journal article·2026Open access

Recent Advances in Constructing Oriented Ion Transport Channels with Two-dimensional Layered Materials for Electrochemical Energy Storage

Shanli QIN, Jiawen GUO, Yanmeng CHEN, An’an JU, Yi WEI, Kelin HUANG, Xianghua HOU, Sishi Lü, Zhipeng WEN, Lian WU

Journal of Inorganic Materials· Volume 41· Issue 7

Abstract

No abstract is available for this record. The assistant can identify its topic from the title, but cannot infer the study’s results.

Source: Not provided · Quality: missing

Research context

OpenAlex topics: Nanopore and Nanochannel Transport Studies · Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (85)

Show source-provided references
1. QUILTY C D, WU D, LI W, et al . Electron and ion transport in lithium and lithium-ion battery negative and positive composite electrodes. Chemical Reviews , 2023, 123(4): 1327.10.1021/acs.chemrev.2c00214 ↗
2. WU L, HONG L, GAO S, et al . Cu 2- x Se@montmorillonite heterostructured electrocatalyst for high-performance lithium- sulfur batteries. Journal of Energy Storage , 2024, 101: 113800.10.1016/j.est.2024.113800 ↗
3. WU L, ZHAO Y, YU Y, et al . FeS 2 intercalated montmorillonite as a multifunctional separator coating for high-performance lithium-sulfur batteries. Inorganic Chemistry Frontiers , 2023, 10(2): 651.10.1039/D2QI02324E ↗
4. EDIGAR M, MOMBESHORA E T, MUIVA C M, et al . Lithium-ion batteries: recent progress in improving the cycling and rate performances of transition metal oxide anodes by incorporating graphene-based materials. Journal of Energy Storage , 2023, 73B: 109013.10.1016/j.est.2023.109013 ↗
5. CHENG Y, XIE Y, YAN S, et al . Maximizing the ion accessibility and high mechanical strength in nanoscale ion channel MXene electrodes for high-capacity zinc-ion energy storage. Science Bulletin , 2022, 67(21): 2216.10.1016/j.scib.2022.10.003 ↗
6. WROGEMANN J M, LÜTHER M J, BÄRMANN P, et al . Overcoming diffusion limitation of Faradaic processes: property- performance relationships of 2D conductive metal-organic framework Cu 3 (HHTP) 2 for reversible lithium-ion storage. Angewandte Chemie International Edition , 2023, 62(26): e202303111.10.1002/anie.202303111 ↗
7. PETTINARI C, TOMBESI A. MOFs for electrochemical energy conversion and storage. Inorganics , 2023, 11(2): 65.10.3390/inorganics11020065 ↗
8. OTGONBAYAR Z, YANG S, KIM I J, et al . Recent advances in 2D MXene and solid state electrolyte for energy storage applications: comprehensive review. Chemical Engineering Journal , 2023, 472: 144801.10.1016/j.cej.2023.144801 ↗
9. PHILIP A, KUMAR A R. Recent advancements and developments employing 2D-materials in enhancing the performance of electrochemical supercapacitors: a review. Renewable and Sustainable Energy Reviews , 2023, 182: 113423.10.1016/j.rser.2023.113423 ↗
10. HE Y, SHEN X, ZHANG Y. Layered 2D materials in batteries. ACS Applied Nano Materials , 2024, 7(24): 27907.10.1021/acsanm.3c06242 ↗
11. CHEN Z, ZHI C. MXene based zinc ion batteries: recent development and prospects. Journal of Inorganic Materials , 2024, 39(2): 204.10.15541/jim20230503 ↗
12. RUIZ-HITZKY E, ARANDA P. Polymer-salt intercalation complexes in layer silicates. Advanced Materials , 1990, 2(11): 545.10.1002/adma.19900021108 ↗
13. WEN Z P, WEI Y, HOU X H, et al . Research progress of bentonite-based functional materials in electrochemical energy storage. Journal of Inorganic Materials , 2024, 39(12): 1301.10.15541/jim20240240 ↗
14. YANG Y, LI Z, YANG Z, et al . Ultrafast lithium-ion transport engineered by nanoconfinement effect. Advanced Materials , 2025, 37(8): e2416266.10.1002/adma.202416266 ↗
