Magnetic and Mössbauer studies of cyanide-bridged bimetallic assembly [Mn(cyclam)][Fe(CN)6]·3H2O
Source abstract
Abstract
Abstract Cyanide-bridged bimetallic assembly [Mn(cyclam)][Fe(CN) 6 ]·3H 2 O (cyclam=1,4,8,11-tetraazacyclotetradecane) was synthesized from the reaction of trans -[MnCl 2 (cyclam)]Cl with K 3 Fe(CN) 6 . A linear chain structure consisting of alternating [Mn(cyclam)] 3+ and [Fe(CN) 6 ] 3− units was indicated by the IR and Mossbauer spectra. The variable-temperature magnetization and Mossbauer measurements revealed that this complex exhibited a long-range ordering below 6.8 K. The magnetic behavior of the complex was based on intrachain ferromagnetic and interchain antiferromagnetic interactions.
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Research context
OpenAlex topics: Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes · Metal complexes synthesis and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (33)
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