain boundary contribution to recoil loop openness of exchange-coupled nanocrystalline magnets10.1063/1.3127226 ↗