15. LIU Y T, ZHU P, SUN N, et al . Self-assembly of transition metal oxide nanostructures on MXene nanosheets for fast and stable lithium storage. Advanced Materials , 2018, 30(23): e1707334.10.1002/adma.201707334 ↗
16. LIAN H, MOMEN R, XIAO Y, et al . High ionic conductivity motivated by multiple ion-transport channels in 2D MOF-based lithium solid state battery. Advanced Functional Materials , 2023, 33(49): 2306060.10.1002/adfm.202306060 ↗
17. HE M, GUAN M, ZHAN R, et al . Two-dimensional materials applied in membranes of redox flow battery. Chemistry-An Asian Journal , 2023, 18(3): e202201152.10.1002/asia.202201152 ↗
18. VIJAYAKUMAR V, GHOSH M, ASOKAN K, et al . 2D layered nanomaterials as fillers in polymer composite electrolytes for lithium batteries. Advanced Energy Materials , 2023, 13(15): 2203326.10.1002/aenm.202203326 ↗
19. YANG Y, DONG R, CHENG H, et al . 2D layered materials for fast-charging lithium-ion battery anodes. Small , 2023, 19(34): 2301574.10.1002/smll.202301574 ↗
20. JIANG D, WANG X, YIN S, et al . Solid-state electrolytes with vertically aligned Li + transport channels for lithium batteries: a comprehensive review. Energy Storage Materials , 2025, 74: 103986.10.1016/j.ensm.2024.103986 ↗
21. XIA Y, MATHIS T S, ZHAO M Q, et al . Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes. Nature , 2018, 557(7705): 409.10.1038/s41586-018-0109-z ↗
22. LI X, WANG Y, XI K, et al . Quasi-solid-state ion-conducting arrays composite electrolytes with fast ion transport vertical-aligned interfaces for all-weather practical lithium-metal batteries. Nano-Micro Letters , 2022, 14(1): 210.10.1007/s40820-022-00952-z ↗
23. JU Z, KING S T, XU X, et al . Vertically assembled nanosheet networks for high-density thick battery electrodes. Proceedings of the National Academy of Sciences , 2022, 119(40): e2212777119.10.1073/pnas.2212777119 ↗
24. NAGUIB M, COME J, DYATKIN B, et al . MXene: a promising transition metal carbide anode for lithium-ion batteries. Electrochemistry Communications , 2012, 16(1): 61.10.1016/j.elecom.2012.01.002 ↗
25. XU M, WEI M. Layered double hydroxide-based catalysts: recent advances in preparation, structure, and applications. Advanced Functional Materials , 2018, 28(47): 1802943.10.1002/adfm.201802943 ↗
26. 胡朔. NiAl LDHs电极材料的制备及超级电容器性能研究. 郑州: 郑州轻工业大学硕士学位论文, 2025.
27. XIONG D, DENG X, CAO Z, et al . 2D metal-organic frameworks for electrochemical energy storage. Energy & Environmental Materials , 2023, 6(6): e12521.10.1002/eem2.12521 ↗
28. TAKAAKI T, FURUKAWA S, TAKASHIMA Y, et al . Nanoporous nanorods fabricated by coordination modulation and oriented attachment growth. Angewandte Chemie International Edition , 2009, 121(26): 4833.10.1002/ange.200901177 ↗
29. SHEBERLA D, BACHMAN J C, ELIAS J S, et al . Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nature Materials , 2017, 16(2): 220.10.1038/nmat4766 ↗
30. NIU L, WU T, CHEN M, et al . Conductive metal-organic frameworks for supercapacitors. Advanced Materials , 2022, 34(52): 2200999.10.1002/adma.202200999 ↗
31. KHALIL I E, FONSECA J, REITHOFER M R, et al . Tackling orientation of metal-organic frameworks (MOFs): the quest to enhance MOF performance. Coordination Chemistry Reviews , 2023, 481: 215043.10.1016/j.ccr.2023.215043 ↗
32. 张秩远, 陈浩彤, 李妍, 等. 插层结构过渡金属氢氧化物的制备及其能源应用研究进展. 化学通报, 2024, 87(8): 913.
33. RADICH J G, MCGINN P J, KAMAT P V. Graphene-based composites for electrochemical energy storage. Electrochemical Society Interface , 2011, 20(1): 63.10.1149/2.F08111if ↗
34. WU Z, WANG E, ZHANG G, et al . Recent progress of vertical graphene: preparation, structure engineering, and emerging energy applications. Small , 2024, 20(15): 2307923.10.1002/smll.202307923 ↗
35. 何明亮. 垂直石墨烯自支撑电极的可控制备与超级电容器应用研究. 南昌: 江西师范大学博士学位论文, 2024.
