Interface Modulation and Microwave Absorbing Mechanism of Ti ₄ O ₇ /CoNi/CNT Heterostructures

1. 李英豪, 廖擎玮, 殷宇翔, 等. 多波段兼容隐身材料的研究进展. 现代技术陶瓷, 2025, 46(5): 431.

2. CHEN H Y, TANG Z P, YIN L J, et al . Low-frequency microwave absorption of CIPs@Mn 0.8 Zn 0.2 Fe 2 O 4 -CNTs composites. Journal of Inorganic Materials , 2024, 39(1): 71.10.15541/jim20230333 ↗

3. WAN H J, XIAO X. Terahertz electromagnetic shielding and absorbing of MXenes and their composites. Journal of Inorganic Materials , 2024, 39(2): 129.10.15541/jim20230453 ↗

4. 李明展, 李恩, 潘亚敏, 等. 电磁屏蔽导电涂料的研究与应用进展. 复合材料学报, 2024, 41(2): 572.

5. GUAN H Y, ZHANG L, JING K K, et al . Interfacial mechanical properties of the domestic 3rd generation 2.5D SiC f /SiC composite. Journal of Inorganic Materials , 2024, 39(3): 259.10.15541/jim20230352 ↗

6. 王江涛, 陈帅, 沈承, 等. 吸波材料/结构及吸波-承载功能一体化结构研究进展. 复合材料学报, 2024, 41(8): 3866.

7. 徐俊杰, 王岭, 王晓猛, 等. 耐高温吸波材料的研究进展. 现代技术陶瓷, 2024, 45: 189.10.37155/2811-0633-0202-63 ↗

8. KOLBRECKA K, PRZYLUSKI J. Sub-stoichiometric titanium oxides as ceramic electrodes for oxygen evolution—structural aspects of the voltammetric behaviour of Ti n O 2 n -1 . Electrochimica Acta , 1994, 39(11/12): 1591.10.1016/0013-4686(94)85140-9 ↗

9. 李阳, 高振良, 卿玉长, 等. Ti x O 2 x -1 基电磁波吸收剂的研究现状与设计展望. 现代技术陶瓷, 2025, 46(S1): 327.10.37155/3041-0819-0106-16 ↗

10. ANDERSSON S, MAGNÉLI A. Diskrete titanoxydphasen im zusammensetzungsbereich TiO 1.75 -TiO 1.90 . Naturwissenschaften , 1956, 43(21): 495.10.1007/BF00632520 ↗

11. XIA T, ZHANG C, OYLER N A, et al . Hydrogenated TiO 2 nanocrystals: a novel microwave absorbing material. Advanced Materials , 2013, 25(47): 6905.10.1002/adma.201303088 ↗

12. XIA T, CAO Y H, OYLER N A, et al . Strong microwave absorption of hydrogenated wide bandgap semiconductor nanoparticles. ACS Applied Materials & Interfaces , 2015, 7(19): 10407.10.1021/acsami.5b01598 ↗

13. GREEN M, XIANG P, LIU Z Q, et al . Microwave absorption of aluminum/hydrogen treated titanium dioxide nanoparticles. Journal of Materiomics , 2019, 5(1): 133.10.1016/j.jmat.2018.12.005 ↗

14. GREEN M, VAN TRAN A T, SMEDLEY R, et al . Microwave absorption of magnesium/hydrogen-treated titanium dioxide nanoparticles. Nano Materials Science , 2019, 1(1): 48.10.1016/j.nanoms.2019.02.001 ↗

15. XU J L, QI X S, LUO C Z, et al . Synthesis and enhanced microwave absorption properties: a strongly hydrogenated TiO 2 nanomaterial. Nanotechnology , 2017, 28(42): 425701.10.1088/1361-6528/aa81ba ↗

16. XU J L, SUN L, QI X S, et al . A novel strategy to enhance the multiple interface effect using amorphous carbon packaged hydrogenated TiO 2 for stable and effective microwave absorption. Journal of Materials Chemistry C , 2019, 7(20): 6152.10.1039/C9TC00483A ↗

