journal article·2008-11-01

Laser-enhanced electroless plating of silver seed layers for selective electroless copper deposition

Nicholas S. Dellas, Kenneth Meinert, Suzanne E. Mohney

Journal of Laser Applications· Volume 20· Issue 4
Publisher page

Abstract

Copper (Cu) has been patterned using a laser direct-write metallization technique for fabrication of printed wiring boards. The approach consists of writing a silver (Ag) seed layer with a subsequent step of electroless Cu plating to increase thickness and electrical conductivity. Ag seed layers were patterned with a frequency tripled Nd:YVO4 (λ=355 nm) laser with a spot size of approximately 50 μm. Final Cu linewidths after electroless plating were found to be 150 μm with a thickness of 2 μm and electrical resistivity of 5 μΩ cm. An optimal laser power of 0.81 W was found by a factorial-type design experiment. A modern prototype circuit was also patterned with this technique, demonstrating its compatibility with current resolution requirements.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Electrodeposition and Electroless Coatings · Copper Interconnects and Reliability · Semiconductor materials and devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802

Applied Research Laboratory, The Pennsylvania State University, University Park, Pennsylvania 16802

References (33)

Show source-provided references
1. Laser chemical vapor deposition: A technique for selective area deposition
2. Direct laser writing of aluminum and copper on glass surfaces from metal powder10.1016/S0169-4332(01)00065-4 ↗
3. Laser direct fabrication of silver conductors on glass boards10.1016/j.tsf.2004.12.053 ↗
4. Laser-induced surface activation of LTCC materials for chemical metallization10.1109/TADVP.2005.847899 ↗
5. Laser activation of diamond surface for electroless metal plating10.1063/1.111747 ↗
6. Excimer laser-induced surface activation of alumina for electroless metal deposition10.1016/S0169-4332(96)00666-6 ↗
7. Laser-assisted activation of dielectrics for electroless metal plating10.1007/s003390050775 ↗
8. Repair of circuits by laser seeding and constriction induced plating10.1109/33.142902 ↗
9. Laser writing of copper lines from metalorganic films10.1063/1.98928 ↗
10. Diode laser-assisted pyrolysis of organometallic films for the fabrication of metallic conductors on polyimide10.1109/96.475277 ↗
11. Maskless laser-induced deposition of Cu film patterns from copper formate10.1117/12.352717 ↗
12. Laser-induced prenucleation and/or metallization of alumina substrates by a new palladium resin10.1016/0169-4332(92)90368-8 ↗
13. Micromachining compatible metal patterning technique using localized decomposition of an organometallic compound by laser irradiation10.1088/0960-1317/8/3/001 ↗
14. A chemical and mechanistic view of reaction profiles in laser direct-write metallization in metallo-organic films. Gold.10.1063/1.337442 ↗
15. Laser decomposition of platinum metallo-organic films for electroless copper plating10.1149/1.2100275 ↗
16. High-conductance customized copper interconnections produced by laser seeding and selective electrodeposition10.1063/1.102875 ↗
17. Matrix assisted laser transfer of electronic materials for direct write applications10.1117/12.405735 ↗
18. Laser-induced forward transfer direct-write of miniature sensor and microbattery systems10.1117/12.486567 ↗
19. Excimer and femtosecond pulsed laser induced forward transfer process of metal thin film10.1117/12.479249 ↗
20. 2003 · 84
21. Laser direct writing of Ag films from solution on Si substrate
22. Novel technique for synthesis of silver nanoparticles by laser-liquid interaction10.1023/A:1013270305004 ↗
23. Synthesis of silver nanoparticles by a laser-liquid-solid interaction technique10.1023/A:1022691302150 ↗
24. Electroless copper plating on a glass substrate coated with ZnO film under UV illumination
25. Multiple-layer laser direct writing metal deposition in electrolyte solution10.1016/j.apsusc.2005.01.142 ↗
26. Laser enhanced electroless plating of micron-scale copper wires10.1149/1.1393371 ↗
27. Excimer laser-induced formation of metallic microstructures by electroless copper10.1088/0960-1317/12/2/309 ↗
28. Reaction dynamics of CW Ar+ laser induced copper direct writing from liquid electrolyte on polyimide substrates10.1016/S0169-4332(99)00602-9 ↗
29. Laser direct writing of copper on polyimide surface from solution
30. Laser-enhanced palladium electroless plating10.1080/00202967.1997.11871134 ↗
31. Laser assisted Pd seeding for electroless plating on SiO210.1063/1.111846 ↗
32. Palladium thin film deposition on polyimide by CW Ar+ laser radiation for electroless copper plating10.1016/S0040-6090(00)01829-0 ↗
33. 1998 · 12