36. LIMA K A L, LARANJEIRA J A S, MARTINS N F, et al . Petal-graphyne: a novel 2D carbon allotrope for high-performance Li and Na ion storage. Journal of Energy Storage , 2025, 130: 117235.10.1016/j.est.2025.117235 ↗
37. LIAN W, XIN H, YIFANG Z, et al . Montmorillonite-based materials for electrochemical energy storage. Green Chemistry , 2024(2): 26.10.1039/D3GC03447J ↗
38. LV R, KOU W, GUO S, et al . Preparing two-dimensional ordered Li 0.33 La 0.557 TiO 3 crystal in interlayer channel of thin laminar inorganic solid-state electrolyte towards ultrafast Li + transfer. Angewandte Chemie International Edition , 2022, 134(7): e202114220.10.1002/ange.202114220 ↗
39. ZHANG Y, HUANG J, LIU H, et al . Lamellar ionic liquid composite electrolyte for wide-temperature solid-state lithium-metal battery. Advanced Energy Materials , 2023, 13(23): 2300156.10.1002/aenm.202300156 ↗
40. GASA J V, WEISS R, SHAW M T. Structured polymer electrolyte blends based on sulfonated polyetherketoneketone (SPEKK) and a poly(ether imide) (PEI). Journal of Membrane Science , 2008, 320(1/2): 215.10.1016/j.memsci.2008.03.075 ↗
41. 吴代琼, 苏琼, 陈磊, 等. 石墨烯在复合材料中的定向排布及其应用进展. 机械工程学报, 2023, 59(18): 144.
42. ZHU Y, JU Z, ZHANG X, et al . Evaporation-induced vertical alignment enabling directional ion transport in a 2D-nanosheet-based battery electrode. Advanced Materials , 2020, 32(10): 1907941.10.1002/adma.201907941 ↗
43. WANG Y, LI J, LI X, et al . Metal-organic-framework derived Co@CN modified horizontally aligned graphene oxide array as free-standing anode for lithium-ion batteries. Journal of Materials Chemistry A , 2022, 10(2): 699.10.1039/D1TA07638H ↗
44. HUANG X, HUANG J, YANG D, et al . A multi-scale structural engineering strategy for high-performance MXene hydrogel supercapacitor electrode. Advanced Science , 2021, 8(18): 2101664.10.1002/advs.202101664 ↗
45. LI X, LI M, YANG Q, et al . Vertically aligned Sn 4+ preintercalated Ti 2 CTX MXene sphere with enhanced Zn ion transportation and superior cycle lifespan. Advanced Energy Materials , 2020, 10(35): 2001394.10.1002/aenm.202001394 ↗
46. LIN C, ZHANG Y, LIEU W Y, et al . Boosting zinc-ion storage capability in longitudinally aligned MXene arrays with microchannel architecture. Advanced Functional Materials , 2025, 35(3): 2413613.10.1002/adfm.202413613 ↗
47. OWUSU K A, WANG Z, SAAD A, et al . Room temperature synthesis of vertically aligned amorphous ultrathin NiCo-LDH nanosheets bifunctional flexible supercapacitor electrodes. Energy & Environmental Materials , 2024, 7(2): e12545.10.1002/eem2.12545 ↗
48. TANG L B, LI P Y, CUI R D, et al . Adjusting crystal orientation to promote sodium-ion transport in V 5 S 8 @graphene anode materials for high-performance sodium-ion batteries. Small Methods , 2023, 7(2): 2201387.10.1002/smtd.202201387 ↗
49. DAI H, ZHAO X, XU H, et al . Design of vertically aligned two-dimensional heterostructures of rigid Ti 3 C 2 T x MXene and pliable vanadium pentoxide for efficient lithium ion storage. ACS Nano , 2022, 16(4): 5556.10.1021/acsnano.1c10212 ↗
50. CHEN Y, XIAO L, LI Y, et al . Laser-assisted preparation of vertically aligned reduced graphene oxide/tannic acid arrays for flexible aqueous zinc-ion hybrid capacitors. Applied Surface Science , 2024, 665: 160230.10.1016/j.apsusc.2024.160230 ↗
51. JIANG X, ZHANG Y, TANG C, et al . Printing 3D array of electrodes made of graphene/carbon black for microsupercapacitors. ACS Applied Nano Materials , 2025, 8(21): 10956.10.1021/acsanm.5c01095 ↗
52. CHEN H, PEI A, WAN J, et al . Tortuosity effects in lithium-metal host anodes. Joule , 2020, 4(4): 938.10.1016/j.joule.2020.03.008 ↗