17. SHI S Q, HAO S J, YANG C, et al . Enhanced microwave absorption properties of reduced graphene oxide/TiO 2 nanowire composites synthesized via simultaneous carbonation and hydrogenation. Journal of Materials Chemistry C , 2022, 10(25): 9586.10.1039/D2TC01473D ↗

18. SHI X F, LIU Z W, LI X, et al . Enhanced dielectric polarization from disorder-engineered Fe 3 O 4 @black TiO 2- x heterostructure for broadband microwave absorption. Chemical Engineering Journal , 2021, 419: 130020.10.1016/j.cej.2021.130020 ↗

19. YANG P J, LI T H, LI H, et al . Effect of graphene on graphitization, electrical and mechanical properties of epoxy resin carbon foam. Journal of Inorganic Materials , 2024, 39(1): 107.10.15541/jim20230385 ↗

20. LI Y, QING Y C, CAO Y R, et al . Positive charge holes revealed by energy band theory in multiphase Ti x O 2 x -1 and exploration of its microscopic electromagnetic loss mechanism. Small , 2023, 19(41): 2302769.10.1002/smll.202302769 ↗

21. 彭夏文, 张景钦, 陈凌云, 等. 雷达和红外隐身材料的最新研究进展及挑战. 材料研究与应用, 2025, 19(1): 15.

22. LUO W, JIANG X, LIU Y, et al . Entropy-driven morphology regulation of MAX phase solid solutions with enhanced microwave absorption and thermal insulation performance. Small , 2024, 20(8): 2305453.10.1002/smll.202305453 ↗

23. QING Y C, LI Y, LI W, et al . Ti 3+ self-doped dark TiO 2 nanoparticles with tunable and unique dielectric properties for electromagnetic applications. Journal of Materials Chemistry C , 2021, 9(4): 1205.10.1039/D0TC05112H ↗

24. LI Y, QING Y C, LI W, et al . Novel Magnéli Ti 4 O 7 /Ni/poly(vinylidene fluoride) hybrids for high-performance electromagnetic wave absorption. Advanced Composites and Hybrid Materials , 2021, 4(4): 1027.10.1007/s42114-021-00297-y ↗

25. LI Y, QING Y C, ZHAO B, et al . Tunable magnetic coupling and dipole polarization of core-shell Magnéli Ti 4 O 7 ceramic/magnetic metal possessing broadband microwave absorption properties. Ceramics International , 2021, 47(23): 33373.10.1016/j.ceramint.2021.08.240 ↗

26. WANG L, YU X F, LI X, et al . MOF-derived yolk-shell Ni@C@ZnO Schottky contact structure for enhanced microwave absorption. Chemical Engineering Journal , 2020, 383: 123099.10.1016/j.cej.2019.123099 ↗

27. WU Z C, YANG Z Q, JIN C, et al . Accurately engineering 2D/2D/0D heterojunction in hierarchical Ti 3 C 2 T x MXene nanoarchitectures for electromagnetic wave absorption and shielding. ACS Applied Materials & Interfaces , 2021, 13(4): 5866.10.1021/acsami.0c21833 ↗

28. HE M K, ZHANG K Y, QIU H, et al . Low-frequency microwave absorption composites. Advanced Science , 2025, 12(35): e11580.10.1002/advs.202511580 ↗

29. QU N, SUN H X, SUN Y Y, et al . 2D/2D coupled MOF/Fe composite metamaterials enable robust ultra-broadband microwave absorption. Nature Communications , 2024, 15: 5642.10.1038/s41467-024-49762-4 ↗

30. LU X K, LI X, CAO Y C, et al . 1D CNT-expanded 3D carbon foam/Si 3 N 4 sandwich heterostructure: utilizing the polarization compensation effect for keeping stable electromagnetic absorption performance at elevated temperature. ACS Applied Materials & Interfaces , 2022, 14(34): 39188.10.1021/acsami.2c08389 ↗

