journal article·2022-02Open access

Influence of ZrO2/SiO2 nanomaterial incorporation on the properties of PEO layers on Mg-Mn-Ce alloy

D.V. Mashtalyar, I.M. Imshinetskiy, K.V. Nadaraia, A.S. Gnedenkov, S.L. Sinebryukhov, A.Yu. Ustinov, A.V. Samokhin, S.V. Gnedenkov

Journal of Magnesium and Alloys· Volume 10· Issue 2

Abstract

The properties of coatings formed on the MA8 magnesium alloy by the plasma electrolytic oxidation in electrolytes containing mechanical mixture of zirconia and silica nanoparticles in concentrations of 2, 4 and 6 g/l have been investigated. It has been established by SEM, EDS, and XPS that ZrO2/SiO2 nanoparticles successfully were incorporated into the coatings. Micro-Raman spectroscopy showed the presence of ZrO2 in tetragonal and monoclinic forms in the PEO-coating composition as well as Mg2SiO4 in tetrahedral configuration uniformly distributed in the outer part of coatings. Obtained coatings significantly reduce corrosion current density in comparison with bare Mg alloy and base PEO-layer (from 2.4 × 10–7 A/cm2 for base PEO layer to 0.7 × 10–7 A/cm2 for coatings with nanoparticles). It has been found that the presence of solid nanoparticles in the composition of coating has a positive effect on their hardness (this parameter was increased from 2.1 ± 0.3 GPa to 3.1 ± 0.4 GPa) and wearproof (the wear was reduced from (4.3 ± 0.4)×10–5 mm3/(N × m) to (3.5 ± 0.2)×10–5 mm3/(N × m)).
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Metal and Thin Film Mechanics · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (57)