53. MU Y, CHEN Y, WU B, et al . Dual vertically aligned electrode- inspired high-capacity lithium batteries. Advanced Science , 2022, 9(30): 2203321.10.1002/advs.202203321 ↗
54. CHEN Q, WEI Y, ZHANG X, et al . Vertically aligned MXene nanosheet arrays for high-rate lithium metal anodes. Advanced Energy Materials , 2022, 12(18): 2200072.10.1002/aenm.202200072 ↗
55. TANG L, LIAO C, LI T, et al . In situ vertically aligned MoS 2 arrays electrodes for complexing agent-free bromine-based flow batteries with high power density and long lifespan. Advanced Energy Materials , 2024, 14(1): 2303282.10.1002/aenm.202303282 ↗
56. LI W, LI X, ZHANG X, et al . Flexible poly(vinyl alcohol)-polyaniline hydrogel film with vertically aligned channels for an integrated and self-healable supercapacitor. ACS Applied Energy Materials , 2020, 3(9): 9408.10.1021/acsaem.0c01794 ↗
57. ZHAO T, YANG D, LI B X, et al . A supercapacitor architecture for extreme low-temperature operation featuring MXene/carbon nanotube electrodes with vertically aligned channels and a novel freeze-resistant electrolyte. Advanced Functional Materials , 2024, 34(24): 2314825.10.1002/adfm.202314825 ↗
58. ZHU L, YANG H, XU T, et al . Engineered nanochannels in MXene heterogeneous proton exchange membranes mediated by cellulose nanofiber/sodium alginate dual crosslinked networks. Advanced Functional Materials , 2025, 35(19): 2419334.10.1002/adfm.202419334 ↗
59. ZHENG Y, YAO Y, OU J, et al . A review of composite solid-state electrolytes for lithium batteries: fundamentals, key materials and advanced structures. Chemical Society Reviews , 2020, 49(23): 8790.10.1039/D0CS00305K ↗
60. LAN X, LUO N, LI Z, et al . Status and prospect of two- dimensional materials in electrolytes for all-solid-state lithium batteries. ACS nano , 2024, 18(13): 9285.10.1021/acsnano.4c00128 ↗
61. WANG Y, TU H, SUN A, et al . Dual Li + transport enabled by BN-assisted solid-polymer-electrolyte for high-performance lithium batteries. Chemical Engineering Journal , 2023, 475: 146414.10.1016/j.cej.2023.146414 ↗
62. HUANG Y, LEE M, YANG M, et al . Montmorillonite particle alignment and crystallization and ion-conducting behavior of montmorillonite/poly(ethylene oxide) nanocomposites. Applied Clay Science , 2010, 49(3): 163.10.1016/j.clay.2010.04.021 ↗
63. LI F, ZHOU B, HE J, et al . Polyethylene oxide-based solid electrolytes with fast Li-ion transport channels constructed from 2D montmorillonite for solid-state lithium-metal batteries. Chemical Engineering Journal , 2024, 488: 150700.10.1016/j.cej.2024.150700 ↗
64. SHI J, GUI F, HUANG K, et al . Magnetic field-assisted vertically aligned NiFe 2 O 4 nanosheets in composite solid polymer electrolytes for advanced all solid-state lithium metal batteries. Journal of Colloid and Interface Science , 2025, 678: 583.10.1016/j.jcis.2024.08.174 ↗
65. XU L, XIAO X, TU H, et al . Engineering functionalized 2D metal-organic frameworks nanosheets with fast Li + conduction for advanced solid Li batteries. Advanced Materials , 2023, 35(38): 2303193.10.1002/adma.202303193 ↗
66. MENG J, YIN M, GUO K, et al . In situ polymerization in COF boosts Li-ion conduction in solid polymer electrolytes for Li metal batteries. Nano-Micro Letters , 2025, 17(1): 248.10.1007/s40820-025-01768-3 ↗
67. ZHAO Y, LI L, ZHOU D, et al . Opening and constructing stable lithium-ion channels within polymer electrolytes. Angewandte Chemie International Edition , 2024, 136(31): e202404728.10.1002/ange.202404728 ↗
68. TANG W, TANG S, GUAN X, et al . High-performance solid polymer electrolytes filled with vertically aligned 2D materials. Advanced Functional Materials , 2019, 29(16): 1900648.10.1002/adfm.201900648 ↗
