Efficient catalytic application of Cu-Fe bimetallic nanoparticles towards the preparation of bio-medically important polymer based Schiff bases
Source abstract
Abstract
Abstract A Cu and Fe based bimetallic nanoparticle (BMNP) was prepared by chemical reduction method through the formation of CuO and Fe2O3 nanocomposites. The Cu-Fe BMNP was characterized by FT-IR, UV–visible, fluorescence emission spectra, XRD, XPS, HR-TEM, SEM, EDX and VSM like instruments. The FT-IR spectrum showed a metal-oxide stretching peak around 600 cm-1 associating with the Fe-O and Cu-O composites. The formation of metal oxides was confirmed by XRD. The Janus nanoparticle formation between Fe and Cu was confirmed by HR-TEM. The surface catalytic activity of Cu-Fe BMNP was tested towards the Schiff base (SB) formation between alcohol and amine in an air atmosphere. The amount of SB formation was determined by using the 1H NMR spectrum. Among the systems, the PVA based SB yielded 20% via ketone formation.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Asymmetric Hydrogenation and Catalysis · Metal complexes synthesis and properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Synthesis of Pt-Co/C electrocatalyst for PEM fuel cell applications
2. Bimetallic Pt/Ir modified mesoporous catalysts applied in the hydrogenation of HMF10.1016/j.cattod.2019.06.037 ↗
3. Bimetallic Pd-Fe supported on γ-Al2O3 catalyst used in the ring opening of 2-methylfuran to selective formation of alcohols10.1016/j.apcata.2017.06.019 ↗
4. Pd-Ni bimetallic nanoparticles supported on active carbon as an efficient catalyst for hydrodeoxygenation of aldehydes10.1016/j.apcata.2018.10.038 ↗
5. Graphene supported Au-Pd bimetallic nanoparticles with excellent catalytic performance in selective oxidation of methanol to methylformate10.1039/c3cc43948h ↗
6. Ellagicacid directed growth of Au-Pt bimetallic nanoparticles, their catalytic applications10.1142/S0219581X12500378 ↗
7. Zn-Co bimetallic nanoparticles embedded in porous nitrogen doped carbon frame works for the reduction of nitro compounds10.1557/jmr.2017.148 ↗
8. Rational design of thermoresponsive functionalized MCM-14, their decoration with bimetallic Ag-Pd nanoparticles for catalytic application
9. Synthesis, structure, properties and applications of bimetallic nanoparticles of noble metals10.1002/adfm.201909260 ↗
10. Surface plasamon resonant Au-Pd bimetallic nanoparticle for photo catalytic oxidation10.1557/adv.2019.222 ↗
11. P.K. Khinya, M.A. Moradiya, P.S. Khare, Development of Fe-Ru bimetallic nanoparticles for promising application in the selective synthesis of SWNTs. Mater. Int. 2:0250–0255. DOI: 10.33263/materials22.10.33263/Materials22 ↗
12. Synthesis of triazine based dendrimer assisted Pd-Cu bimetallic nanoparticles and catalytic activity for C-C coupling reaction
13. Synthesis and hydrogenation application of Pt-Pd bimetallic nanocatalyst stabilized by macrocylcle modified dendrimer
14. Synthesis, structural characterization and catalytic application of citrate stabilized monometallic and bimetallic Pd@Cu nanoparticles in microbial anti activities10.2147/IJN.S145085 ↗
15. Synthesis of Fe/Ni bimetallic nanoparticles and application to the catalytic removal of nitrates from water
16. Controlled organization of building blocks to prepare 3D architecture of Pd-Ag aerogel as a high active electro-catalyst toward formicacid oxidation10.1016/j.compositesb.2019.05.021 ↗
17. Green synthesis of glucose-reduced graphene oxide supported Ag-Cu2O nanocomposites for the enhanced visible light photocatalytic activity10.1016/j.compositesb.2017.11.021 ↗
18. CES as an efficient natural catalyst for synthesis of Schiff bases under solvent free conditions: an innovative green approach
19. Hβ-catalyzed condensation reaction between aromatic ketones and anilines: to access ketimines (imines)10.1007/s10562-017-2196-0 ↗
20. Vanadium catalyzed direct synthesis of imines from amines or alcohols and amines by an aerobic oxidative reaction under mild conditions10.1016/S1872-2067(14)60196-0 ↗
21. Iron catalyzed direct synthesis of imines from amines or alcohols and amines via aerobic oxidative reactions under air10.1021/ol4010118 ↗
22. Rapid and efficient synthesis of Schiff bases catalyzed by copper nitrate10.1080/15533170902858047 ↗
23. One-pot synthesis of imines and secondary amines by Pd catalyzed coupling of benzyl alcohols and primary amines10.1021/jo8026609 ↗
24. Structural modification of aminoclay for catalytic applications10.1080/00986445.2019.1630394 ↗
25. Synthesis, characterization and catalytic application of eco-friendly Ca-bridged aminoclay10.1002/kin.21317 ↗
26. One-pot synthesis of imines from benzyl alcohol and amines on Au/ZrO2 catalyst10.1007/s11144-013-0576-z ↗
27. Cobalt catalyzed acceptorless alcohol dehydrogenation: synthesis of imines from alcohols and amines10.1021/ol303479f ↗
28. Fe and Cu doped graphitic carbonnitride as an eco-friendly photo-assisted catalyst for aniline degradation10.1007/s11356-020-08148-x ↗
29. Luminascence of Cu nanoparticles10.1016/j.jlumin.2011.05.019 ↗
30. Synthesis, characterization and multifunctional application of Cu-Fe and Ni-Fe nanomaterials10.1021/acsomega.0c01259 ↗
31. Selective catalytic reduction of NO with NH3 over H2SM-5 supported Fe-Cu nanocomposite catalysts: the Fe-Cu bimetallic effect Appl Catal
32. Iron-Copper bimetallic nanoparticles supported on silicon spheres: the effect of Fe/Cu ratio on heterogeneous degradation of a dye10.1039/C6RA08501F ↗
33. Structural, thermal, morphological, adsorption and catalytic properties of Poly(BPDAH-co-ODA/PPDA)-Ag/V2O5 nanocomposites10.9767/bcrec.15.1.5595.155-174 ↗
34. Evaluation of kinetic parameters for the crystallization and degradation process of synthesized strontium mercaptosuccinate functionalized poly(ε-caprolactone) by non-isothermal approach10.1007/s13726-019-00723-5 ↗
35. Synthesis, characterization and sustainable drug release activity of drug bridged diblock copolymer10.1007/s42452-019-1623-9 ↗
36. 2-aminomethylpyridine Nickel(ii) complexes- synthesis, molecular structure and catalysis of ethylene polymerization10.1142/S025676790800328X ↗
37. Synthesis, characterization and application of a novel Schiff base