journal article·2014-10

Electrodepositing salicylate modified PHEMA on stainless steel surface for hemocompatibility

B. Chen, J. Chen, L. Yang, G. Zhao, G. Ding

Surface Engineering· Volume 30· Issue 10
Publisher page

Abstract

Using electrodeposition of poly(hydroxyethylmethacrylate)–glycidyl methacrylate–salicylic acid (PHEMA-GMA-SA) in this study, the surface of stainless steel was modified by PHEMA to improve its surface properties of corrosion resistance and hemocompatibility for biomedical applications. Electropolymerisable SA was introduced on PHEMA-GMA by ring opening reaction of the epoxy group of GMA. Poly(hydroxyethylmethacrylate)–glycidyl methacrylate was synthesised by precipitation copolymerisation of HEMA and GMA in ethyl acetate. Ultraviolet spectrum was applied for calculating the degree of substitution of SA in the copolymer. Structure of the electrodeposited layer was verified by Fourier transform infrared. Polarisation curves and electrochemical impedance spectroscopy technologies were used to estimate the corrosion resistance of PHEMA modified stainless steel. The hemocompatibility of PHEMA modified stainless steel was determined by bovine serum albumin adsorption and platelet adhesion.
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Research context

OpenAlex topics: Electrospun Nanofibers in Biomedical Applications · Polymer Surface Interaction Studies · Advanced Sensor and Energy Harvesting Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Environmental and Chemical Engineering Shanghai University, 333 Nanchen Road, Shanghai 200444, China

Department of Oral and Maxillofacial Surgery Tongji University, Tongji Hospital, 389 Xincun Road, Shanghai 200065, China

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