69. WANG Y, LI X, QIN Y, et al . Local electric field effect of montmorillonite in solid polymer electrolytes for lithium metal batteries. Nano Energy , 2021, 90: 106490.10.1016/j.nanoen.2021.106490 ↗
70. MIAO X, HONG J, HUANG S, et al . Vertically-aligned card-house structure for composite solid polymer electrolyte with fast and stable ion transport channels. Small , 2024, 20(31): 2310912.10.1002/smll.202310912 ↗
71. WANG L, YI S, LIU Q, et al . Bifunctional lithium-montmorillonite enabling solid electrolyte with superhigh ionic conductivity for high-performanced lithium metal batteries. Energy Storage Materials , 2023, 63: 102961.10.1016/j.ensm.2023.102961 ↗
72. LI X, FENG J, LI Y, et al . Regulating Li + transport behavior by cross-scale synergistic rectification strategy for dendrite-free and high area capacity polymeric all-solid-state lithium batteries. Energy Storage Materials , 2024, 72: 103759.10.1016/j.ensm.2024.103759 ↗
73. 杨舢, 吴朝军, 陈业红. 锂离子电池中凝胶聚合物电解质研究进展. 中国造纸, 2024, 43(11): 116.10.12677/AEPE.2023.115017 ↗
74. ZUO J, DANG Y, ZHAI P, et al . Fast lithium ion transport pathways constructed by two-dimensional boron nitride nanoflakes in quasi-solid-state polymer electrolyte. Nano Letters , 2023, 23(17): 8106.10.1021/acs.nanolett.3c02169 ↗
75. DU K, SUN C, XUAN Y. Functionalized fillers as “ions relay stations” enabling Li + ordered transport in quasi-solid electrolytes for high-stability lithium metal batteries. Journal of Energy Chemistry , 2025, 102: 84.10.1016/j.jechem.2024.09.069 ↗
76. WEI X, CAI M, YUAN F, et al . The surface functional modification of Ti 3 C 2 T x MXene by phosphorus doping and its application in quasi-solid state flexible supercapacitor. Applied Surface Science , 2022, 606: 154817.10.1016/j.apsusc.2022.154817 ↗
77. KAIBARTA B, DASMAHAPATRA A K. Carbon-based hierarchical mesoporous polyaniline/montmorillonite nanocomposites for high energy density supercapacitors. Journal of Energy Storage , 2024, 83: 110703.10.1016/j.est.2024.110703 ↗
78. YANG Y, XIAO R, SUN X, et al . Constructing two dimensional composite nanosheets with montmorillonite and graphene-like carbon: towards high-rate-performance PVA based gel polymer electrolytes for quasi-solid-state supercapacitors. Materials Chemistry and Physics , 2022, 287: 126333.10.1016/j.matchemphys.2022.126333 ↗
79. BU R, ZHANG B, LI D, et al . Recyclable covalent organic framework templated polymer entanglement for quasi-solid-state lithium-metal batteries. Advanced Functional Materials , 2025, 36(7): e12777.10.1002/adfm.202512777 ↗
80. 孙文浩, 刘娜, 张锟, 等. 高安全锂离子电池用耐高温隔膜的研究进展. 材料工程, 2025, 53(7): 104.
81. MENG X, PENG Q, PENG L, et al . In situ growth of covalent organic framework on graphene oxide nanosheet enable proton-selective transport in flow battery membrane. Journal of Power Sources , 2024, 609: 234690.10.1016/j.jpowsour.2024.234690 ↗
82. LI L, BU R, ZHONG W, et al . Densely packed and vertically oriented covalent organic framework membrane enabled efficient ion sieving for zinc iodine battery. Nano Energy , 2025, 138: 110886.10.1016/j.nanoen.2025.110886 ↗
83. WANG D, CHEN N, LONG C, et al . Electric-field-aligned functionalized-layered double hydroxide/polyphenyl ether composite membrane for ion transport. International Journal of Hydrogen Energy , 2019, 44(26): 13852.10.1016/j.ijhydene.2019.03.252 ↗
84. FANG F, LIU L, MIN L, et al . Enhanced proton conductivity of Nafion membrane with electrically aligned sulfonated graphene nanoplates. International Journal of Hydrogen Energy , 2021, 46(34): 17784.10.1016/j.ijhydene.2021.02.190 ↗
85. GAO Y, QIAO Z, ZHANG L, et al . High-performance proton exchange membrane with vertically aligned montmorillonite nanochannels. Small , 2025, 21(7): 2409192.10.1002/smll.202409192 ↗