journal article·2020-06

Valence fluctuation and magnetic frustration in Ga substituted YMnO3

Pralay Paul, A.K. Rajarajan, A.K. Debnath, Rekha Rao, T.V. Chandrasekhar Rao

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Abstract

Abstract Ga substituted YMnO3 has been studied using XPS, dc magnetization and Raman measurements. XPS measurements show mixed valency of 2+ and 4+ for manganese ions, which is consistent with magnetization measurements. XPS and magnetization measurements on Ga substituted samples provide evidence for stabilization of manganese 3+ valency as Ga concentration is increased. The magnetic frustration factor is also found to be influenced by the substitution.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Multiferroics and related materials · Advanced Condensed Matter Physics

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