31. LI Y, QING Y C, ZHANG Y R, et al . Simultaneously tuning structural defects and crystal phase in accordion-like Ti x O 2 x -1 derived from Ti 3 C 2 T x MXene for enhanced electromagnetic attenuation. Journal of Advanced Ceramics , 2023, 12(10): 1946.10.26599/JAC.2023.9220799 ↗

32. FU X, YANG B, CHEN W, et al . Electromagnetic wave absorption performance of Ti 2 O 3 and vacancy enhancement effective bandwidth. Journal of Materials Science & Technology , 2021, 76: 166.10.1016/j.jmst.2020.11.001 ↗

33. XIAO J X, ZHAN B B, HE M K, et al . Mechanically robust and thermal insulating nanofiber elastomer for hydrophobic, corrosion- resistant, and flexible multifunctional electromagnetic wave absorbers. Advanced Functional Materials , 2025, 35(14): 2419266.10.1002/adfm.202419266 ↗

34. 吴海华, 傅文鑫, 刘少康, 等. ZnO-石墨烯-TPU/PLA复合材料的制备及吸波性能. 复合材料学报, 2024, 41(3): 1316.

35. QIAN J J, MA D D, ZHOU X L, et al . Synthesis of SiOC@C ceramic nanospheres with tunable electromagnetic wave absorption performance. Journal of Advanced Ceramics , 2024, 13(9): 1394.10.26599/JAC.2024.9220944 ↗

36. LI X, WANG X L, LI M H, et al . Built-in electric field enhancement strategy induced by cross-dimensional nano- heterointerface design for electromagnetic wave absorption. Advanced Functional Materials , 2025, 35(18): 2407217.10.1002/adfm.202407217 ↗

37. CHEN Y Q, CHEN M, LEI H Y, et al . Microwave-assisted synthesis of high-performance TaC nanorods for enhanced electromagnetic wave absorption. Journal of Advanced Ceramics , 2025, 14(8): 9221130.10.26599/JAC.2025.9221130 ↗

38. LI Y, QING Y C, ZHOU Y F, et al . Unique nanoporous structure derived from Co 3 O 4 -C and Co/CoO-C composites towards the ultra-strong electromagnetic absorption. Composites Part B : Engineering , 2021, 213: 108731.10.1016/j.compositesb.2021.108731 ↗

39. YANG L Y, WANG L M, DONG S, et al . Lightweight C f /HC-SiBCN composite for multifunctional applications. Journal of Advanced Ceramics , 2025, 14(5): 9221068.10.26599/JAC.2025.9221068 ↗

40. 王腾飞, 刘博宇, 庞青, 等. 缺陷介孔TiO 2 的制备及其吸波性能研究. 材料研究与应用, 2025, 19(1): 72.

41. YUAN M Y, LI B X, DU Y Q, et al . Programmable electromagnetic wave absorption via tailored metal single atom- support interactions. Advanced Materials , 2025, 37(8): 2417580.10.1002/adma.202417580 ↗

42. LIANG Q Q, HE M K, ZHAN B B, et al . Yolk-shell CoNi@N-doped carbon-CoNi@CNTs for enhanced microwave absorption, photothermal, anti-corrosion, and antimicrobial properties. Nano-Micro Letters , 2025, 17(1): 167.10.1007/s40820-024-01626-8 ↗

43. CHE R C, M PENG L, DUAN X F, et al . Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes. Advanced Materials , 2004, 16(5): 401.10.1002/adma.200306460 ↗

44. YAO L, DANG J, XIAO J X, et al . Metal chelate-derived and catalytical strategy to produce CoFe/C@bamboo-like carbon nanotubes for microwave absorption, hydrophobicity, and corrosion resistance. Journal of Materials Science & Technology , 2026, 240: 190.10.1016/j.jmst.2025.04.011 ↗