Show source-provided references
1. Characterization of anodic films on AZ31 magnesium alloys in alkaline solutions containing fluoride and phosphate anions10.1149/1.2257987 ↗
2. Magnesium and its alloys as orthopedic biomaterials: a review10.1016/j.biomaterials.2005.10.003 ↗
3. Increasing the wear and corrosion resistance of magnesium alloy (AZ91D) with electrodeposition from eco-friendly copper- and trivalent chromium-plating baths10.1016/j.surfcoat.2010.06.012 ↗
4. Corrosion resistance and superhydrophobicity of one-step polypropylene coating on anodized AZ31 Mg alloy
5. Tribology characteristics of magnesium alloy AZ31B and its composites10.1016/j.triboint.2014.02.024 ↗
6. Effect of particles addition to solution of plasma electrolytic oxidation (PEO) on the properties of PEO coatings formed on magnesium and its alloys: a review10.1016/j.jma.2020.05.001 ↗
7. Evolution of PEO coatings on AM50 magnesium alloy using phosphate-based electrolyte with and without glycerol and its electrochemical characterization10.1016/j.jma.2020.05.002 ↗
8. Plasma electrolytic oxidation of AZ31 and AZ91 magnesium alloys: comparison of coatings formation mechanism10.1016/j.jma.2020.06.002 ↗
9. D.V. Mashtalyar, K.V. Nadaraia, A.S. Gnedenkov, I.M. Imshinetskiy, M.A. Piatkova, A.I. Pleshkova, E.A. Belov, V.S. Filonina, S.N. Suchkov, S.L. Sinebryukhov, S.V. Gnedenkov, Bioactive coatings formed on titanium by plasma electrolytic oxidation: composition and properties, Materials. 13 (2020) 4121. https://doi.org/10.3390/ma13184121.10.3390/ma13184121 ↗
10. Cerium-based sealing of PEO coated AM50 magnesium alloy10.1016/j.surfcoat.2015.01.003 ↗
11. Structural, tribological and electrochemical behavior of SiC nanocomposite oxide coatings fabricated by plasma electrolytic oxidation (PEO) on AZ31 magnesium alloy10.1016/j.jallcom.2016.05.096 ↗
12. Effects of Al2O3 nano-additive on performance of micro-arc oxidation coatings formed on AZ91D Mg alloy10.1016/j.jmst.2014.03.006 ↗
13. Potential and morphological transitions during bipolar plasma electrolytic oxidation of tantalum in silicate electrolyte10.1016/j.ceramint.2020.02.120 ↗
14. Release rate kinetics of corrosion inhibitor loaded halloysite nanotube-based anticorrosion coatings on magnesium alloy AZ91D
15. D.V. Mashtalyar, K.V. Nadaraia, I.M. Imshinetskiy, E.A. Belov, V.S. Filonina, S.N. Suchkov, S.L. Sinebryukhov, S.V. Gnedenkov, Composite coatings formed on Ti by PEO and fluoropolymer treatment, Appl Surf Sci. 536 (2021) 147976. https://doi.org/10.1016/j.apsusc.2020.147976.10.1016/j.apsusc.2020.147976 ↗
16. Role of particle type and concentration on characteristics of PEO coatings on AM50 magnesium alloy10.1016/j.surfcoat.2017.11.058 ↗
17. Electrochemical response of ZrO2-incorporated oxide layer on AZ91 Mg alloy processed by plasma electrolytic oxidation10.1016/j.surfcoat.2011.01.033 ↗
18. An investigation on ZrO2 nano-particle incorporation, surface properties and electrochemical corrosion behaviour of PEO coating formed on Cp-Ti10.1016/j.surfcoat.2017.01.105 ↗
19. Transformation of plasma electrolytic oxidation coatings from crater to cluster–based structure with increase in DC voltage and the role of ZrO2 nanoparticles10.1016/j.surfcoat.2016.12.112 ↗
20. Antibacterial activities and corrosion behavior of novel PEO/nanostructured ZrO2 coating on Mg alloy10.1016/S1003-6326(18)64799-5 ↗
21. Anticorrosive ZrO 2 and ZrO 2 -SiO 2 layers on titanium substrates for biomedical applications10.1016/j.surfcoat.2017.10.011 ↗
22. Electrophoretic deposition of nano-zirconia coating on AZ91D magnesium alloy for bio-corrosion control purposes10.1016/j.surfcoat.2016.12.103 ↗
23. Review of zirconia-based bioceramic: surface modification and cellular response10.1016/j.ceramint.2016.05.077 ↗
24. Structure, corrosion behavior, and antibacterial properties of nano-silica/graphene oxide coating on biodegradable magnesium alloy for biomedical applications10.1016/j.vacuum.2016.05.021 ↗
25. Bioengineering of the silica-polymerizing enzyme silicatein-α for a targeted application to hydroxyapatite10.1016/j.actbio.2010.03.010 ↗
26. Multifunctional silica nanoparticles with potentials of imaging and gene delivery10.1016/j.nano.2010.12.008 ↗
27. Bioactive and biodegradable silica biomaterial for bone regeneration10.1016/j.bone.2014.07.025 ↗
28. Biocompatible silica-based magnesium composites10.1016/j.jallcom.2018.09.060 ↗
