journal article·2025Open access

Performance and Influencing Factors of Iron-based Catalyst for Ortho to Para Hydrogen Conversion

Na LI, Ruixiao CAO, Jin WEI, Han ZHOU, Hongmei XIAO

Journal of Inorganic Materials· Volume 40· Issue 1

Abstract

Ortho to para hydrogen conversion catalyst (O-P catalyst) is integral for large-scale hydrogen liquefaction projects.However, factors that influence catalyst performance remain preliminary and unclear.In the mean time, the mechanical strength of the O-P catalyst is crucial for its efficacy and longevity, yet most related research has paid sufficient attention to the catalytic activity.In this work, an iron-based O-P catalyst was synthesized using a straightforward precipitation method.And effects of catalyst activation method, drying temperature, particle size, concentration ratio, and doping element on catalytic activity and mechanical strength were studied.Furthermore, the catalytic performance and structural characterization of the prepared catalyst and commercial catalyst were compared.The prepared catalyst achieved a para hydrogen (p-H 2 ) content of 46.49% post-conversion at 77 K with a hydrogen flow rate of 1200 mL/min, surpassing the commercial catalyst by 2.9%.The maximum single particle crushing force
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Catalysis and Hydrodesulfurization Studies · Catalysts for Methane Reforming · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (16)

Show source-provided references
1. MUTHUKUMAR P, KUMAR A, AFZAL M, et al. Review on large-scale hydrogen storage systems for better sustainability. International Journal of Hydrogen Energy, 2023, 48(85): 33223.10.1016/j.ijhydene.2023.04.304 ↗
2. ZHOU H, LI Z, LI M, et al. Study of activation methods for ortho-para hydrogen catalysts in a small isothermal converter based on gas chromatography at LN2 temperature. International Journal of Hydrogen Energy, 2024, 55: 55.10.1016/j.ijhydene.2023.10.155 ↗
3. RIAZ A, QYYUM M A, HUSSAIN A, et al. Significance of ortho- para hydrogen conversion in the performance of hydrogen liquefaction process. International Journal of Hydrogen Energy, 2023, 48(68): 26568.10.1016/j.ijhydene.2022.09.022 ↗
4. WAN C, ZHU S, SHI C, et al. Numerical simulation on pressure evolution process of liquid hydrogen storage tank with active cryogenic cooling. International Journal of Refrigeration, 2023, 150: 47.10.1016/j.ijrefrig.2023.01.012 ↗
5. 杨晓阳, 杨昌乐. 正仲氢转化催化剂性能研究. 化学推进剂与高分子材料, 2018, 16(3): 79.
6. 朱楠. 氢正仲转化用铁基催化剂的制备与催化性能研究. 北京: 北京化工大学硕士学位论文, 2019.
7. FUKUTANI K, SUGIMOTO T. Physisorption and ortho-para conversion of molecular hydrogen on solid surfaces. Progress in Surface Science, 2013, 88(4): 279.10.1016/j.progsurf.2013.09.001 ↗
8. WIGNER E. Concerning the paramagnetic conversion of para-ortho hydrogen. III. Zeitschrift Fur Physikalische Chemie-Abteilung B-Chemie Der Elementarprozesse Aufbau Der Materie, 1933, 23(1/2): 28.
9. XU H, WANG J, HAN Y, et al. Effect of unpaired electron number elements (Al, Cr, Mn) doping in Fe2O3 on ortho to para hydrogen conversion at 77 K. Journal of Energy Storage, 2023, 74: 109512.10.1016/j.est.2023.109512 ↗
10. DAS T, KWEON S C, NAH I W, et al. Spin conversion of hydrogen using supported iron catalysts at cryogenic temperature. Cryogenics, 2015, 69: 36.10.1016/j.cryogenics.2015.03.003 ↗
11. XU P, LEI G, XU Y, et al. Study on continuous cooling process coupled with ortho-para hydrogen conversion in plate-fin heat exchanger filled with catalyst. International Journal of Hydrogen Energy, 2022, 47(7): 4690.10.1016/j.ijhydene.2021.11.074 ↗
12. DONAUBAUER P J, CARDELLA U, DECKER L, et al. Kinetics and heat exchanger design for catalytic ortho-para hydrogen conversion during liquefaction. Chemical Engineering & Technology, 2019, 42(3): 669.10.1002/ceat.201800345 ↗
13. ZHUZHGOV A V, KRIVORUCHKO O P, ISUPOVA L A, et al. Low- temperature conversion of ortho-hydrogen into liquid para-hydrogen: process and catalysts. Review. Catalysis in Industry, 2018, 10(1): 9.10.1134/S2070050418010117 ↗
14. WEITZEL D H, PARK O E. Iron catalyst for production of liquid para-hydrogen. Review of Scientific Instruments, 1956, 27(1): 57.10.1063/1.1715369 ↗
15. SNADIN A V, CHUKLINA N O, KIRYUTIN A S, et al. Magnetic field dependence of the para-ortho conversion rate of molecular hydrogen in SABRE experiments. Journal of Magnetic Resonance, 2024, 360: 107630.10.1016/j.jmr.2024.107630 ↗
16. XU H, BI S, XUE M, et al. Amorphous cobalt iron oxide nanoparticles with high magnetization intensity for spin conversion of hydrogen at 77 K. International Journal of Hydrogen Energy, 2023, 48(81): 31643.10.1016/j.ijhydene.2023.04.313 ↗