29. Dual incorporation of SiO2 and ZrO2 nanoparticles into the oxide layer on 6061 Al alloy via plasma electrolytic oxidation: coating structure and corrosion properties10.1016/j.jallcom.2016.11.098 ↗
30. Synergistic influence of inorganic oxides (ZrO2 and SiO2) with N2H4 to protect composite coatings obtained via plasma electrolyte oxidation on Mg alloy10.1039/C6CP07135J ↗
31. Fabrication of Coatings on the Surface of Magnesium Alloy by Plasma Electrolytic Oxidation Using ZrO2 and SiO2 Nanoparticles
32. I.M. Imshinetskiy, S.V. Gnedenkov, S.L. Sinebryukhov, D.V. Mashtalyar, A.V. Samokhin, Y.V. Tsvetkov, Incorporation of zirconia and silica nanoparticles into PEO-coatings on magnesium alloys, Solid State Phenom 213 (2014) 125–130. https://doi.org/10.4028/www.scientific.net/SSP.213.125.10.4028/www.scientific.net/SSP.213.125 ↗
33. Plasma-assisted processes for manufacturing nanosized powder materials10.1134/S0018143906020056 ↗
34. D.V. Mashtalyar, S.V. Gnedenkov, S.L. Sinebryukhov, I.M. Imshinetskiy, A.V. Puz’, Plasma electrolytic oxidation of the magnesium alloy MA8 in electrolytes containing TiN nanoparticles, J Mater Sci Technol. 33 (2017) 461–468. https://doi.org/10.1016/j.jmst.2017.01.021.10.1016/j.jmst.2017.01.021 ↗
35. D.V. Mashtalyar, S.L. Sinebryukhov, I.M. Imshinetskiy, A.S. Gnedenkov, K.V. Nadaraia, A.Y. Ustinov, S.V. Gnedenkov, Hard wearproof PEO-coatings formed on Mg alloy using TiN nanoparticles, Appl Surf Sci. 503 (2020) 144062. https://doi.org/10.1016/j.apsusc.2019.144062.10.1016/j.apsusc.2019.144062 ↗
36. A method for the solution of certain non-linear problems in least squares10.1090/qam/10666 ↗
37. An algorithm for least-squares estimation of nonlinear parameters10.1137/0111030 ↗
38. Localized currents and pH distribution studied during corrosion of MA8 Mg alloy in the cell culture medium10.1016/j.corsci.2020.108689 ↗
39. Composite coatings formed on the PEO-layers with the use of solutions of tetrafluoroethylene telomers10.1016/j.surfcoat.2018.04.036 ↗
40. Surface layers produced on titanium by the microarc oxidation: an X-ray diffractometry study
41. Tuning the structural and mechanical properties in ZrO2-SiO2 binary system through Y3+ inclusions10.1016/j.msec.2017.11.046 ↗
42. Quantum cutting properties of Tb3+/Yb3+ co-doped ZrO2-SiO2 nano-crystalized glasses synthesized via a sol-gel route10.1016/j.jallcom.2018.11.380 ↗
43. Raman-active modes and the tetragonal-monoclinic phase transition in ZrO2 doped with 12mol% CeO210.1016/0022-3697(95)00027-5 ↗
44. Characterization of sol–gel derived TiO2/ZrO2 films and powders by Raman spectroscopy10.1016/j.tsf.2011.10.189 ↗
45. Temperature dependence of the Raman spectra of ZrO210.1111/j.1151-2916.1977.tb15561.x ↗
46. Infrared and Raman spectra of zirconia polymorphs10.1111/j.1151-2916.1971.tb12283.x ↗
47. Structural and photoluminescence investigations of Cr3+ mixed Li2O—Bi2O3—ZrO2—SiO2 glass ceramics for optoelectronic device application10.1016/j.ijleo.2018.12.110 ↗
48. Absorption, emission and absorption saturation of Cr4+ ions in calcium aluminate glass10.1016/j.jnoncrysol.2005.08.030 ↗
49. Spectroscopic features of Ni2+ ion in PbO-Bi2O3-SiO2 glass system10.1016/j.saa.2015.01.058 ↗
50. Raman spectroscopy and the origin of electrooptical Kerr phenomenon in niobium alkali-silicate glasses10.1016/S0925-3467(02)00093-9 ↗
51. IR and Raman spectroscopic studies of sol-gel derived alkaline-earth silicate glasses10.1007/s12034-011-0064-x ↗
52. Properties of sol-gel-derived Al2O3□SiO2 glasses using Eu3+ ion fluorescence spectra10.1016/0022-3093(95)00621-4 ↗
53. Perceiving impressive optical properties of ternary SiO2-TiO2-ZrO2:eu3+ sol-gel glasses with high reluctance for concentration quenching: an experimental approach10.1016/j.jnoncrysol.2017.12.027 ↗
54. Luminescence and phonon side band analysis of Eu3+-doped lead fluorosilicate glasses10.1016/j.optmat.2016.09.006 ↗
55. Structural and electrochemical properties of the catalytic CeO2 nanoparticles-based PEO ceramic coatings on AZ91 Mg alloy10.1016/j.jallcom.2017.07.301 ↗
56. Vibrational spectroscopic and computational studies of sol–gel derived CaO–MgO–SiO2 binary and ternary bioactive glasses10.1016/j.vibspec.2007.11.008 ↗
57. D.V. Mashtalyar, S.V. Gnedenkov, S.L. Sinebryukhov, I.M. Imshinetskiy, A.V. Puz’, Plasma electrolytic oxidation of the magnesium alloy MA8 in electrolytes containing TiN nanoparticles, J Mater Sci Technol. 33 (2017) 461–468. https://doi.org/10.1016/j.jmst.2017.01.021.10.1016/j.jmst.2017.01.021 ↗